铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究   总被引：1，自引：0，他引：1  

张淑云  何平 《岩矿测试》1997,16(4):313-315

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。  相似文献   

The Organization of Production in High Technology Industries: An Empirical Assessment*     

Audrey E. Clarke  Brian P. Holly 《The Professional geographer》1996,48(2):127-139

Recent attention given to the concept of vertical integration and disintegration of production processes has identified the existence of a continuum, with small, flexibly specialized producers at one end and large, mass production units at the other end. Firms along the continuum constantly strive for the optimum combination of economies of scale and scope. This paper attempts to identify the organizational characteristics of high technology firms in one industrial complex of the U.S. Manufacturing Belt. A principal components analysis is performed on a number of theoretically relevant variables for a sample of high technology establishments in Northeast Ohio. The results indicate that the region contains a variety of organizational forms ranging from isolated workshops to large, vertically integrated assembly plants. These findings conform to expectations derived from recent conceptualizations in the literature. Additional empirical research will further enhance understanding of the processes that shape the organization of production in territorial complexes.  相似文献   

Rapid Variscan exhumation and the role of magma in core complex formation: southern Brittany metamorphic belt, France   总被引：6，自引：0，他引：6  

MICHAEL BROWN  R. DAVID DALLMEYER 《Journal of Metamorphic Geology》1996,14(3):361-379

ABSTRACT The high-grade migmatitic core to the southern Brittany metamorphic belt has mineralogical and textural features that suggest high-temperature decompression. The chronology of this decompression and subsequent cooling history have been constrained with ⁴⁰Ar/³⁹ Ar ages determined for multigrain concentrates of hornblende and muscovite prepared from amphibolite and late-orogenic granite sheets within the migmatitic core, and from amphibolite of the structurally overlying unit. Three hornblende concentrates yield plateau isotope correlation ages of c. 303–298 Ma. Two muscovite concentrates record well-defined plateau ages of c. 306–305 Ma. These ages are geologically significant and date the last cooling through temperatures required for intracrystalline retention of radiogenic argon. The concordancy of the hornblende and muscovite ages suggest rapid post-metamorphic cooling. Extant geochronology and the new ⁴⁰Ar/³⁹Ar data suggest a minimum time-integrated average cooling rate between c. 725 °C and c. 125 °C of c. 14 ± 4°C Ma^-1, although below 600 °C the data permit an infinitely fast rate of cooling. Mineral assemblages and reaction textures in diatexite migmatites suggest c. 4 kbar decompression at 800–750 °C. This must have pre-dated the rapid cooling. Emplacement of two-mica granites into the metamorphic belt occurred between 345 and 300 Ma. The youngest plutons were emplaced synkinematically along shallow-dipping normal faults interpreted to be reactivated Eo-Variscan thrusts. A penetrative, west-plunging stretching lineation developed in these granites suggests that extension was orogen-parallel. Extension was probably related to regional uplift and gravitational collapse of thermally weakened crust during constrictional (escape) tectonics in this narrow part of the Variscan orogen. This followed slab breakoff during the terminal stages of convergence between Gondwana and Laurasia; detachment may have been consequent upon a change in kinematics leading to dextral displacement within the orogen. Dextral ductile strike-slip displacement was concentrated in granites emplaced synkinematically along the South Armorican Shear Zone. Rapid cooling is interpreted to have resulted from tectonic unroofing with emplacement of granite along decollement surfaces. The high-grade migmatitic core of the southern Brittany metamorphic belt represents a type of metamorphic core complex formed during orogen-parallel extensional unroofing and regional-scale ductile flow.  相似文献   

瞬变电磁场的奇点展开法     

汤井田 《物探与化探》1996,20(5):321-328

在分析电磁系统自然谐振现象的基础上,简述了瞬变电磁场奇点展开法的物理基础、基本理论、极点提取方法,并考查了奇点展开法在地球物理中的应用可能性。  相似文献   

安徽省铜陵地区侵入岩成因的实验研究     

邢凤鸣  赵斌  徐祥  朱成明  赵劲松  蔡恩照 《地质通报》1997,(3)

通过３７次成岩实验研究认为：（１）在地壳温度下，地壳物质的重熔不可能形成石英闪长质或更基性的岩浆；（２）碱性玄武岩浆同化花岗质地壳，可以生成石英闪长质和花岗闪长质岩浆，所产生的岩浆高钾富碱，属高钾岩系，与铜陵地区侵入岩相似；（３）高压下形成的岩浆比中压下形成的岩浆更高钾富碱；（４）在岩浆演化过程中铜与钾似无成因联系，钾与铜的“相关性”与它们的趋同性有关，即两者均于岩浆晚期富集。  相似文献   

The mafic-ultramafic complex near Finero (Ivrea-Verbano Zone), I. Chemistry of MORB-like magmas     

Meihua Lu  Albrecht W. Hofmann  Maurizio Mazzucchelli  Giorgio Rivalenti 《Chemical Geology》1997,140(3-4):207-222

