钙镁硅酸盐系列结晶釉的研究——氧硅比对析晶种属的影响   总被引：2，自引：0，他引：2  

俞平利  吴季怀  张樵英 《矿物学报》2001,21(3):477-480

针对K2O－Na2O-CaO-MgO-Al2O3-SiO2系统，选定CaO/MgO值近于1和0．5，配制釉式中碱性组分、氧化铝含量确定的两组结晶釉，研究氧硅比对矿物种属的影响。结果显示：CaO/MgO≈1时，O／Si值近于3．1时析出钙镁黄长石，在3左右同时出现黄长石和透辉石，小于3为透辉石，继续减小开始产生少量硅灰石；CaO/MgO≈0．5时，O／Si值大于3．1时同时形成钙镁黄长石和透辉石，近于3时仅出现透辉石。  相似文献   

Routine Control of Accuracy in Silicate Rock Analysis by X-Ray Fluorescence Spectrometry     

Maria Aparecida Vendemiatto  Jacinta Enzweiler 《Geostandards and Geoanalytical Research》2001,25(2-3):283-291

In this study, we used the modified Horwitz expression (H_c= 0.01c^0.8495, which gives the precision as a function of concentration) to evaluate and control the accuracy of results of silicate rock analysis obtained by X-ray fluorescence spectrometry. This expression is currently used by the organisers of the GeoPT international proficiency tests, to assign the precision limits of each analyte and subsequently to evaluate the data provided by laboratories whose main application is geochemistry. Results for major and trace elements, determined in glass disk and pressed pellets, respectively, were evaluated. Nine international silicate rock reference materials were analysed and results were compared to the recommended values plus and minus the limits given by the above expression. Those limits are easily attained for most major elements, but not for trace elements. Sample preparation and sub-sampling contributions to precision were evaluated by analysis of an in-house reference sample. In our results, precision does not follow the Horwitz expression relationship with concentration. It is known that the final accuracy in XRF analysis depends strongly on instrumental settings and on the uncertainties associated with the certified or recommended values of the reference materials used to calibrate the spectrometer, but our results indicate that the precision expression can be useful, especially to inspect and correct calibration curves and to check routine instrumental accuracy.  相似文献   

Experimental Study Assessing the Role of Sedimentary Organic Materials to Control the Redox State of Ground Materials to Control the Redox State of Groundwater: Consumption of Dissolved Oxygen by Humic Acid     

Ken-ichiro Haysahi    Hideyuki Shibata    Mikazu Yui  Hiroshi Ohmoto 《Resource Geology》2001,51(1):45-54

Abstract: A total of 189 runs were completed to determine the rate of dissolved oxygen consumption in water by the reaction humic acid at 25°, 45°, and 65°C. Glass vial bottles were used as reaction vessels, and humic aicd and pure water of different intitial O₂ concentration was loaded with humic acid/water weight of 0.008 and 0.009. Vials were opened periodically to measure O₂ concentrations. The pH of the solution fluctuated in the early stages of the experiments and gradually decreased to a constant value. Dissolved oxygen concentration decreased, for example, from initial value of 12 mg/l to 9 mg/l at 25°C, to 5 mg/l at 45°C, and to 2 mg/l at 65°C after the reaction of 500 hours. Analyses of rates suggest that the reaction is first order, and rate constants are 8.42 × 10^-9 at 25°C, 2.22 × 10^-8 at 45°C, and 1.28 × 10^-7 moles m^-2 s^-1 at 65°C.  相似文献   

陕西省蓝田县灞河谷地饮用天然矿泉水资源特征及开发利用条件     

肖平新 《陕西地质》1991,(1)

蓝田县灞河谷地是最近查明的一个饮用天然矿泉水集中区,已发现16处矿泉水。本文从这些矿泉水产出的地质—水文地质条件,分析了矿泉水的分布规律,进而论述了矿泉水水质、水量特征和可开采资源的保证程度,并对矿泉点的开发利用条件进行了多因素综合评价。  相似文献   

水平式ICP—AES测定岩石中痕量铍,铬,锰,钒和锆     

毛启佑  杨云 《矿物岩石》1991,11(3):103-106

用HNO_3—HCLO_4—HF混合酸,加压分解试样,以水平式ICP—AES可同时测定岩石中痕量铍、铬、锰、钒和锆。方法简单、现性好、准确度高。Bc,Cr,Mn,V,Zr的检出限分别为0.0001,0.002,0.002,0.002,0.005mg/ml,变异系数均小于5％。结果令人满意。  相似文献   

Major ion chemistry of the Ganga source waters: Weathering in the high altitude Himalaya   总被引：2，自引：0，他引：2  

