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61.
Tom Andersen  William L Griffin   《Lithos》2004,73(3-4):271-288
The Storgangen orebody is a concordantly layered, sill-like body of ilmenite-rich norite, intruding anorthosites of the Rogaland Intrusive Complex (RIC), SW Norway. 17 zircon grains were separated from ca. 5 kg of sand-size flotation waste collected from the on-site repository from ilmenite mining. These zircons were analysed for major and trace elements by electron microprobe, and for U–Pb and Lu–Hf isotopes by laser ablation microprobe plasma source mass spectrometry. Eight of the zircons define a well-constrained (MSWD=0.37) concordant population with an age of 949±7 Ma, which is significantly older than the 920–930 Ma ages previously reported for zircon inclusions in orthopyroxene megacrysts from the RIC. The remaining zircons, interpreted as inherited grains, show a range of 207Pb/206Pb ages up to 1407±14 Ma, with an upper intercept age at ca. 1520 Ma. The concordant zircons have similar trace element patterns, and a mean initial Hf isotope composition of 176Hf/177Hf949 Ma=0.28223±5 (Hf=+2±2). This is similar to the Hf-isotope composition of zircons in a range of post-tectonic Sveconorwegian granites from South Norway, and slightly more radiogenic than expected for mid-Proterozoic juvenile crust. The older, inherited zircons show Lu–Hf crustal residence ages in the range 1.85–2.04 Ga. One (undated) zircon plots well within the field of Hf isotope evolution of Paleoproterozoic rocks of the Baltic Shield. These findings indicate the presence of Paleoproterozoic components in the deep crust of the Rogaland area, but do not demonstrate that such rocks, or a Sveconorwegian mantle-derived component, contributed significantly to the petrogenesis of the RIC. If the parent magma was derived from a homogeneous, lower crustal mafic granulite source, the lower crustal protolith must be at least 1.5 Ga old, and it must have an elevated Rb/Sr ratio. This component would be indistinguishable in Sr, Nd and Hf isotopes from some intermediate mixtures between Sveconorwegian mantle and Paleoprotoerzoic felsic crust, but it cannot account for the initial 143Nd/144Nd of the most primitive, late Sveconorwegian granite in the region, without the addition of mantle-derived material.  相似文献   
62.
The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ~1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=~5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献   
63.
应用高光谱遥感数据估算土壤表层水分的研究   总被引:8,自引:0,他引:8  
土壤水分是土壤的重要组成部分,它在陆地表层和大气之间的物质和能量交换方面扮演着重要角色,寻求快速而准确的方法估算土壤水分具有重要意义。通常,从可见光一近红外对土壤表层水分的估计多是建立在土壤水分与反射率的关系之上的。而在土壤水分含量不高时,土壤水分的增加使土壤光谱反射率在整个波长范围内降低,尤其在760nm,970nm,1190nm,1450nm,1940nm和2950nm等水分吸收波段,而在土壤水分含量较高时,土壤水分的增加会使土壤光谱反射率在某些光谱波段升高。而土壤水分的估计往往是基于土壤水分与土壤水分吸收波段的吸收强度之间的线性关系上,虽然这些经验的方法对于估算某些土壤的表层水分含量是有效的,但这些关系应用于其它条件(如不同种类土壤、土壤湿度变化范围很大的情况)时却面临很多困难,这与土壤的光谱反射率是由土壤的组成成分(土壤水分、有机质、氧化铁和粘土矿物等)的含量和它们在土壤中的分布密切相关。微分技术处理“连续”的光谱是遥感中常用的数学方法,微分技术能部分消除低频光谱成分的影响。现在微分光谱已广泛地应用于研究植被的生物物理参数、矿物和有机质等。然而利用微分光谱对土壤水分反演的研究却鲜见报道。本文通过对实验室中多种不同类型的土壤进行光谱与土壤表层水分含量进行观测,探讨了通过土壤反射率与微分光谱对土壤表层水分的反演方法。4种类型的土壤光谱数据(反射率(R),反射率倒数的对数(log(1/R)),反射率的一阶微分光谱(dR/dλ),反射率倒数的对数的一阶微分光谱(d(log(1/R))/dλ))与土壤表层水分之间的关系在本文中得到分析,R与log(1/R)对于不同土壤类型与土壤表层水分都很敏感,说明通过R与log(1/R)反演土壤表层水分受土壤类型的影响很大,而dR/dλ,d(log(1/R))/dλ)对土壤类型却不敏感,对土壤表层水分较为敏感,说明dR/dλ和d(log(1/R))/dλ)对于反演不同类型土壤具有很大的潜力,微分光谱与土壤水分在某些波段具有显著的相关性。通过随机对9种土壤(各具有4个土壤水分)的数据建立反演土壤水分的模型,并其他9种土壤(各具有4个土壤水分)的数据进行验证模型,结果表明,dR/dλ和d(log(1/R))/dλ)能够显著提高R与log(1/R)对于不同土壤类型土壤表层水分的反演精度,由于吸收过程是非线性的,在四种类型的土壤光谱数据中,总体来说,d(log(1/R))/dλ)具有最好的能力预测不同类型土壤的表层水分含量。  相似文献   
64.
