Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

Elastic properties of granulite facies rocks of Mahabalipuram, Tamil Nadu, India     

M. V. M. S. Rao  K. J. Prasanna Lakshmi  L. P. Sarma  K. B. Chary 《Journal of Earth System Science》2006,115(6):673-683

Compressional and shear wave velocities and attenuation measurements have been carried out in some of the borehole samples of acidic, basic and intermediate granulites of Mahabalipuram, Tamil Nadu, India. The results have been obtained at ambient conditions using ‘time-of-flight’ pulse transmission technique at 1.0 MHz frequency. The results show linear relationships between velocity and density, and velocity and attenuation properties of the rocks. The acidic granulites show lower velocities and higher attenuation than the intermediate and basic granulites. The average values of the Poisson’s ratio of acidic, intermediate and basic granulites have been found to be 0.210, 0.241 and 0.279 respectively. The variations in velocities and attenuation in these low porosity crystalline rocks are found to be strongly influenced by their mineral composition. The laboratory velocity data (extrapolated to high pressure) of the present study and the published field velocity data from deep seismic sounding studies indicate that these granulite facies rocks may belong to mid-crustal depths only.  相似文献   

Ground motion scaling in the Marmara region, Turkey   总被引：1，自引：0，他引：1  

A. Akinci  L. Malagnini  R. B. Herrmann  R. Gok  M. B. Sørensen 《Geophysical Journal International》2006,166(2):635-651

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Dual simulations of fluid flow and seismic wave propagation in a fractured network: effects of pore pressure on seismic signature   总被引：1，自引：0，他引：1  

S. Vlastos  E. Liu  I. G. Main  M. Schoenberg  C. Narteau  X. Y. Li  B. Maillot 《Geophysical Journal International》2006,166(2):825-838

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The Removal of Dissolved Metals by Hydroxysulphate Precipitates during Oxidation and Neutralization of Acid Mine Waters, Iberian Pyrite Belt   总被引：4，自引：0，他引：4  

J. Sánchez España  E. López Pamo  E. Santofimia Pastor  J. Reyes Andrés  J. A. Martín Rubí 《Aquatic Geochemistry》2006,12(3):269-298

This study examines the removal of dissolved metals during the oxidation and neutralization of five acid mine drainage (AMD) waters from La Zarza, Lomero, Esperanza, Corta Atalaya and Poderosa mines (Iberian Pyrite Belt, Huelva, Spain). These waters were selected to cover the spectrum of pH (2.2–3.5) and chemical composition (e.g., 319–2,103 mg/L Fe; 2.85–33.3 g/L SO₄⁼) of the IPB mine waters. The experiments were conducted in the laboratory to simulate the geochemical evolution previously recognized in the field. This evolution includes two stages: (1) oxidation of dissolved Fe(II) followed by hydrolysis and precipitation of Fe(III), and (2) progressive pH increase during mixing with fresh waters. Fe(III) precipitates at pH < 3.5 (stages 1 and 2) in the form of schwertmannite, whereas Al precipitates during stage 2 at pH 5.0 in the form of several hydroxysulphates of variable composition (hydrobasaluminite, basaluminite, aluminite). During these stages, trace elements are totally or partially sorbed and/or coprecipitated at different rates depending basically on pH, as well as on the activity of the SO₄⁼ anion (which determines the speciation of metals). The general trend for the metals which are chiefly present as aqueous free cations (Pb²⁺, Zn²⁺, Cu²⁺, Cd²⁺, Mn²⁺, Co²⁺, Ni²⁺) is a progressive sorption at increasing pH. On the other hand, As and V (mainly present as anionic species) are completely scavenged during the oxidation stage at pH < 3.5. In waters with high activities (> 10⁻¹) of the SO ₄⁼ ion, some elements like Al, Zn, Cd, Pb and U can also form anionic bisulphate complexes and be significantly sorbed at pH < 5. The removal rates at pH 7.0 range from around 100% for As, V, Cu and U, and 60–80% for Pb, to less than 20% for Zn, Co, Ni and Mn. These processes of metal removal represent a significant mechanism of natural attenuation in the IPB.  相似文献   

Early Estimation of Seismic Hazard for Strong Earthquakes in Taiwan   总被引：1，自引：0，他引：1  

Wen-Yu Jean  Yu-Wen Chang  Kuo-Liang Wen  Chin-Hsiung Loh 《Natural Hazards》2006,37(1-2):39-53

