New analytical solution of the dispersion equation     

Khaled S.M. Essa  Soad M. Etman  M. Embaby 《Atmospheric Research》2007,84(4):337-344

The dispersion of pollutants from a point source is analytically investigated taking into consideration the vertical variation of both wind speed and eddy diffusivity. The deposition of the diffusing particles on the ground is taken into account throughout the boundary conditions. The concentration of pollutants under different atmospheric stabilities was found assuming that the vertical diffusion is limited by an elevated inversion layer. The decay distance of a pollutant along the wind direction for different atmospheric stabilities was derived. The resulting analytical formulae have been applied on a case study namely, the emission from the research reactor at Inshas. The results are discussed and presented in illustrative figures.  相似文献   

黄土高原典型塬区土壤热性质变化特征研究   总被引：1，自引：0，他引：1  

马欣  张堂堂  陈金雷 《高原气象》2019,38(3):507-517

利用2014年7月至2015年1月黄土高原地区土壤含水量和土壤热性质观测资料,分析了该区域土壤热性质及其变化特征,并讨论了降水对土壤热性质的影响,结果显示:(1)除10 cm外,各层土壤热扩散率整体上呈现夏季下降,秋季平稳,冬季上升三个阶段,土壤体积比热容和土壤导热率表现为夏季上升,秋季平稳,冬季下降的趋势;100 cm处的土壤热扩散率始终高于40 cm,土壤热扩散率不随土壤深度增加而线性增加。(2)5 cm与10 cm层的土壤热性质均有明显日变化特征,且振幅较大,40 cm与100 cm处的日变化振幅逐渐变小。由于10 cm层土壤含水量的波动最大,该层的土壤热性质变化波动也最大。(3)土壤温度与土壤热扩散率随降水增加而下降,土壤热扩散率下降主要是土壤含水量较高时,土壤导热率与土壤体积比热容变化的幅度不一致所致;土壤体积比热容与土壤导热率随降水量增加而上升,降水主要通过土壤含水量的变化影响土壤热性质。  相似文献   

Analysis of Diffusion and Adsorption of Volatile Organic Compounds in Zeolites by a Single Pellet Moment Technique     

Cevdet Akosman  Mehmet Kalender 《洁净——土壤、空气、水》2009,37(2):115-121

The diffusion and adsorption of two common volatile organic compounds, i. e., methanol and benzene, in different zeolite pellets were studied experimentally by using the single pellet moment technique. The experiments were conducted in a one‐sided single pellet adsorption cell at different temperatures in the range between 303 and 343 K. The results showed that both volatile organic tracers were adsorbed reversibly onto all zeolite samples. The overall adsorption equilibrium constants of both volatile organic compounds decreased with increasing temperature. The adsorption of the tracers onto the zeolite samples were found to increase in the order of NaY > clinoptilolite > 4A. In the range between 303 and 343 K, the adsorption constants of benzene range from 10.51 to 5.52 for zeolite 4A, from 11.90 to 6.37 for clinoptilolite and from 20.32 to 9.82 for NaY. The adsorption constants of methanol range from 19.05 to 8.26 for zeolite 4A, from 38.40 to 9.12 for clinoptilolite and from 74.21 to 14.70 for NaY at temperatures between 303 and 333 K. The effective diffusivities for benzene varied from 2.20·10^–6 to 13.01·10^–6 m²/s, whereas for methanol, they varied from 9.80·10^–6 to 15.60·10^–6 m²/s at the temperatures studied.  相似文献   

Assessing vertical diffusion in a stratified lake using a three-dimensional hydrodynamic model     

Fei Dong  Chenxi Mi  Michael Hupfer  Karl-Erich Lindenschmidt  Wenqi Peng  Xiaobo Liu  Karsten Rinke 《水文研究》2020,34(5):1131-1143

Vertical turbulent diffusivity (K_z), which can be estimated from water temperature, is a key factor in the evolution of water quality in lentic waters. In this study, we analysed the capability of a three-dimensional hydrodynamic model (EFDC) to capture water temperature and vertical diffusivity in Lake Arendsee in the Northern German plain. Of particular interest to us is to evaluate the model performance for capturing the diffusion minimum within the metalimnion and analyse the response of the metalimnetic K_z to meteorological forcing, namely changing wind speed and warming. The comparison confirmed that the calibrated model could reproduce both stratification dynamics and vertical diffusion profiles in the lake. The model was also shown to be able to capture the duration and vertical extent of the metalimnetic diffusion minimum. The scenario results illustrate that, compared to air temperature, wind velocity appeared to be the more influential meteorological variable on the vertical exchange within the metalimnion. While increasing wind velocities mostly affected the minimum values of K_z in the metalimnion and thus led to intensified vertical exchange, the reduction of wind velocity mostly affected the depth of minimal K_z, but not its absolute value.  相似文献   

