Major and Trace Element Analysis of Silicate Rocks by XRF and Laser Ablation ICP-MS Using Lithium Borate Fused Glasses: Matrix Effects, Instrument Response and Results for International Reference Materials     

Zongshou Yu  Marc D. Norman  Philip Robinson 《Geostandards and Geoanalytical Research》2003,27(1):67-89

Major and trace element compositions of fifteen silicate rock reference materials have been determined by a combined XRF and laser ablation ICP‐MS (LA‐ICP‐MS) technique on glasses prepared by fusing the sample with a lithium borate flux (sample:flux = 1:3). Advantages of this technique include the ability to measure major and trace element abundances on a single sample using a quick and simple preparation that attacks resistant phases such as zircon without the need for acid dissolution. The method is suitable for a wide variety of bulk compositions including mafic, intermediate and silicic rocks. Abundance‐normalized mass response patterns (the ratio of signal intensity to element concentration) of the LA‐ICP‐MS analyses vary systematically with major element composition, demonstrating the presence of a matrix effect that cannot be compensated by normalisation to a single internal standard element. Increasing the sampling distance between the ICP‐MS cone and the torch reduces the magnitude of this effect, suggesting that a mechanism related to residence time of ablated particles in the plasma may be at least partially responsible for the observed variations in mass response patterns. When using a matrix‐matched calibration, agreement of the LA‐ICP‐MS results with published reference values or those obtained by solution ICP‐MS is 10% relative. Analytical precision based on replicate analyses is typically 5% RSD. Procedural detection limits that include contributions from gas background and flux are 0.01‐0.1 μg g‐¹ for the heavy mass trace elements (Rb‐U). Major element analyses by XRF show excellent agreement with results obtained using a conventional heavy element absorbing flux. High quality major and trace element data for silicate rocks can be achieved by a combined XRF and LA‐ICP‐MS analysis of Li₂B₄O₇/LiBO₂ fused glasses provided an appropriate matrix‐matched calibration is adopted.  相似文献   

沈阳低温核供热站厂址基岩地面运动特性分析     

廖旭  黄河  白云  李小军 《地震工程与工程振动》2003,23(5):57-60

用确定性法和综合概率法给出沈阳低温核供热站厂址基岩地面运动峰值加速度和加速度反应谱，并和标定的RG1．60谱和HAF0101(1)谱及国家核规范谱作了对比，表明厂址谱整体上比RG1．60谱要低；概率法厂址谱在较短周期(小于0．3s)部分明显低，在较长周期(大于0．35s)部分略高。本文研究为类似地震地质条件区域的核电抗震设计积累了新经验，并作了有益探索。  相似文献   

强震近场加速度峰值比和反应谱统计分析   总被引：12，自引：3，他引：12  

周正华  周雍年  赵刚 《地震工程与工程振动》2002,22(3):15-18

本文对国内外数十次强地震的近场加速度记录进行了统计分析，给出了近场加速度峰值比及反应谱的统计结果，并将统计反应谱与设计反应谱进行了比较。  相似文献   

三塘湖盆地中生界烃源岩有机质成熟度的确定     

马安来  钟宁宁等 《中国煤田地质》2002,14(3):9-12

运用镜质组反射率、袍子体荧光参数、生物标志物参数详细研究了三塘湖盆地中生界烃源岩的有机质热演化特征及演化阶段。研究表明镜质组反射率是该区有机质热汪化最可靠听成熟度参数，孢子体荧光参数是重要的热演化指标，生物标志物参数是有效的热演化指标。三塘湖盆地有机质总体热演化水平较低，且在横向和纵向上存在明显的差异。该区的有机质热演化具有明显的阶段性，运用成熟度参数将其划分为未成熟和成熟两个阶段。  相似文献   

Peak Horizontal-to-Vertical Acceleration Ratio and Local Amplification of Strong Ground Motion     

Markušić  Snježana  Herak  Marijan  Herak  Davorka  Ivančić  Ines 《Studia Geophysica et Geodaetica》2002,46(1):83-92

