Assessment of Heavy Metal Contamination of Wetland Soils from a Typical Aquatic–Terrestrial Ecotone in Haihe River Basin,North China     

Rong Xiao  Junhong Bai  Qinggai Wang  Haifeng Gao  Laibin Huang  Xinhui Liu 《洁净——土壤、空气、水》2011,39(7):612-618

Surface soils were collected in the aquatic–terrestrial ecotone (ATE) of Yongnianwa wetland, downstream of Haihe River basin of North China in June of 2007. Samples were subjected to a total digestion technique before they were analyzed for total concentrations of Cr, Cu, Ni, Pb, and Zn to investigate their pollution levels in the ATE. The contamination index, integrated contamination index, geoaccumulation index, toxic units, and sum of toxic units were adopted to assess the heavy metal contamination levels and ecotoxicity, respectively. The results showed all the selected element concentrations in upland soils of the ecotone were relatively higher than those in the lowland soils. No Cr pollution was observed in all soil samples, but almost all samples were slightly polluted by Cu, Ni, Pb, and Zn except for Site 1. The contamination indexes and geoaccumulation indexes consistently presented no contamination for Site 1 and slight contamination for other sites. The ΣTUs increased from lowland to upland, but the whole level of toxicity in this ecotone was relatively low.  相似文献   

Distribution of heavy metals in soils of Port Harcourt and its environs,Niger Delta,Nigeria   总被引：1，自引：0，他引：1  

Minapuye I Odigi  Lucky O. Ukren  Hycienth O. Nwankwoala 《中国地球化学学报》2011,30(4):415-421

Geochemical evaluation of the distribution of heavy metals in soils of Port Harcourt and its environs in the Niger Delta region is presented in respect of anthropogenic factor and index of geoaccumulation. Sixteen (16) soil samples were collected from two horizons (0-10 cm and 100 cm) from the various grids and analyzed. The geo-chemical analyses showed the vertical and horizontal distributions of heavy metals. The results showed the ranges of the metals determined as follows: Pb (6.86-2.49)×10-6, with an average of 4.63×10-6; Cd (0.05-0.00)×10-6, with an average of 0.02×10-6, As (0.01-0.00)×10-6, with an average of 0.00×10-6. Cu (15.36-10.80) ×10-6, with an average of 13.36×10-6, and V (1.36-0.20)×10-6, with an average of 0.94×10-6. Quantification of the degree of pollution was carried out using anthropogenic factor (AF) and index of geoaccumulation (Igeo). The Igeo values of 0.06, 0.02 and 0.00 for Pb, Cd and As, respectively indicate low-level contamination while Zn (1.14) and V (1.40) show me-dium-level contamination. The sources of contamination are attributed to urbanized anthropogenic activities. The majority of the samples analyzed show that the AF values are less than 1 with the exception of vanadium (V) whose AF values range from 2.73 to 13.60×10-6. Vanadium is more enriched than As, Cd, Pb, and Cu. The order of degrees of anthropogenic contamination and index of geoaccumulation in the soil is V >Zn >Pb >Cu >Cd >AS. Metals were retained near the top soil and their concentrations in the deepest horizons were lower and normal for uncontaminated soils. Metal concentrations in the top soil horizons were significantly related to distance from the industrial and hu-man activities.  相似文献   

舒城县东部地区地下水环境质量评价与污染分析     

宋仁亮  王少龙  陈干  王志强  解会存 《地下水》2011,(6):63-67

根据舒城东部地区地下水环境实地调查结果,本文选取78个地下水样,按埋深10m以浅、10m以深进行地下水质量分类评价和污染分析.结果表明:①地下水水质绝大部分为Ⅳ类、Ⅴ类水,地下水污染非常严重,主要污染因素是Fe、Mn、Al、Hg、NO3-和氨氮等.②埋深10m以浅的地下水水质主要是Fe、Mn、Al、Hg、NO3-和氨氮...  相似文献   

Soil baseline geochemistry and plant response in areas of complex geology. Application to NW Euboea,Greece     