Bioturbation and erosion rates along the soil-hillslope conveyor belt,part 2: Quantification using an analytical solution of the diffusion–advection equation     

Andrea Román-Sánchez  Ana Laguna  Tony Reimann  Juan Vicente Giráldez  Adolfo Peña  Tom Vanwalleghem 《地球表面变化过程与地形》2019,44(10):2066-2080

Particles on soil-mantled hillslopes are subject to downslope transport by erosion processes and vertical mixing by bioturbation. Both are key processes for understanding landscape evolution and soil formation, and affect the functioning of the critical zone. We show here how the depth–age information, derived from feldspar-based single grain post-infrared infrared stimulated luminescence (pIRIR), can be used to simultaneously quantify erosion and bioturbation processes along a hillslope. In this study, we propose, for the first time, an analytical solution for the diffusion–advection equation to calculate the diffusivity constant and erosion–deposition rates. We have fitted this model to age–depth data derived from 15 soil samples from four soil profiles along a catena located under natural grassland in the Santa Clotilde Critical Zone Observatory, in the south of Spain. A global sensitivity analysis was used to assess the relative importance of each model parameter in the output. Finally, the posterior probability density functions were calculated to evaluate the uncertainty in the model parameter estimates. The results show that the diffusivity constant at the surface varies from 11.4 to 81.9 mm² a^-1 for the hilltop and hill-base profile, respectively, and between 7.4 and 64.8 mm² a^-1 at 50 cm depth. The uncertainty in the estimation of the erosion–deposition rates was found to be too high to make a reliable estimate, probably because erosion–deposition processes are much slower than bioturbation processes in this environment. This is confirmed by a global sensitivity analysis that shows how the most important parameters controlling the age–depth structure in this environment are the diffusivity constant and regolith depth. Finally, we have found a good agreement between the soil reworking rates proposed by earlier studies, considering only particle age and depth, and the estimated diffusivity constants. The soil reworking rates are effective rates, corrected for the proportion of particles actually participating in the process. © 2019 John Wiley & Sons, Ltd.  相似文献   

Determination of hydraulic diffusivity of aquifers by spectral analysis   总被引：1，自引：1，他引：0  

D. C.-F. Shih 《Stochastic Environmental Research and Risk Assessment (SERRA)》1999,13(1-2):85-99

This study uses the cyclical frequency to develop the mathematical relationship between hydraulic diffusivity and spectral density functions calculated from groundwater level variation. Such relationship can be applied to (1) unsteady state, one-dimensional confined aquifer with time-dependent water level on both end boundaries, and (2) linearized unconfined aquifer with or without vertical recharge. The spectral density functions of groundwater fluctuations are largely affected by the spectral density functions obtained from time-dependent end boundaries and their cross-spectral density functions. Hydraulic diffusivity of an aquifer can be solved by type-curve matching technique at a specified frequency band under the conditions of (1) confined aquifer having equal time-dependent boundaries on both ends, (2) unconfined aquifer having equal time-dependent boundaries on both ends with surface recharge, and (3) unconfined aquifer subjected to surface recharge but neglecting the water table fluctuations on both end boundaries.  相似文献   

Temperature and Pressure Dependencies of Thermal Transport Properties of Rocks: Implications for Uncertainties in Thermal Lithosphere Models and new Laboratory Measurements of High-Grade Rocks in the Central Fennoscandian Shield     

I.T. Kukkonen  J. Jokinen  U. Seipold 《Surveys in Geophysics》1999,20(1):33-59

Measurements on thermal conductivity and diffusivity as functions of temperature (up to 1150 K) and pressure (up to 1000 MPa) are presented for Archaean and Proterozoic mafic high-grade rocks metamorphosed in middle and lower crustal pressures, and situated in eastern Finland, central Fennoscandian Shield. Decrease of 12–20% in conductivity and 40–55% in diffusivity was recorded between room temperature and 1150 K, which can be considered as typical of phonon conductivity. Radiative heat transfer effects were not detected in these samples. Pressure dependencies of the samples are weak if compared to crystalline rocks in general, but relatively typical for mafic rocks.The temperature and pressure dependencies of thermal transport properties (data from literature and the present study) were applied in an uncertainty analysis of lithospheric conductive thermal modellings with random (Monte Carlo) simulations using a 4-layer model representative of shield lithosphere. Model parameters were varied according to predetermined probability functions and standard deviations were calculated for lithospheric temperature and heat flow density after 1500 independent simulations. The results suggest that the variations (uncertainties) in calculated temperature and heat flow density values due to variations in the temperature and pressure dependencies of conductivity are minor in comparison to the effects produced by typical variations in the room temperature value of conductivity, heat production rate or lower boundary condition values.  相似文献   

