The interlayer pores of swelling 2:1 clays provide an ideal 2-dimensional environment in which to study confined fluids. In this paper we discuss our understanding of the structure and dynamics of interlayer fluid species in expanded clays, based primarily on the outcome of recent molecular modelling and neutron scattering studies. Counterion solvation is compared with that measured in bulk solutions, and at a local level the cation-oxygen coordination is found to be remarkably similar in these two environments. However, for the monovalent ions the contribution to the first coordination shell from the clay surfaces increases with counterion radius. This gives rise to inner-sphere (surface) complexes in the case of potassium and caesium. In this context, the location of the negative clay surface charge (i.e. arising from octahedral or tetrahedral substitution) is also found to be of major importance. Divalent cations, such as calcium, eagerly solvate to form outer-sphere complexes. These complexes are able to pin adjacent clay layers together, and thereby prevent colloidal swelling. Confined water molecules form hydrogen bonds to each other and to the clays' surfaces. In this way their local environment relaxes to close to the bulk water structure within two molecular layers of the clay surface. Finally, we discuss the way in which the simple organic molecules methane, methanol and ethylene glycol behave in the interlayer region of hydrated clays. Quasi-elastic neutron scattering of isotopically labelled interlayer CH3OD and (CH2OD)2 in deuterated clay allows us to measure the diffusion of the CH3- and CH2-groups in both clay and liquid environments. We find that in both the one-layer methanol solvates and the two-layer glycol solvates the diffusion of the most mobile organic molecules is close to that in the bulk solution. 相似文献
The Chinese Continental Scientific Drilling (CCSD) main drill hole (0–3000 m) in Donghai, southern Sulu orogen, consists of eclogite, paragneiss, orthogneiss, schist and garnet peridotite. Detailed investigations of Raman, cathodoluminescence, and microprobe analyses show that zircons from most eclogites, gneisses and schists have oscillatory zoned magmatic cores with low-pressure mineral inclusions of Qtz, Pl, Kf and Ap, and a metamorphic rim with relatively uniform luminescence and eclogite-facies mineral inclusions of Grt, Omp, Phn, Coe and Rt. The chemical compositions of the UHP metamorphic mineral inclusions in zircon are similar to those from the matrix of the host rocks. Similar UHP metamorphic P–T conditions of about 770 °C and 32 kbar were estimated from coexisting minerals in zircon and in the matrix. These observations suggest that all investigated lithologies experienced a joint in situ UHP metamorphism during continental deep subduction. In rare cases, magmatic cores of zircon contain coesite and omphacite inclusions and show patchy and irregular luminescence, implying that the cores have been largely altered possibly by fluid–mineral interaction during UHP metamorphism.
Abundant H2O–CO2, H2O- or CO2-dominated fluid inclusions with low to medium salinities occur isolated or clustered in the magmatic cores of some zircons, coexisting with low-P mineral inclusions. These fluid inclusions should have been trapped during magmatic crystallization and thus as primary. Only few H2O- and/or CO2-dominated fluid inclusions were found to occur together with UHP mineral inclusions in zircons of metamorphic origin, indicating that UHP metamorphism occurred under relatively dry conditions. The diversity in fluid inclusion populations in UHP rocks from different depths suggests a closed fluid system, without large-scale fluid migration during subduction and exhumation. 相似文献
In their comment, Park & Ree have raised several points against the interpretation by Park et al. , and argued that the remagnetization in the Jeongseon area was caused by the thermal effects of a Late Cretaceous pluton and/or associated short-range hydrothermal fluids, rather than by long-range fluids advocated by us. We disagree with most points raised by Park & Ree and we make a case that these are invalid because of what we believe is incorrect geologic evidence. Hence, our model—that the fluids causing the chemical remagnetization might migrate through the fault system within the Ogcheon Fold Belt—is the most plausible scenario. We recognize that our model needs to be tested in a future study and we welcome new interpretations for or against our model based on reliable geologic or geophysical data. 相似文献
Reconstructing recent limnological history often relies on lead-210 dating to accurately ascribe a chronology to a sediment
profile. In Lake Okeechobee, Florida, a large, shallow subtropical lake that may experience severe mixing, multiple dating
methods are required to confirm that conformable sedimentation has been preserved and that the assumptions of the 210Pb method are satisfied. This study uses stratigraphic profiles of heavy metals, 137Cs, PCBs and pollen as independent dating markers to validate the sediment chronology as determined by 210Pb for three cores from the central mud zone of the lake. Unsupported 210Pb and most dating markers show distinct concentration/depth profiles, suggesting that the sediments have not been severely
mixed for at least the last 75 years. Onset and maximum activity of the radioisotope 137Cs in the cores coincides with the 210Pb-dated interval of 1945–1970. This agrees well with the known timing of atmospheric deposition of 137Cs that resulted from above-ground nuclear testing during late 1940s until 1963. Sediment core profiles of atmospherically
deposited metals such as Zn and Pb, which reflect regional increases during industrialization and decreases after regulation
in the 1970s, exhibit expected concentration increases and peaks coinciding within 5–15 years of the predicted 210Pb dates. Uranium, a contaminant in some phosphate fertilizers, shows large concentration increases at core depths dated to
be about 1950 by 210Pb, matching the intensification of agriculture after WWII. PCBs, which are expected to peak in the early 1970s, were measured
in one core, and the observed peak corresponds to a 210Pb date of about 1960. Pollen makers were unable to verify specific events, but increases in disturbance taxa and declines
in native types correspond generally with the expected dates assigned by 210Pb dating. Conformity between the 210Pb defined dates and independent markers of < ±15 years confirm that Lake Okeechobee sediments do preserve a sequential and
reliable stratigraphic history of the lake, useful for reconstructing past limnological conditions. 相似文献
Disadvantaged urban neighbourhoods with their complex social, economic and physical situations have increasingly become the focus of governmental policies in the EU. The emphasis has shifted from improving physical qualities to building opportunities for social groups in these areas. While physical upgrade is easier to achieve, at least in the short run, initiatives often fail in outcomes on communities and local participation. This paper aims to improve understanding on how to tackle area-based social exclusion and create socially coherent communities. Building on the results of the NEHOM project, the focus is on examining how various interventions have impacted local communities and their opportunities for better inclusion. A comparison between neighbourhoods shows that mixing social groups to a certain degree is likely to be a necessary step towards opening long-term opportunities for a disadvantaged neighbourhood. The planned initiatives should at the same time directly benefit local communities, and the involvement of local groups in the planning and implementation process helps to guarantee that the overall changes are accepted by the local community. However, the proposed guidelines do not provide a universal recipe for a successful renewal suiting each neighbourhood—the contextual matters should always be a starting point when planning an initiative. 相似文献
1 IntroductionFracturing plays an important role in increasingthe production and injection and enhancing the final re-covery of oil and gas. At present, the use of ahydroxypropyl guar gum, borate-crosslinked, hydraulicfracturing fluid systemhas become ext… 相似文献