Underground coal and copper ore exploitation in two Polish mining regions causes mining tremors and a series of other negative phenomena in the environment. Although these tremors are strictly connected with human activity, they differ considerably from other paraseismic vibrations. The moment of their occurrence is not to be foreseen likewise for earthquakes. The main problem discussed in the paper was formulated as the neural network evaluation of a relation between mining tremor energies, epicentral distances and acceleration response spectra. Back-propagation neural networks with Resilient back-propagation learning method were used. Each input vector included information about the mining tremor energy and the epicentral distance. Values of acceleration response spectrum were expected as the outputs of neural networks. Neurally evaluated spectra were compared with spectra computed on the basis of experimental data. After the network is trained and tested, it can be used for mapping of new data of mining tremor energies and epicentral distances into the spectra. Then, what is the substantial advantage of neural approach, the prediction of acceleration response spectra can be performed without recording of surface vibrations. In the light of the results, it is visible that the presented way of computation of acceleration response spectra can be peculiarly applied to prognosis of mining tremors influences on structures.  相似文献   
65.
Introduction Estimation of an attenuation relationship for strong ground motion parameters has been an interesting research subject in the field of engineering seismology and has played a very important role in seismic safety evaluation, seismic zoning, seismic hazard evaluation of major constructions, etc. At present, the generally used parameters include peak acceleration, peak velocity and elastic response spectrum. Such parameters mentioned above are essentially independent of the duration…  相似文献   
66.
A large amount of nuclear wastes has been pro-duced due to nuclear weapon development and nuclear electricity generation. One possible resolution for the disposal of the nuclear wastes is to seal them in an underground repository, which requires detailed knowledge on the mobility, chemical behavior and immobilization of radionuclides in underground water. In addition, toxic heavy metals are extensively present in ground and underground water, how to immobilize and remedy these toxic heavy meta…  相似文献   
67.
68.
不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。  相似文献   
69.
70.
Salinity is a vital factor that regulates leaf photosynthesis and growth of mangroves, and it frequently undergoes large seasonal and daily fluctuations creating a range of environments – oligohaline to hyperhaline. Here, we examined the hypotheses that mangroves benefit opportunistically from low salinity resulting from daily fluctuations and as such, mangroves under daily fluctuating salinity (FS) grow better than those under constant salinity (CS) conditions. We compared growth, salt accumulation, gas exchange, and chlorophyll fluorescence of leaves of mangrove Bruguiera gymnorhiza seedlings growing in freshwater (FW), CS (15 practical salinity units, PSU), and daily FS (0–30 PSU, average of 4.8 PSU) conditions. The traits of FS-treated leaves were measured in seedlings under 15 PSU. FS-treated seedlings had greater leaf biomass than those in other treatment groups. Moreover, leaf photosynthetic rate, capacity to regulate photoelectron uptake/transfer, and leaf succulence were significantly higher in FS than in CS treatment. However, leaf water-use efficiency showed the opposite trend. In addition to higher concentrations of Na+ and Cl, FS-treated leaves accumulated more Ca2+ and K+. We concluded that daily FS can enhance water absorption, photosynthesis, and growth of leaves, as well as alter plant biomass allocation patterns, thereby positively affecting B. gymnorhiza. Mangroves that experience daily FS may increase their adaptability by reducing salt build-up and water deficits when their roots are temporally subjected to low salinity or FW and by absorbing sufficient amounts of Na+ and Cl for osmotic adjustment when their roots are subsequently exposed to saline water.  相似文献   
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