PHP——NKHm泥浆水敏性地层中的应用     

贺晓东 《中国煤炭地质》2008,(5):72-74

长城窝堡井田内施工的油田参数井,地层复杂,工艺要求高,其白垩系泉头组的灰紫色泥岩易水化膨胀,是重点防御井段;第四系平原组,主要以灰黄色细砂层为主,浅灰色不等粒砂层次之,此层难度在于护壁和防塌。为此选择降失水性能高、且具有较低粘度的CPAN作为降失水剂,选择阴离子型、分子量300～500,水解度为30％的聚丙烯酰胺（PHP）作为絮凝剂。将处理剂进行复配,并做一系列的抗泥侵、防塌等试验对比工作,最终选定PHP-CPAN-NKHM高聚物泥浆配方。通过白20号参数井和生产实践,证明该配方在水敏性地层的应用效果比较显著。  相似文献   

外源水和外源酸对万华岩地下河系统岩溶碳汇效应的影响     

刘朋雨  张连凯  黄奇波  覃小群 《中国岩溶》2020,39(1):17-23

流域的岩石化学风化过程是全球碳循环中的重要环节。近年来流域水化学碳汇通量估算已越来越多地关注到外源水(硅酸盐风化)及外源酸对全球碳循环的影响。文章选取万华岩地下河流域为研究区,流域硅酸盐岩和碳酸盐岩分布面积占比为64%和36%,于2017年对洞口进行为期一年的取样监测,并分别于4月和9月对万华岩地下河系统内13个水点的离子组成进行监测,利用水化学平衡法和Galy模型,对流域岩石化学风化速率和CO2消耗通量进行了计算,对万华岩地下河系统的岩石风化和碳循环过程进行了分析。结果表明,万华岩地下河系统岩石风化消耗CO2的速率为31.02 t·(km2·a)-1;以碳酸岩风化为主,其风化速率为硅酸盐溶蚀的20倍;流域内碳酸盐岩风化对CO2消耗量占到整个流域的92.16%;不同岩石风化类型对碳通量的贡献率以碳酸溶解碳酸盐岩最大,为87.06%;流域上游的外源水对岩溶碳汇具有巨大的促进作用,外源水汇入后碳酸盐岩碳汇速率可以达到无外源水汇入流域的2倍;硫酸溶解碳酸盐岩次之,为9.24%;碳酸风化硅酸盐岩最小,为3.7%,在计算流域碳汇量的时候应将硫酸参与岩石风化的影响去除。  相似文献   

镁铝对烧结矿中铁酸钙的矿物学特性影响     

韩秀丽  司天航  李鸣铎  周祥  刘磊  赵凯 《地学前缘》2020,27(5):280-290

铁酸钙是高碱度烧结矿中的主要黏结相矿物,它的含量、结晶形态、化学成分及晶体结构等矿物学特性对烧结矿质量起着关键性作用,而烧结原料中各组分的含量直接影响着铁酸钙的生成。以Fe₃O₄、SiO₂、CaO、MgO、Al₂O₃的化学纯试剂为原料,在实验室进行微型烧结实验,运用XRD、偏光显微镜、电子探针等手段,定量分析研究了原料组分中MgO、Al₂O₃对烧结矿中铁酸钙的生成及其矿物学特性的影响。原料中MgO含量的增加对铁酸钙的生成有一定抑制作用,尤其在MgO含量为2.0%~3.0%时,烧结矿中铁酸钙含量明显减少,其晶体形态也从以板柱状和针状为主逐渐过渡为它形不规则状;原料中Al₂O₃的增加,对烧结矿中铁酸钙的形成具有促进作用,即随着Al₂O₃的增加铁酸钙含量呈明显增加趋势,且铁酸钙的形态也由以柱状和针状为主向板柱状变化。电子探针成分分析及矿物化学式计算结果表明,铁酸钙是由Fe₂O₃、CaO、SiO₂、Al₂O₃及MgO组成的复杂结晶体,其化学通式为Ca_2.60Mg_0.44Si_1.07Al_0.96Fe_8.92O₂₀。原料中MgO、Al₂O₃含量的变化,对铁酸钙的化学成分中Fe₂O₃/CaO摩尔分数比影响不大,均接近3∶2。上述研究结果对于深刻理解烧结工艺条件下铁酸钙晶相的晶体化学特征及其对烧结矿质量的影响具有重要指导意义。  相似文献   