Christos Kanellopoulos  Ariadne Argyraki 《Chemie der Erde / Geochemistry》2013

A soil and vegetation survey was undertaken in NW Euboea Island, Greece. The objectives of the study were to establish the geochemical baseline of soil and identify the impact of local geology on threshold values of potentially harmful elements. The studied area is characterized by complex geology comprising metamorphic and ultramafic rocks as well as active hot springs. A total of 117 soil samples were collected from 89 sites at depths of 0–25 cm and 25–50 cm. Eighteen vegetation samples were also collected representing prevalent indigenous perennial species in the region. Soil samples from the present study were enriched in As, Ca, Cu, Mg, Ni with concentrations reaching 233 mg/kg, 38%, 336 mg/kg, 10.8%, 1560 mg/kg respectively. Factor analysis revealed three main factors controlling the chemical composition of soil reflecting the influence of ultramafic rocks (Cr, Ca, Mg, Ni), hot spring deposits (Ca, S, Sr, As) and paedogenesis processes (Fe, Co, V, Mn, Al). The first two of these factors showed significant spatial correlation with the geological features within the study area. Subsequently, baseline concentrations based on statistical and spatial data were estimated within sub-areas reflecting the influence of local geology in soil composition. Concentrations of potentially harmful elements in the plant tissues of indigenous perennial vegetation species showed a wide range of variation from below the detection limit up to 1700 mg/kg for Ni in the hyperaccumulator Alyssum chalcidicum demonstrating that plant species have adapted to the stressful conditions caused by high elemental concentrations in soil. The results of this study can be utilized in future studies at areas of similar geology by providing an objective basis for setting realistic threshold values for pollution assessment and remediation.  相似文献   

地下水污染监测网多目标优化设计模型及进化求解   总被引：2，自引：2，他引：0       下载免费PDF全文

骆乾坤  吴剑锋  林锦  祝晓彬  吴吉春 《水文地质工程地质》2013,40(5):97-103

采用模拟-优化方法建立了一个用于地下水污染监测网设计的多目标优化模型,该模型包括最小化监测费用、污染物质量评估误差、污染羽一阶矩评估误差和二阶矩评估误差等4个目标函数,以充分揭示减少地下水污染监测费用与提高污染监测精度之间的权衡关系.将改进小生境Pareto遗传算法与地下水流模拟程序和污染物运移模拟程序相耦合用于求解地下水污染监测网多目标设计模型.算例研究表明,采用进化算法求解监测网的多目标模型,能真实地反映各个目标函数间的权衡关系,并且不用考虑传统方法中惩罚因子的影响.与单目标优化模型相比,多目标优化模型可在较短的时间内得到优化问题的一系列Pareto权衡解,以利于相应条件下决策者选择最为经济有效的地下水污染监测方案.  相似文献   

新疆阿尔金山喀腊大湾地区玄武岩的地球化学特征及地质意义   总被引：3，自引：0，他引：3  

郝瑞祥  陈柏林  陈正乐  王永  李松彬  韩凤彬  周永贵 《地球学报》2013,34(3):307-317

对新疆阿尔金山东段喀腊大湾地区玄武岩进行了系统的岩石地球化学分析, 结果表明, 喀腊大湾地区的玄武岩具有低的Mg#值(Mg#=Mg/(Mg+Fe)×100)。稀土元素的含量变化范围较大, 轻重稀土分异不明显, 具有轻微的轻稀土富集, 弱的Eu负异常。微量元素Ni、Co、Cr与MgO呈正相关, 微量元素多元素标准化图解中, 普遍具有Nb、Ta的负异常, 部分样品具有Ti的负异常。在Th/Yb-Ta/Yb和Th/Hf-Ta/Hf构造环境判别图解中, 分别落入活动大陆边缘环境和大陆拉张(或初始裂谷)环境, 结合本区双峰式火山岩中玄武岩的地球化学特征, 以及与北阿尔金蛇绿混杂岩带其它地区玄武岩的对比, 认为喀腊大湾地区的玄武岩可能形成于紧邻北阿尔金地区古洋盆的活动大陆边缘环境。  相似文献   

土壤污染评价中几种不同评价标准的比较——以合肥地区为例   总被引：2，自引：0，他引：2  

邢润华  陈永宁 《安徽地质》2008,18(1):42-46

利用不同的评价标准对合肥地区土壤重金属污染状况进行评价。发现以区域土壤环境背景值上限值作为评价标准,土壤污染问题十分普遍,相当多的城镇区和工业区污染程度很严重,据此统计出的污染面积一般较大;而采用GB15618土壤环境质量标准并根据土壤的应用功能不同进行评价,土壤中污染元素含量多属于相对洁净水平,以此统计的污染面积要小得多。  相似文献   

