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11.
A model is proposed for the formation of water ice mantles on grains in interstellar clouds. This occurs by direct accretion of monomers from the gas, be they formed by gas or surface reactions. The formation of the first monolayer requires a minimum extinction of interstellar radiation, sufficient to lower the grain temperature to the point where thermal evaporation of monomers is just offset by monomer accretion from the gas. This threshold is mainly determined by the adsorption energy of water molecules on the grain material; for hydrocarbon material, chemical simulation places this energy between 0.5 and 2 kcal mol−1, which sets the (true) visible extinction threshold at a few magnitudes. However, realistic distributions of matter in a cloud will usually add to this an unrelated amount of cloud core extinction, which can explain the large dispersion of observed (apparent) thresholds. Once the threshold is crossed, all available water molecules in the gas are quickly adsorbed, because the grain cools down and the adsorption energy on ice is higher than on bare grain. The relative thickness of the mantle, and, hence, the slope of  τ3( A v)  depend only on the available water vapour, which is a small fraction of the oxygen abundance. Chemical simulation was also used to determine the adsorption sites and energies of O and OH on hydrocarbons and study the dynamics of formation of water molecules by surface reactions with gaseous H atoms, as well as their chances to stick in situ.  相似文献   
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The hypothesis of an extended red emission (ERE) in diffuse Galactic light (DGL) has been put forward in 1998 by Gordon, Witt & Friedmann who found that scattered starlight was not enough to explain the amount of DGL in the R band, in some high Galactic latitude directions. This paper re-investigates, for high Galactic latitudes, the brightnesses and colours of DGL, integrated star and galaxy light (ISGL), and of the total extrasolar light (ISGL+DGL) measured by Pioneer. Under the traditional assumption that DGL is forward scattering of background starlight by interstellar dust on the line of sight, ISGL and Pioneer have very close colours, as it is found by Gordon, Witt & Friedmann. Pioneer observations at high |b| thus accept an alternative and simple interpretation, with no involvement of ERE in DGL.  相似文献   
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This study explores garnet coronas around hedenbergite, which were formed by the reaction plagioclase + hedenbergite→garnet + quartz, to derive information about diffusion paths that allowed for material redistribution during reaction progress. Whereas quartz forms disconnected single grains along the garnet/hedenbergite boundaries, garnet forms ~20‐μm‐wide continuous polycrystalline rims along former plagioclase/hedenbergite phase boundaries. Individual garnet crystals are separated by low‐angle grain boundaries, which commonly form a direct link between the reaction interfaces of the plagioclase|garnet|hedenbergite succession. Compositional variations in garnet involve: (i) an overall asymmetric compositional zoning in Ca, Fe2+, Fe3+ and Al across the garnet layer; and (ii) micron‐scale compositional variations in the near‐grain boundary regions and along plagioclase/garnet phase boundaries. These compositional variations formed during garnet rim growth. Thereby, transfer of the chemical components occurred by a combination of fast‐path diffusion along grain boundaries within the garnet rim, slow diffusion through the interior of the garnet grains, and by fast diffusion along the garnet/plagioclase and the garnet/hedenbergite phase boundaries. Numerical simulation indicates that diffusion of Ca, Al and Fe2+ occurred about three to four, four and six to seven orders of magnitude faster along the grain boundaries than through the interior of the garnet grains. Fast‐path diffusion along grain boundaries contributed substantially to the bulk material transfer across the growing garnet rim. Despite the contribution of fast‐path diffusion, bulk diffusion through the garnet rim was too slow to allow for chemical equilibration of the phases involved in garnet rim formation even on a micrometre scale. Based on published garnet volume diffusion data the growth interval of a 20‐μm‐wide garnet rim is estimated at ~103–104 years at the inferred reaction conditions of 760 ± 50 °C at 7.6 kbar. Using the same parameterization of the growth law, 100‐μm‐ and 1‐mm‐thick garnet rims would grow within 105–106 and 106–107 years respectively.  相似文献   
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罗氏沼虾育苗用水中Mg2+与Ca2+含量及Mg2+/Ca2+对出苗率的影响   总被引:13,自引:0,他引:13  
1991年3-6月和1992年3-6月在南汇县东海水产养殖公司对罗氏沼虾育苗用水调配原则与不同基础水的调配方法进行试验研究。结果表明,育苗用水中Mg^2+与Ca^2+含量及Mg^2+/Ca^2+必须达到一定的范围,这是调配的基本原则。以鱼塘水作基础水时,需添加6种化学药品,其中Mg^2+与Ca^2+含量可适范围分别为300.0-440.0mg/L与170.0-244.0mg/L,Mg^2+/Ca^  相似文献   
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Low-frequency damping of a moored semisubmersible drilling platform was obtained from numerical extinction tests simulated in still water and in regular waves and from mean wave drift forces calculated at zero forward speed. The influence of drag forces was represented by the modified Morison equation. The platform as used for the 18th ITTC Comparative Mooring Study was analyzed in irregular beam waves. The computed time series of sway as well as the corresponding sway response spectrum compared favourably with model test measurements, demonstrating that this procedure to determine low-frequency damping can be effective.  相似文献   
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提出波浪作用下岸坡和海底动态和静态平衡条件的数学模型。在已建立的推移质泥沙体积输沙率基本关系式的基础上,根据连续方程,计算出底坡、泥沙、波浪三要素在动态和静态平衡情况下的关系式,得出反映这种关系的底坡平衡函数曲线图。用实际资料对这一函数曲线进行了验证,并对实际资料相对模型的某些差异作出解释。  相似文献   
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