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21.
用矩阵方法,求解McCreary和Fickian铅垂向湍扩散形式下,无界海洋条件时在风应力和深层浮力作用下的线性解。得出不同的湍扩散系数A情况下McCreary与Fickian湍扩散形式的流场结构。指出随湍扩散系数的增加,McCreary和Fickian湍扩散形式下u分量结构及其量值差异增大。在Fickian湍扩散形式下,能量穿越密度跃层的传递能力较强。当A=0.1cm~2s~(-3)时,在风应力和深层浮力作用下两种湍扩散形式造成流场的差异很小。提出在小湍扩散系数下,用McCreary湍扩散形式研究热带海洋环流,其结果和Fickian形式应相当一致。 相似文献
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成都经济区天降水与下渗水元素地球化学特征及土壤元素输入输出通量 总被引:2,自引:0,他引:2
论文研究了成都经济区天降水和下渗水中元素含量、在农田耕层中的输入输出通量及其影响因素.研究表明,研究区雨水中含有大量SO2-4、NO-3等酸性物质,雨水中SO2-4 >NO-3>Cl-.雨水中Ca2 和NH 4含量最高,且NH 4>Ca2 >K >Na >Mg2 .雨水的pH与阴、阳离子摩尔浓度差值具有显著相关性.下渗水中以Ca2 为主要阳离子,且Ca2 >Na >Mg2 >K >NH 4;HCO-3为主要阴离子,且HCO-3>NO-3>SO2-4>Cl->F-,下渗水pH与阳、阴离子摩尔浓度差值具有显著相关性.不同地区雨水中Pb>As>Cd>Se>Hg,下渗水中Pb>As>Se>Cd>Hg,因此,Cd、Pb、Se和Hg等元素累积在耕层中,而As则被下渗水携带迁移出耕层进入地下水.由降雨输入土壤中的Cd通量均大于下渗水输出Cd的通量,局部地区As下渗通量高于雨水输入通量的5.45~13.16倍.土壤中元素的下渗比与土壤质地、pH有关. 相似文献
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An in situ method of estimating the effective diffusion coefficient for a chemical constituent that diffuses into the primary porosity of a rock is developed by abruptly changing the concentration of the dissolved constituent in a borehole in contact with the rock matrix and monitoring the time-varying concentration. The experiment was conducted in a borehole completed in mudstone on the campus of the University of the Free State in Bloemfontein, South Africa. Numerous tracer tests were conducted at this site, which left a residual concentration of sodium chloride in boreholes that diffused into the rock matrix over a period of years. Fresh water was introduced into a borehole in contact with the mudstone, and the time-varying increase of chloride was observed by monitoring the electrical conductivity (EC) at various depths in the borehole. Estimates of the effective diffusion coefficient were obtained by interpreting measurements of EC over 34 d. The effective diffusion coefficient at a depth of 36 m was approximately 7.8×10?6 m2/d, but was sensitive to the assumed matrix porosity. The formation factor and mass flux for the mudstone were also estimated from the experiment. 相似文献
25.
Results from numerical investigations regarding the exchange of HNO3, NH3, and NH4NO3 between the atmosphere and the biosphere are presented. The investigations were performed with a modified inferential method which is based on the generally accepted micrometeorological ideas of the transfer of momentum, sensible heat and matter near the Earth's surface and the chemical reactions among these nitrogen compounds. This modified inferential method calculates the micrometeorological quantities (such as the friction velocity and the fluxes of sensible and latent heat), the height-invariant fluxes of the composed chemically conservative trace species with group concentrationsc
1=[HNO3]+[NH4NO3] (total nitrate),c
2=[NH3]+[NH4NO3] (total ammonia), andc
3=[HNO3]-[NH3] as well as the fluxes of the individual nitrogen compounds. The parameterization of the fluxes is based on the flux-gradient relationships in the turbulent region of the atmospheric surface layer. The modified inferential method requires only the data of wind velocity, temperature, humidity and concentrations (HNO3, NH3, and NH4NO3) measured at a reference height by stations of a monitoring network. 相似文献
26.
Neal T. Skipper Peter A. Lock James O. Titiloye Jan Swenson Zakaria A. Mirza W. Spencer Howells Felix Fernandez-Alonso 《Chemical Geology》2006,230(3-4):182-196
The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献
27.
The authors identify and describe the following global forces of nature driving the Earth’s climate: (1) solar radiation as a dominant external energy supplier to the Earth, (2) outgassing as a major supplier of gases to the World Ocean and the atmosphere, and, possibly, (3) microbial activities generating and consuming atmospheric gases at the interface of lithosphere and atmosphere. The writers provide quantitative estimates of the scope and extent of their corresponding effects on the Earth’s climate. Quantitative comparison of the scope and extent of the forces of nature and anthropogenic influences on the Earth’s climate is especially important at the time of broad-scale public debates on current global warming. The writers show that the human-induced climatic changes are negligible. 相似文献
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W. M. L. Meijninger A. E. Green O. K. Hartogensis W. Kohsiek J. C. B. Hoedjes R. M. Zuurbier H. A. R. De Bruin 《Boundary-Layer Meteorology》2002,105(1):63-83
A large aperture scintillometer (LAS) andradio wave scintillometer (RWS)were installed over a heterogeneous areato test the applicability of the scintillation method.The heterogeneity in the area, whichconsisted of many plots, was mainly caused bydifferences in thermal properties ofthe crops; the variations in theaerodynamic roughness lengthwere small. The water vapour fluxesderived from the combined LAS-RWSsystem, also known as the two-wavelengthmethod, agreed fairly well with the aggregatedwater vapour fluxes derived from in-situeddy covariance measurements. The water vapourfluxes derived from a stand-alone LASare also presented. It was found that a single LASand an estimate of the area averagedavailable energy (using a simple parameterisationscheme) can provide also reasonablearea-averaged water vapour fluxes. 相似文献