多组分有机质作用下碳酸钙的矿化现象     

王旭辉  董发勤  李琼芳  潘玲  宋娜  于璐嘉 《岩石矿物学杂志》2020,39(3):291-297

采用SEM、XRD、FT-IR等手段对氨基酸、多糖以及有机酸混合体系中形成的碳酸钙晶体进行了表征,进而比较了多组分有机质作用下碳酸钙的矿化现象。结果表明,氨基酸-单糖体系(A-M)促进了碳酸钙的沉积,其钙化速率相较于对照组提高了36%;有机酸则抑制了碳酸钙的沉积,单糖-有机酸体系(M-O)、氨基酸-有机酸体系(A-O)和氨基酸-有机酸-单糖体系(A-O-M)的钙化速率分别下降了33%、29%、17%。其次,A-M体系合成的晶体以方解石为主,包含少量的球霰石,M-O、A-O和A-O-M体系则在柠檬酸的调控下合成了方解石。最后,A-M体系合成了块状晶体(粒径为10μm)及中空的环状晶体(粒径为5μm),而A-O和M-O体系合成了棒状晶体(长轴径5～15μm,短轴径3～5μm)。A-O-M体系存在含量最高的有机质,导致成核速率高于生长速率,因此合成的晶体呈粒状(粒径1～3μm)且发育不完整。研究揭示了多组分共存体系中的生物矿化现象,阐明了柠檬酸在多组分体系中对晶体成核及生长的主导调控作用,对研究黄龙高寒环境下的生物矿化机制具有重要意义。  相似文献   

含碳酸盐混合砂的三轴剪切试验研究     

李小刚  朱长歧  崔翔  张珀瑜  王睿 《岩土力学》2020,41(1):123-131

含碳酸盐混合砂作为一种特殊的岩土材料主要分布于热带沿海地区,独特的成因和组构使得其具有不同于陆源砂的岩土工程特性。针对取自我国南海的珊瑚砂与取自长江流域石英砂按不同质量百分比配制而成的混合砂,开展不同围压下的三轴固结排水剪切试验,研究不同碳酸钙含量混合砂的剪切特性。结果表明：（1）混合砂峰值强度随有效围压和碳酸钙含量的增加呈近似线性增长;（2）围压及碳酸含量是影响混合砂剪胀特性的主要参数,随着碳酸盐含量的增加,胀缩转换点及其对应的轴向应变量增大;（3）随着碳酸盐含量的增加,混合砂的黏聚力呈线性增加趋势,峰值内摩擦角?f缓慢增长;（4）混合砂的相对破碎率Br随碳酸钙含量及围压的增加而增加。  相似文献   

δCa evolution in a carbonate aquifer and its bearing on the equilibrium isotope fractionation factor for calcite     

Andrew D. Jacobson  Chris Holmden 《Earth and Planetary Science Letters》2008,270(3-4):349-353

To improve understanding of Ca isotope transport during water-rock interaction on the continents, we measured dissolved δ⁴⁴Ca values along a 236 km flow path in the Madison aquifer, South Dakota, where fluids have chemically evolved according to dolomite and anhydrite dissolution, calcite precipitation, and Ca-for-Na ion-exchange over a timescale spanning ~ 15 kyr. We used a reactive transport model employing rate data constrained from major ion mass-balances to evaluate the extent to which calcite precipitation and ion-exchange fractionate Ca isotopes. Elevated δ⁴⁴Ca values during the initial and final stages of water transport possibly result from calcite precipitation under supersaturated conditions and Ca-for-Na ion-exchange, respectively. However, for the bulk of the flow path, δ⁴⁴Ca values evolve by mixing between anhydrite and dolomite dissolution, with no fractionation during calcite precipitation under saturated conditions. We attribute the absence of Ca isotope fractionation to the long timescale of water-rock interaction and slow rate of calcite precipitation, which have enabled fluids to chemically and isotopically equilibrate with calcite. We therefore conclude that the equilibrium Ca isotope fractionation factor between calcite and water (Δ_cal–w) is very close to zero. To the extent that the Madison aquifer typifies other groundwater systems where calcite slowly precipitates from solutions at or near chemical equilibrium, this study suggests that groundwater contributions to δ⁴⁴Ca variability on the continents can be modeled according to simple mixing theory without invoking isotope discrimination.  相似文献   