M. M. Sarin  S. Krishnaswami  J. R. Trivedi  K. K. Sharma 《Journal of Earth System Science》1992,101(1):89-98

A systematic study of the major ion chemistry of the Ganga source waters—the Bhagirathi, Alaknanda and their tributaries—has been carried out to assess the chemical weathering processes in the high altitude Himalaya. Among major ions, Ca, Mg, HCO₃ and SO₄ are the most abundant in these river waters. These results suggest that weathering of carbonate rocks by carbonic and sulphuric acids dominates in these drainage basins. On an average, silicate weathering can contribute up to ∼ 30% of the total cations. The concentration of total dissolved salts in the Bhagirathi and the Alaknanda is 104 and 115mg/l, respectively. The chemical denudation rate in the drainage basins of the Bhagirathi and the Alaknanda is, respectively, 110 and 137 tons/km²/yr, significantly higher than that derived for the entire Ganga basin, indicating intense chemical erosion of the Himalaya.  相似文献   

Diatom assemblages from Adirondack lakes (New York,USA) and the development of inference models for retrospective environmental assessment   总被引：5，自引：0，他引：5  

Sushil S. Dixit  Brian F. Cumming  H. J. B. Birks  John P. Smol  John C. Kingston  Allen J. Uutala  Donald F. Charles  Keith E. Camburn 《Journal of Paleolimnology》1993,8(1):27-47

Detrended canonical coreespondence analysis (DCCA) was used to examine the relationships between diatom species distributions and environmental variables from 62 drainage lakes in the Adirondack region, New York (USA). The contribution of lakewater pH, Al_m (monomeric Al), NH₄, maximum depth, Mg, and DOC (dissolved organic carbon) were statistically significant in explaining the patterns of variation in the diatom species composition. Twenty-three and sixteen diatom taxa were identified as potential indicator species for pH and Al_m, respectively (i.e. a taxon with a strong statistical relationship to the environmental variable of interest, a well defined optimum, and a narrow tolerance to the variable of interest). Using weighted-averaging regression and calibration, predictive models were developed to infer lakewater pH (r ²=0.91), Al_m (r ²=0.83), DOC (dissolved organic carbon) (r ²=0.64), and ANC (acid neutralizing capacity; r ²=0.90). These variables are of key importance in understanding watershed acidification processes. These predictive models have been used in the PIRLA-II (Paleoecological Investigation of Recent Lake Acidification-II) project to answer policy-related questions concerning acidification, recovery, and fisheries loss.  相似文献   

Dissolved oxygen in the Dead Sea— seasonal changes during the holomictic stage     

Michal Shatkay  David A. Anati  Joel R. Gat 《International Journal of Salt Lake Research》1993,2(2):93-110

Measurements of dissolved oxygen, density and temperature were con ducted in the Dead Sea between August 1987 and December 1989. Oxygen concentrations were found to vary around an average value of 0.8 mlSTP (standard temperature and pressure) per kg. Dissolved oxygen variations were found to reflect both physical processes (a deepening of the epilimnion, a turnover etc.) and chemical processes (oxidation reduction). Transport coefficients for the oxygen exchange across the air/sea interface were found to be generally low compared to expected values based on laboratory experiments; the presence of surface films which inhibit the gas exchange rates under calm weather conditions is suspected. During stormy weather, the exchange rates were considerably higher, suggesting that the entrainment of bubbles was involved in the gas exchange process. Contribution No. 95, Department of Environmental Sciences and Energy Research. The Weizmann Institute of Science  相似文献   

Significance of bacteria in carbon fluxes in the Arabian Sea     

Farooq Azam  Grieg F. Steward  David C. Smith  Hugh W. Ducklow 《Journal of Earth System Science》1994,103(2):341-351

In the Arabian Sea, temporal contiguity of highly oligotrophic and eutrophic periods, along with high water temperatures, may result in unique features of bacteriaorganic matter coupling, nutrient cycling and sedimentation, which are unlike those in the classical oligotrophic and eutrophic waters. Bacteria-phytoplankton interactions are suggested to influence phytoplankton aggregation and its timing. It is also hypothesized that, within aggregates, hydrolytic ectoenzyme activity, together with condensation reactions between the hydrolysis products, produce molecular species which are not readily degraded by pelagic bacteria. Accumulation of a reservoir of such slow-to-degrade dissolved organic carbon (DOC) is proposed to be a carbon flux and energy buffer, which moderates the response of bacteria to the dramatic variations in primary production in the Arabian Sea. Use of the slow-to-degrade DOC pool during the intermonsoon could temporarily render the Arabian Sea net-heterotrophic and a source of CO₂ to the atmosphere. Stored DOC is also suggested to balance the observed deficit between mesopelagic carbon demand and the sinking particulate organic carbon supply. Knowledge of the significance of bacteria in carbon storage and cycling in the Arabian Sea is needed to understand the response of the ocean’s biogeochemical state to strong physical forcing and climate change.  相似文献   

我国首次发现的硅钾铀矿     

薄崇俭 《矿物学报》1990,10(2):157-160

硅钾铀矿属罕见的次生铀矿物,1986年我国首次发现于甘肃龙首山铀矿床氧化。带。对该矿物进行了多种测试工作。矿物为层状结构的铀酰硅酸盐矿物。晶胞参数a=6.62,b=7.03,c=7.06,β=105.2°。化学式:(K_(0·58) Na_(0·33)0.91(H_3O)[UO_2SiO_4]·0.8H_2O  相似文献