Residuals of the peak horizontal acceleration for site-independent attenuation relations are shown to have weak positive correlation with the average observed peak horizontal/vertical acceleration ratio (q) at the recording site. This ratio systematically increases as the hardness of the soil decreases. Taking the average observed q at the recording station into account reduces the scatter of data slightly in fitting the assumed peak acceleration attenuation law. If the soil classification of the data is available, soil dependence is found to be weaker if the data are corrected for the effect of q prior to regression. This correction reduced the mean value of q = 1.85 for the Dinarides area to q = 1.52, which, on the average, is characteristic of rock sites.  相似文献   

Attenuation modeling of recent earthquakes in Turkey   总被引：1，自引：0，他引：1  

Polat Gülkan  Erol Kalkan 《Journal of Seismology》2002,6(3):397-409

This paper deals with the derivation of a consistent set of empiricalattenuation relationships for predicting free-field horizontal components ofpeak ground acceleration (PGA) and 5 percent damped pseudoacceleration response spectra (PSA) from 47 strong ground motion recordsrecorded in Turkey. The relationships for Turkey were derived in similarform to those previously developed by Boore et al. (1997) for shallowearthquakes in western North America. The used database was compiledfor earthquakes in Turkey with moment magnitudes (M_w) = 5 thatoccurred between 1976–1999, and consisted of horizontal peak groundacceleration and 5 percent damped response spectra of accelerogramsrecorded on three different site conditions classified as rock, soil and softsoil. The empirical equations for predicting strong ground motion weretypically fit to the strong motion data set by applying nonlinear regressionanalysis according to both random horizontal components and maximumhorizontal components. Comparisons of the results show that groundmotion relations for earthquakes in one region cannot be simply modifiedfor use in engineering analyses in another region. Our results, patternedafter the Boore et al. expressions and dominated by the Kocaeli andDüzce events in 1999, appear to underestimate predictions based ontheir curves for up to about 15 km. For larger distances the reverse holds.  相似文献   

A seismic hazard scenario for the main cities of Crete island, Greece   总被引：1，自引：0，他引：1  

Theodoros M. Tsapanos 《Geophysical Journal International》2003,153(2):403-408

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山东内陆及附近海域构造环境剪应力场的分布特征     

山长仑  范培乐  王蜂吉  颜启 《地震地磁观测与研究》2004,(Z1)

利用山东数字地震台网二年多的地震记录资料,根据陈培善等用地震发生的断裂力学模式和震源谱理论,导出的震源处峰值加速度与构造环境剪应力值的关系,计算了山东内陆及附近海域发生的46次中小地震构造环境剪应力值,并对应力场的分布状况和时空变化进行了分析。  相似文献   

X射线荧光光谱法测定多目标地球化学调查样品中主次痕量组分   总被引：25，自引：13，他引：25  

张勤  樊守忠  潘宴山  李国会 《岩矿测试》2004,23(1):19-24

采用低压聚乙烯镶边垫底的粉末样品压片制样,用PW2440X射线荧光光谱仪对多目标地球化学调查样品中Na2O、MgO、Al2O3、SiO2、P、K2O、CaO、Ti、Mn、Fe2O3、Co、Nb、Zr、Y、Sr、Rb、Pb、Th、Zn、Cu、Ni、V、Cr、Ba、La等组分进行测定。重点讨论了微量元素的背景选择和谱线重叠校正问题。使用经验系数法和康普顿散射线作内标校正基体效应,经标准物质分析检验,结果与标准值吻合,用GBW07308和GBW07310水系沉积物国家一级标准物质作精密度试验,统计结果RSD(n=12)除La、Cr、Co和Th<14.00%以外,其余各组分均小于6.00%。  相似文献   

无色散原子荧光法直接测定海水中的痕量镉   总被引：5，自引：1，他引：5  

周泳德  陈志兵  肖灵 《岩矿测试》2004,23(1):67-69

利用硫脲和Co2 对镉易挥发组分的形成有增强作用,建立了无色散原子荧光光谱直接测定海水中痕量镉的方法,检出限为0.044 μg/L,对镉含量为2.08 μg/L的样品进行11次测定,RSD为4.0%,线性范围为0～20 μg/L.对国家二级海水标准物质进行测定,结果与标准值相符.  相似文献