Geochemical data are presented for the meta-igneous, mafic-ultramafic complex near Finero. This complex is in contact with a phlogopite-bearing mantle peridotite and is subdivided into the Internal Gabbro unit, the Amphibole Peridotite unit, and the External Gabbro unit. The Internal Gabbro and the Amphibole Peridotite units consist of coarse-grained, chemically heterogeneous cumulates, whereas the External Gabbro unit is generally massive, chemically more uniform and approximately representative of the residual melt with MgO contents between 6.6 and 9.1% and Mg numbers between 38 and 58. Both whole-rock and mineral contents of Ni and Cr are significantly higher (at similar Mg numbers) in the Amphibole Peridotite unit than in the Internal Gabbro unit. The most straightforward interpretation of this is that the Amphibole Peridotite unit accumulated after the influx of fresh mafic (or ultramafic) magma into the magma chamber. Major-element chemical trends are continuous from the Amphibole Peridotite unit to the External Gabbro unit and are consistent with closed-system fractionation with no further addition of magma or contamination by wall or roof rock assimilation. In the External Gabbro unit, total FeO and TiO₂ contents are strongly correlated with each other (and with P₂O₅ and Zr) and reach values as high as 19 and 4%, respectively, indicating an advanced degree of crystal fractionation along a tholeftic trend. The External Gabbro samples have generally smooth normalized trace element patterns, which are consistent with being representative of a liquid composition. The residual nature of the External Gabbro magma is also indicated by negative Eu and Sr anomalies, clear evidence for prior feldspar fractionation. REE patterns are otherwise indistinguishable from N-type MORB, but Th and U are significantly more depleted than in MORB. This Th and U depletion is similar to that found in olivine basalts and picrites on Iceland and Hawaii; its origin is not well understood. No evidence is seen for any assimilation of crystal material, in sharp contrast with the situation of the igneous complex in Val Sesia near Balmuccia, where the magma composition is dominated by assimilation of crust. We suggest that the heat provided by at most two injections of magma near Finero was insufficient to induce crystal anatexis, in contrast with the excess heat supplied by multiple magma injections at Balmuccia.  相似文献   

水口山矿田花岗质潜火山杂岩的成因特征   总被引：5，自引：1，他引：5  

喻亨祥  刘家远 《大地构造与成矿学》1997,21(1):32-40

水口山矿田内发育的花岗质岩石并非是互不联系的单体，而是一套由地下火山作用一潜火山作用在特定的构造条件和不同深度环境下，以不同方式形成的并规律结合的岩浆岩组合──花岗质潜火山杂岩。包括浅成（超浅成）侵入的花岗闪长质岩石、次火山侵入的英安份岩质岩石及其伴生的隐爆碎屑岩类。老鸦巢Ⅳ号角砾岩是英安玢岩质母岩浆在超浅成环境下隐蔽爆破而形成的隐爆角砾岩，它至少存在三条标志以区别于其它各类角砾岩。这套潜火山杂岩具过渡性地质地球化学特征。  相似文献   

张宣幔枝构造的成矿作用研究     

牛树银  孙爱群 《吉林大学学报(地球科学版)》1997,(4)

地幔热柱具有多级演化特征。河淮亚热柱顶部地幔物质以薄板状斜插至燕山造山带之下，燕山造山带轴部东西向尚义－赤城韧性剪切带与太行山构造岩浆带轴部北北东向乌龙沟－上黄旗韧性剪切带交汇叠加，使深部中下地壳应变软化岩石及深部幔源物质减压释荷产生深熔岩浆并上侵，从而加速了造山带的上隆速度，并可形成地幔热柱的第三级构造单元——幔枝构造。其中隆升较快的地段发育成为典型的变质核杂岩构造。幔枝构造控制着构造变形－岩浆活动－蚀变变质－成矿作用统一体系，并形成与幔枝构造密切相关的内带为金（铜钼）、外带为银（铅锌）多金属的成矿系列。论述了不同构造部位的成矿特征及其相关性、统一性。据此提出了在有利构造部位（参照已有矿点分布）扩大找矿和向深部扩大找矿的认识。  相似文献   

秦岭造山带地壳构造与楔入成山   总被引：23，自引：3，他引：23       下载免费PDF全文

袁学诚 《地质学报》1997,71(3):227-235

横穿秦岭的河南叶县至湖北南漳的反射地震剖面揭示，秦岭造山带地壳由一系列由南向北楔入到中地壳的鳄鱼式构造所组成。南北溱岭上地壳分别形成南秦岭和北秦岭推覆系。北秦岭推覆系是组成基底的地壳沿脆转换面拆离冲叠形成的一个推覆系，可以分出栾川推覆体，瓦穴子推覆体，二郎坪推覆体及朱夏推覆体。  相似文献   

钻孔扩底灌注桩施工新工艺   总被引：3，自引：0，他引：3  

王旭惠  何建平 《华东地质学院学报》1997,20(1):30-34

本文介绍钻孔扩底灌注桩的施工新工艺，多应式扩底钻头特点，成桩技术标准，适用范围及经济效益分析。  相似文献