全文获取类型
收费全文 | 511篇 |
免费 | 86篇 |
国内免费 | 142篇 |
专业分类
大气科学 | 46篇 |
地球物理 | 119篇 |
地质学 | 262篇 |
海洋学 | 188篇 |
天文学 | 12篇 |
综合类 | 41篇 |
自然地理 | 71篇 |
出版年
2024年 | 2篇 |
2023年 | 9篇 |
2022年 | 18篇 |
2021年 | 13篇 |
2020年 | 19篇 |
2019年 | 19篇 |
2018年 | 21篇 |
2017年 | 25篇 |
2016年 | 20篇 |
2015年 | 25篇 |
2014年 | 33篇 |
2013年 | 39篇 |
2012年 | 32篇 |
2011年 | 38篇 |
2010年 | 29篇 |
2009年 | 47篇 |
2008年 | 44篇 |
2007年 | 35篇 |
2006年 | 39篇 |
2005年 | 23篇 |
2004年 | 24篇 |
2003年 | 21篇 |
2002年 | 25篇 |
2001年 | 19篇 |
2000年 | 14篇 |
1999年 | 24篇 |
1998年 | 18篇 |
1997年 | 8篇 |
1996年 | 13篇 |
1995年 | 5篇 |
1994年 | 6篇 |
1993年 | 9篇 |
1992年 | 5篇 |
1991年 | 6篇 |
1990年 | 3篇 |
1988年 | 1篇 |
1987年 | 1篇 |
1986年 | 1篇 |
1985年 | 1篇 |
1982年 | 3篇 |
1981年 | 1篇 |
1977年 | 1篇 |
排序方式: 共有739条查询结果,搜索用时 15 毫秒
11.
珠江口海域无机氮和活性磷酸盐含量的时空变化特征 总被引:17,自引:1,他引:17
主要利用1998年在珠江口海域连续同步观测资料,研究该海域无机氮、活性磷酸盐含量和富营养化状况。结果表明,无机氮主要来自四个口门的径流,但深圳湾附近的陆源亦有一定贡献;无机氮的形态主要以硝酸氮为主,而在深圳湾附近海域则以氨氮为主;无机氮含量普遍超过0.30mg/dm^3的我国海水水质标准二类标准值,大部分海域已超过0.50mg/dm^3的四类水质标准值,径流对活性磷酸盐含量的贡献不显著,而深圳湾附近的陆源则有明显的贡献,从珠江口附近由沿岸流和涨潮流带来的活性磷酸盐亦有明显的影响;除深圳湾附近海域活性磷酸盐含量超过0.030mg/dm^3的二类海水水质标准值外,其他海域基本符合0.015mg/dm^3的一类海水水质标准值要求。该海域的N/P值普遍较高,而且北部海域的高于南部海域;最高值超过300,最小值也大小30;该水域的营养盐主要为磷限制。 相似文献
12.
The Ocean Drilling Program Leg 175 recovered a unique series of stratigraphically continuous sedimentary sections along the SW African margin, an area which is presently affected by active coastal upwelling. The accumulation rates of organic and inorganic carbon are a major component of this record. Four Leg 175 sites (1082, 1084, 1085, 1087) are chosen as part of a latitudinal transect from the present northern to southern boundaries of the Benguela Current upwelling system, to decipher the Pliocene–Pleistocene history of biogenic production and its relationship with global and local changes in oceanic circulation and climate. The pattern of CaCO3 and Corg mass accumulation rates (MARs) over 0.25-Myr intervals indicates that the evolution of carbon burial is highly variable between the northern and the southern Benguela regions, as well as between sites that have similar hydrological conditions. This, as well as the presence over most locations of high-amplitude, rapid changes of carbon burial, reflect the partitioning of biogenic production and patterns of sedimentation into local compartments over the Benguela margin. The combined mapping of CaCO3 and Corg MARs at the study locations suggests four distinct evolutionary periods, which are essentially linked with major steps in global climate change: the early Pliocene, the mid-Pliocene warm event, a late Pliocene intensification of northern hemisphere glaciation and the Pleistocene. The early Pliocene spatially heterogeneous patterns of carbon burial are thought to reflect the occurrence of mass-gravitational movements over the Benguela slope which resulted in disruption of the recorded biogenic production. This was followed (3.5–3 Ma) by an episode of peak carbonate accumulation over the whole margin and, subsequently, by the onset of Benguela provincialism into a northern and a southern sedimentary regime near 2 Ma. This mid and late Pliocene evolution is interpreted as a direct response to changes in the ventilation of bottom and intermediate waters, as well as to dynamics of the subtropical gyral circulation and associated wind stress. 相似文献
13.