A shakemap system providing rapid estimates of strong ground shaking could be useful for emergency response providers in a damaging earthquake. A hybrid procedure, which combines site-dependent ground motion prediction models and the limited observations of the Real-Time Digital stream output system (RTD system operated by Central Weather Bureau, CWB), was set up to provide a high-resolution shakemap in a near-real-time manner after damaging earthquakes in Taiwan. One of the main factors that affect the result of ground motion prediction analysis is the existence of site effects. The purpose of this paper is to investigate the local site effects and their influence in the ground shaking and then establish an early estimation procedure of potential hazard for damaging earthquakes. Based on the attenuation law, the site effects of each TSMIP station are discussed in terms of a bias function that is site and intensity-level dependent function. The standard deviation of the site-dependent ground motion prediction model can be significantly reduced. The nonlinear behavior of ground soil is automatically taken into account in the intensity-level dependent bias function. Both the PGA and the spectral acceleration are studied in this study. Based on the RTD data, event correctors are calculated and applied to precisely estimate the shakemap of damaging earthquakes for emergency response.  相似文献   

企业内部会计控制弱化及其对策     

宋建新 《中国煤田地质》2005,17(3):68-70

列举了企业内邵会计控制存在的内部会计系统控制机制不健全，监督、考核机制乏力，财务控制存在漏洞、公司企业治理结构不完善等目前企业内部会计控制现状及重点存在问题。提出了完善企业的内部会计控制环境．不相容职务必须分离，强化监督，督促实施，加强会计基础工作，完善会计电算化管理，规范业务处理程序等具体改进建议。  相似文献   

FY-1C可见光通道衰减分析及订正试验          下载免费PDF全文

谷松岩 邱红刘玉洁  范天锡 《应用气象学报》2002,13(6):734-740

利用FY-1C连续两年的遥感资料，以敦煌辐射校正场为分析区，系统分析了FY-1C可见光、近红外通道的衰减特征，开展了通道衰减订正试验。分析结果表明，FY-1C除可见光通道1衰减强烈外，其它各可见光、近红外通道衰减性能稳定。利用统计分析法，可以建立定标系数衰减订正量随时间的变化关系。订正后的定标系数与2000年辐射校正场外定标实验结果一致性很好。更新后的定标系数可以有效克服通道衰减带来的通道反射率测值误差，提高FY-1C可见光、近红外通道遥感资料定量应用的精度。  相似文献   

神头泉流量变化规律研究--灰色系统理论的具体应用   总被引：2，自引：0，他引：2  

郭清海  王焰新  武全胜  邓安利 《地质科技情报》2002,21(1):27-31

在分析神头泉流量衰减特征的前提下，利用灰色系统理论建立了描述神头泉流量变化规律的数学模型。以1985年为界，神头泉的流量变化过程可分为两个阶段，GM（1，1）模型与灰色预测校正模型则分别用于对这两个阶段的流量变化特征进行刻画。神头泉2000－2004年的流量预测值表明，在神头泉域保证90年代中期的高降水量和朔州市各地下水用户对泉域内的地下水不进行超采的基础上，神头泉的流量在未来的一段时间内会维持1993年以来的增长趋势。  相似文献   

Modes of raising northeastern Tibet probed by explosion seismology   总被引：4，自引：0，他引：4  

Audrey GalvéAlfred Hirn  Jiang MeiJosep Gallart  Béatrice de VoogdJean-Claude Lépine  Jordi DiazWang Youxue  Qian Hui 《Earth and Planetary Science Letters》2002,203(1):35-43

New wide-angle reflection and refraction seismic data provide constraints on the structure of the upper lithosphere, and test models of its evolution to raise the northeastern part of the Tibetan Plateau. Amplitudes observed for reflections from the crust-mantle boundary are sufficiently large to suggest that there is no significant partial melt in the deep crust. The data show an increase of the crustal thickness between terranes from north of the Kun Lun Fault into the Qang Tang of central Tibet, and a contrast among their intracrustal images and compositions. In the north, P and S velocities are consistent with a dominantly felsic composition and show that only the upper crust thickened. South of the Kun Lun Fault a thicker crust made of two layers could result from the superposition of the originally thin crust of the Bayan Har terrane on the lower part of the crust of the domain to the north, which upper crust it shoved and thickened. Different modes of crustal thickening, either by thickening of individual layers or superpositions and imbrication among them appear to work jointly to raise the topography.  相似文献