南海北部中深层细结构混合研究   总被引：1，自引：0，他引：1  

卢著敏  陈桂英  尚晓东 《热带海洋学报》2009,28(3):21-28

基于2007年8月获得的ADCP（声学多普勒流速剖面仪）海流资料和CTD（温盐深剖面仪）水文资料,应用Gregg模型对南海中深层内波尺度的混合进行估计,同时应用Thorpe尺度对中深层存在的垂向翻转及由此引起的混合进一步分析。两种方法均显示,吕宋海峡附近上层400m的耗散率及混合率均强于18°N断面,中深层两个区域的混合率并没有显著区别。这表明吕宋海峡上层400m,可能存在更活跃的内波活动,从而产生更强的内波混合和垂向水团翻转。Gregg模型估计的耗散率和混合率量级分别为10^-9W·kg^-1和10^-6m^2·s^-1。大部分CTD站位在中深层均存在垂向翻转,而且保持较高的发生率,翻转所对应的混合率并不随深度增加而减小。以上南海北部的细结构混合特征增强对南海中深层混合的认识。  相似文献   

Determining thermal diffusivity using near‐surface periodic temperature variations and its implications for tracing groundwater movement at the eastern margin of the Tibetan Plateau     

Qiongying Liu  Shunyun Chen  Liangwen Jiang  Dong Wang  Zhuzhuan Yang  Lichun Chen 《水文研究》2019,33(8):1276-1286

The thermal diffusivity is the key parameter that controls near‐surface temperature where periodic temperature variation is progressively attenuated and delayed with depth. This article presents the results of apparent thermal diffusivity using temperatures recorded by a bedrock temperature measurement network in the fault zones of western Sichuan. High sensitivity temperature sensors (10^?4 K) were installed at a maximum depth reaching 30 m. The apparent thermal diffusivities were deduced from both amplitude damping and phase shifting of annual temperature variations between two different depths. Under pure conduction, the thermal diffusivity determined through the phase method (α_Φ) should be equivalent to that determined through the amplitude method (α_A), whereas effects of the upward (downward) water flow are evidently reflected in the amplitude decay to make α_Φ larger (lesser) than α_A. The discrepancy between α_Φ and α_A can thus be a tracer of water movement or convective heat transfer. The calculated α_Φ of the measurement stations varies from 1.22 × 10^?6 to 3.00 × 10^?6 m²/s, and the estimated α_A ranges from 0.93 × 10^?6 to 2.41 × 10^?6 m²/s. Two regimes of heat transfer underground were suggested from the results. Conductive heat transport prevails over the nonconductive processes at five stations, which is characterized by α_Φ coincident with α_A for the same depth pair. On the contrary, the values of α_Φ differ from α_A at six stations in the intersection area of the Y‐shaped fault system, implying that convective heat transfer also plays a comparably important role. This finding is consistent with the hot springs distribution of the area. The results also indicate that water moves upward with an average Darcy velocity of approximately ?1 × 10^?7 m/s in this region. Our research provides new evidence for the hydrothermal activity in the fault zones at the eastern margin of the Tibetan Plateau.  相似文献   

Transport properties of high albite crystals,near-endmember feldspar and pyroxene glasses,and their melts to high temperature     

Anne M. Hofmeister  Alan G. Whittington  Maik Pertermann 《Contributions to Mineralogy and Petrology》2009,158(3):381-400

Thermal diffusivity (D) was measured using laser-flash analysis (LFA) from oriented single-crystal albite and glasses near LiAlSi₃O₈, NaAlSi₃O₈, CaAl₂Si₂O₈, LiAlSi₂O₆ and CaMgSi₂O₆ compositions. Viscosity measurements of the supercooled liquids, over 2.6 × 10⁸ to 8.9 × 10¹² Pa s, confirm strongly non-Arrhenian behavior for CaAl₂Si₂O₈, and CaMgSi₂O₆, and near-Arrhenian behavior for the others. As T increases, D _glass decreases, approaching a constant near 1,000 K. Upon crossing the glass transition, D decreases rapidly. For feldspars, D for the melt is ~15% below D of the bulk crystal, whereas for pyroxenes, this difference is ~40%. Thermal conductivity (k _lat = ρC _P D) of crystals decreases with increasing T, but k _lat of glasses increases with T because heat capacity (C _P ) increases with T more strongly than density (ρ) and D decrease. For feldspars, k _lat for the melt is ~10% below that of the bulk crystal or glass, whereas this decrease for pyroxene is ~50%. Therefore, melting substantially impedes heat transport, providing positive thermal feedback that could promote further melting.  相似文献