An Improved Gas Chromatographic Method for the Determination of C6–C12 Petroleum Hydrocarbons in Soil Water     

Maryna Voyevoda  Wolfgang Geyer  Sibylle Mothes 《洁净——土壤、空气、水》2008,36(2):164-170

In this work, investigations dealing with the determination of hydrocarbons in contaminated soil water are presented. The hydrocarbons under investigation range from low to high volatility compounds. A GC‐FID method was developed that due to its efficiency, routine suitability, relative rapidity, and low cost is suitable for the analysis of complex chemical mixtures of highly volatile hydrocarbons (with boiling points between 69 and 190°C). The standard used was a gasoline mixture with boiling points ranging from 100 to 190°C. For this standard, no supplementary preparation is needed and it is suitable for the whole range of hydrocarbons under investigation. The determination of the hydrocarbon content of the samples was performed applying univariate and multivariate statistical analysis to the experimental data. In the characterization of a contamination with highly volatile hydrocarbons of soil water originating from different depth layers from the chemistry location Leuna (Sachsen‐Anhalt, Germany), the advantages of a multivariate method are demonstrated in exemplary manner.  相似文献   

Petrogenesis and tectonic setting of bimodal volcanism in the Sakoli Mobile Belt, Central Indian shield     

Talat  Ahmad  Kabita C.  Longjam  Baishali  Fouzdar  Mike J.  Bickle  Hazel J.  Chapman 《Island Arc》2009,18(1):155-174

The Sakoli Mobile Belt comprises bimodal volcanic rocks that include metabasalt, rhyolite, tuffs, and epiclastic rocks with metapelites, quartzite, arkose, conglomerate, and banded iron formation (BIF). Mafic volcanic rocks are tholeiitic to quartz‐tholeiitic with normative quartz and hypersthene. SiO₂ shows a large compositional gap between the basic and acidic volcanics, depicting their bimodal nature. Both the volcanics have distinct geochemical trends but display some similarity in terms of enriched light rare earth element–large ion lithophile element characteristics with positive anomalies for U, Pb, and Th and distinct negative anomalies for Nb, P, and Ti. These characteristics are typical of continental rift volcanism. Both the volcanic rocks show strong negative Sr and Eu anomalies indicating fractionation of plagioclases and K‐feldspars, respectively. The high Fe/Mg ratios for the basic rocks indicate their evolved nature. Whole rock Sm–Nd isochrons for the acidic volcanic rocks indicate an age of crystallization for these volcanic rocks at about 1675 ± 180 Ma (initial ¹⁴³Nd/¹⁴⁴Nd = 0.51017 ± 0.00017, mean square weighted deviate [MSWD] = 1.6). The εNd_t (t = 2000 Ma) varies between ?0.19 and +2.22 for the basic volcanic rock and between ?2.85 and ?4.29 for the acidic volcanic rocks. Depleted mantle model ages vary from 2000 to 2275 Ma for the basic and from 2426 to 2777 Ma for the acidic volcanic rocks, respectively. These model ages indicate that protoliths for the acidic volcanic rocks probably had a much longer crustal residence time. Predominantly basaltic magma erupted during the deposition of the Dhabetekri Formation and part of it pooled at crustal or shallower subcrustal levels that probably triggered partial melting to generate the acidic magma. The influence of basic magma on the genesis of acidic magma is indicated by the higher Ni and Cr abundance at the observed silica levels of the acidic magma. A subsequent pulse of basic magma, which became crustally contaminated, erupted as minor component along with the dominantly acidic volcanics during the deposition of the Bhiwapur Formation.  相似文献   

利用高密度电阻率法监测地下介质污染问题的数值模拟   总被引：4，自引：0，他引：4  

余京洋 《煤田地质与勘探》2006,34(2):73-76

对地下介质不同污染模式的电性分布特征,给出了不同的地电模型。针对不同的地电模型,利用2.5维有限元正演模拟的方法计算出了不同监测装置形式下的异常分布特征,并给出了针对不同污染模式的最优监测装置形式和异常分析方法。同时模拟分析了对于不同污染程度监测的可行性。   相似文献