过氧化钙在处理厌氧底泥中的应用初探   总被引：1，自引：0，他引：1  

张启超  杨鑫  孙淑雲  古小治  陈开宁 《湖泊科学》2015,27(6):1087-1092

为改善河道厌氧底质及内源氮、磷等营养盐释放问题,考察对沉水植被恢复的影响,研发可同步解决沉积物供氧和削减内源氮、磷释放的氧缓释材料.实验通过向沉积物-水界面处散点注射不同剂量的过氧化钙(Ca O2),研究界面处溶解氧的动态变化特征及表层沉积物与底层水体之间溶解态氮、磷的交换过程.结果表明:添加Ca O2显著提高了界面处底层上覆水溶解氧浓度,随着Ca O2浓度的增加溶解氧浓度增加,不同处理组之间具有显著差异;Ca O2对沉积物中PO3-4-P释放具有明显的抑制作用,且随Ca O2浓度的增加抑制效果愈加明显,上覆水中可溶性活性磷浓度最大可削减98%.实验开始时,磷释放速率可降至-241.916±22.501 mg/(m2·d),降幅最高可达到144%;Ca O2对沉积物NH+4-N释放的抑制效果不佳,上覆水中NH+4-N浓度随着时间的变化波动性较大,且有逐渐增大的趋势.另外,添加Ca O2会显著提高底层上覆水p H值,不同处理组之间差异显著,但当Ca O2投加量小于0.529 kg/m2时,不会对苦草种子的萌发生长有显著影响,p H值波动在可接受范围内(7.62~10.87).因此,结合污染沉积物的状况,适当地投加Ca O2有望同步解决底质厌氧、内源磷释放及后期沉水植被定植底质生境改善的问题,可推荐为一种黑臭污染底泥治理技术在实际的河道生态工程中应用,其适宜浓度为0.176 kg/m2左右.  相似文献   

Characterizing infiltration and internal drainage of South African dryland soils          下载免费PDF全文

Sabelo S.W. Mavimbela  Leon D. van Rensburg 《地球表面变化过程与地形》2017,42(3):414-425

Surface infiltration and internal drainage properties of five soil types from arid drylands of South Africa were studied under double ring infiltrometer, rainfall simulation plots (1 m²) and instantaneous drainage plots (9 m²). Changes in soil water content during 40 minute rainfall simulation for a rainstorm with average intensity of 1.61 mm min^?1 and 30 day drainage period were measured at various depths by 1.5 m long capacitance soil water measuring (DFM) probe. Different (P < 0.05) mean surface steady infiltration rate ranged from 0.05 to 4.47 mm min^?1 and had a negative power relationship (R ² = 0.65) with horizon clay plus fine silt content. Power regression (R ² ≥ 86%) described rainstorm infiltration and obtained steady rates within an average time of 15 minutes. Mean total infiltrated soil water content was lowest (P < 0.05) from surface horizons with either 47.7% clay plus fine silt content or bulk density of 1.91 g cm^?3 and exchangeable sodium of not less than 44 mg kg^?1. Surface horizons with lower surface bulk density and total sand fraction of more than 72% had infiltrated depth and mean total infiltrated soil water content up to 40 cm deeper and 0.55 mm mm^?1 greater, respectively. Drainage rate at drained upper limit calculated from the Wilcox drainage model (R ² ≤ 0.97%) was 0.2 mm day^?1 or less were from underlying horizons with either clay plus fine silt of 45% or soft calcium carbonate. Higher drainage rate with accumulative drainage amount greater than 60 mm were from soil profile horizons with clay plus fine silt content of less than 20% and above unity steady infiltration rates. Rainstorm infiltration and drainage rates was shown to depend on permeability and coarseness of the respective soil surface and subsurface horizons; a phenomenon critical for harnessing rain and flood water to recharge groundwater. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

四川大行大理石矿性能及其综合利用研究     

陈安清  徐胜林  曹珂 《地质与资源》2006,15(4):290-294

四川大行大理石矿地处扬子古板块西缘磨西韧性剪切带的构造岩片中,矿体出露于下二叠统上段,储量达中型矿床规模.对矿石的物理性能和化学性能的研究认为,该矿矿石品质良好,符合国际标准和行业标准.其综合开发利用主要包括饰面板材、碳酸钙填料、雕塑工艺品和异型石材等,有利于取得资源、经济、环境、社会的综合效益.  相似文献   

Time series prediction of mooring line top tension by the NARX and Volterra model     

《Applied Ocean Research》2019

To minimize the computation burdens of long-term analysis, the mooring line top tensions under various short-term sea states were predicted using the pre-calculated nonlinear time domain analysis results of some selected sea states. A nonlinear autoregressive with an exogenous input (NARX) technique was introduced with a finite nonlinear memory length to predict the top-tension of a mooring line of the box-type floating production storage and offloading (FPSO). The NARX was designed in such a way that it takes the floater’s motions as its input and produces the mooring line top tension as an output. After training the NARX using the pre-calculated time series of the motions and tensions of some selected sea states, the tension time histories of different sea sates were predicted and compared with the direct time domain analysis results. In addition, to explore the nonlinearity of the system and its contribution to the response, the transfer functions of different orders were extracted after expanding the NARX equation using a Taylor series expansion. The nonlinear contributions coming from both the 3^rd and 5^th order were significant.  相似文献