Pyruvate kinase (PK) activity measurements are used to assess the role of carbohydrates in global feeding of mesozooplankton communities inhabiting an estuary plume. As a consequence of a remarkably low freshwater discharge rate, the sea surface layers of the area under estuarine influence showed a very moderate salinity fall and a nearly total depletion in nitrates, whereas higher levels of these nutrients were found in deeper, more saline, layers. Small-scale PK activity variations in mesozooplankton appear to be closely correlated to nitrate integration values within the water column. The results were analysed in comparison with literature reports. The study produced a coherent overall interpretation, which strongly supports the reliability of this new biochemical tool in detecting assimilation of trace carbohydrates in the diet of mesozooplankton. 相似文献
14.
15.
Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins 总被引:1,自引:0,他引:1
Raffaela Biesuz Giancarla Alberti Girolamo D'Agostino Emanuele Magi Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189
The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log αM(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 1020 M− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log αM(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations. 相似文献
16.
17.
1993/1994年南极夏季对中国南极长城湾及附近海区表层海水四种营养盐浓度及其分布状况作了调查。结果表明,NH4-N、NO3-N、NO2-N及PO4-P的大致浓度分别是2.13、7.07、0.74和1.12μg·dm-3。一般来说,湾内高于湾外氮盐于12月份常出现高值。四种形态的无机盐类之最高、最低浓度出现的时间和站位不尽一致。∑N/P递减次序大致是12月,2月,1月。水温变化与NH4-N、PO4-P浓度和∑N/P的变化常较一致,而与NO2-N则常不一,一些站位上营养盐浓度偏低可能与浮游植物摄取有关。结果显示了调研海区的浅水内湾特征。浮游植物所需营养充分。该湾仍维持正常状态。 相似文献
18.
19.
Marcelo F. L. Souza Bjrn Kjerfve Bastiaan Knoppers Weber F. Landim de Souza Raimundo N. Damasceno 《Estuarine, Coastal and Shelf Science》2003,57(5-6):843-858
Lagoa de Araruama in the state of Rio de Janeiro, Brazil, is a hypersaline lagoon with salinity varying spatially from 45 to 56. We collected water samples during monthly cruises throughout the lagoon, and along the streams feeding the system, from April 1991 to March 1992. Nutrients and other water quality parameters exhibited great spatial and temporal variations. Mass balance calculations indicate large amounts of anthropogenic nutrient inputs. The data indicate that the lagoon currently is oligotrophic but is in a state of transition to become a mesotrophic system. Molar dissolved inorganic nitrogen:dissolved inorganic phosphorus (DIN/DIP) varied between 2.2:1 and 659:1 with a volume-weighted average of 22:1. The high DIN/DIP ratio contrasts with that found in nearby lagoons, suggesting that phytoplankton primary production is limited by phosphorus in Lagoa de Araruama. The major loss of DIP is apparently driven by biological assimilation and diagenic reactions in the sediments. Calculations indicate that the lagoon is slightly net autotrophic at +0.9 mol C m−2 yr−1. This suggests that the biomass of the primary producers is restricted by phosphorus availability. Phosphorus retention in the sediment and the hypersaline state of the lagoon prevent changes in autotrophic communities and the formation of eutrophic conditions. 相似文献
20.
Lutz Nasdala Wolfgang Hofmeister Nicholas Norberg James M. Martinson Fernando Corfu Wolfgang Dörr Sandra L. Kamo Allen K. Kennedy Andreas Kronz Peter W. Reiners Dirk Frei Jan Kosler Yusheng Wan Jens Götze Tobias Häger Alfred Kröner John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ~ 840 μg g?1 U (Th/U ~ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn. 相似文献