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91.
KADIK A.; PINEAU F.; LITVIN Y.; JENDRZEJEWSKI N.; MARTINEZ I.; JAVOY M. 《Journal of Petrology》2004,45(7):1297-1310
Studies of iron-bearing silicate melt (ferrobasalt) + iron metallicphase + graphite + hydrogen equilibria show that carbon andhydrogen solubilities in melts are important for the evolutionof the upper mantle. In a series of experiments conducted at3·7 GPa and 15201600°C, we have characterizedthe nature (oxidized vs reduced) and quantified the abundancesof C- and H-compounds dissolved in iron-bearing silicate melts.Experiments were carried out in an anvil-with-hole apparatuspermitting the achievement of equal chemical potentials of H2in the inner Pt capsule and outer furnace assembly. The fO2for silicate meltiron equilibrium was 2·32 ±0·04 log units below ironwüstite (IW). Theferrobasalt used as starting material experienced a reductionof its iron oxides and silicate network. The counterpart wasa liberation of oxygen reacting with the hydrogen entering thecapsule. The amount of H2O dissolved in the glasses was measuredby ion microprobe and by step-heating and was found to be between1 and 2 wt %. The dissolved carbon content was found to be 1600ppm C by step-heating. The speciation of C and H componentswas determined by IR and Raman spectroscopy. It was establishedthat the main part of the liberated oxygen was used to formOH and to a much lesser extent H2O, and only traces ofH2, CO2 and 相似文献
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An experimental study on reduction of U (Ⅵ) by anaerobic bacteria, Shewane//a putrefaciens, is first reported here in China. The experimental conditions were: 35℃ and pH =7.0-7.4, corresponding to a physicochemical environments in which the sandstone-hosted interlayer oxidation-zone type uranium deposit formed in Northwest China's Xinjiang. Bacteria adopted in the present experiment, Shewanella putrefaciens, occur extensively in natural environment. Our study shows that nano-crystal precipitates of uraninite quickly occurred on the surface of the cells within one week. It was found that the pitchblende was characterized by a random arrangement of uraninite nanocrystals (2-4 nm) in it, significantly different from natural pitchblende in which uraninite nanocrystals are arranged in order. Finally, a possible mechanism of uranium biomineralization by microorganisms in the deposits is discussed. Our investigation may supply a technical train of thoughts for bioremediation of nuclear-contaminated water environments and for underground dissolving extraction of the sandstone-hosted uranium ores. 相似文献
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Olivier Regnault Vincent Lagneau Hubert Catalette Hélène Schneider 《Comptes Rendus Geoscience》2005,337(15):1331-1339
Carbon dioxide sequestration in deep aquifers and depleted oilfields is a potential technical solution for reducing green-house gas release to the atmosphere: the gas containment relies on several trapping mechanisms (supercritical CO2, CO2(sc), dissolution together with slow water flows, mineral trapping) and on a low permeability cap-rock to prevent CO2(sc), which is less dense than the formation water, from leaking upwards. A leakproof cap-rock is thus essential to ensure the sequestration efficiency. It is also crucial for safety assessment to identify and assess potential alteration processes that may damage the cap-rock properties: chemical alteration, fracture reactivation, degradation of injection borehole seals, etc. The reactivity of the host-rock minerals with the supercritical CO2 fluid is one of the potential mechanisms, but it is altogether unknown. Reactivity tests have been carried out under such conditions, consisting of batch reactions between pure minerals and anhydrous supercritical CO2, or a two-phase CO2/H2O fluid at 200?°C and 105/160 bar. After 45 to 60 days, evidence of appreciable mineral-fluid reactivity was identified, including in the water-free experiments. For the mixed H2O/CO2 experiments, portlandite was totally transformed into calcite; anorthite displayed many dissolution patterns associated with calcite, aragonite, tridymite and smectite precipitations. For the anhydrous CO2 experiments, portlandite was totally carbonated to form calcite and aragonite; anorthite also displayed surface alteration patterns with secondary precipitation of fibrous calcite. To cite this article: O. Regnault et al., C. R. Geoscience 337 (2005). 相似文献
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胡志毅 《云南地理环境研究》2005,17(Z1):26-28
随着西部大开发战略的深入实施,如何全面认识旅游业对西部经济落后地区经济的影响,成为旅游学界关注的热点问题之一。通过对石林县社会经济统计数据的综合分析以及实地调研,证实了旅游业对促进石林县国民经济总量扩大、推动产业结构高级化和带动相关产业发展等方面具有积极作用。同时,针对当前石林旅游内部结构和发展质量中存在的旅游产品单一、景区发展失衡和社区受益不足等主要问题,提出了以推动区域经济总体发展和带动农村居民脱贫作为旅游发展的两大基本任务和实现旅游产业增长模式从数量型向内涵型增长转变的基本思路,以及相应的对策。 相似文献
99.
Effects of forest roads on the hydrological response of a small‐scale mountain watershed in Greece 下载免费PDF全文
The effects of land use changes on the ecology and hydrology of natural watersheds have long been debated. However, less attention has been given to the hydrological effects of forest roads. Although less studied, several researchers have claimed that streamflow changes related to forest roads can cause a persistent and pervasive effect on hillslope hydrology and the functioning of the channel system. The main potential direct effects of forest roads on natural watersheds hydrologic response are runoff production on roads surfaces due to reduced infiltration rates, interruption of subsurface flow by road cutslopes and rapid transfer of the produced runoff to the stream network through roadside ditches. The aforementioned effects may significantly modify the total volume and timing of the hillslope flow to the stream network. This study uses detailed field data, spatial data, hydro‐meteorological records, as well as numerical simulation to investigate the effects of forest roads on the hydrological response of a small‐scale mountain experimental watershed, which is situated in the east side of Penteli Mountain, Attica, Greece. The results of this study highlight the possible effects of forest roads on the watersheds hydrological response that may significantly influence direct runoff depths and peak flow rates. It is demonstrated that these effects can be very important in permeable watersheds and that more emphasis should be given on the impact of roads on the watersheds hydrological response. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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Giulia Zuecco Chiara Marchina Ylenia Gelmini Anam Amin H. J. van Meerveld Daniele Penna Marco Borga 《水文研究》2021,35(3):e14095
Ressi is a small (2.4 ha) forested catchment located in the Italian pre-Alps. The site became an experimental catchment to investigate the water fluxes in the soil–plant–atmosphere continuum and the impact of vegetation on runoff generation in 2012. The elevation of the catchment ranges from 598 to 721 m a.s.l. and the climate is humid temperate. The bedrock consists of rhyolites and dacites; the soil is a Cambisol. The catchment is covered by a dense forest, dominated by beech, chestnut, maple, and hazel trees. The field set up includes measurements of the rainfall in an open area, streamflow at the outlet, soil moisture at various depths and locations, and depth to water table in six piezometers at a 5- or 10-min interval. Samples of precipitation, stream water, shallow groundwater and soil water are collected monthly for tracer analysis (stable isotopes (2H and 18O), electrical conductivity and major ions), and during selected rainfall–runoff events to determine the contribution of the various sources to runoff. Since 2017, soil and plant water samples have been collected to determine the sources of tree transpiration. Data collected in the period 2012–2016 are publicly available. Data collection is ongoing, and the data set is expected to be updated on an annual basis to include the most recent measurements. 相似文献