Significance of isotopic and geochemical methods to determine the evolution of inland brackish and bitter water: An example from the Zuli river in the upper reaches of the Yellow River,China     

Zihao Liu  Hongbing Tan  Mark L. Brusseau 《水文研究》2021,35(1):e14024

With the increasing demand for water resources, the utilization of marginal water resources of poor-quality has become a focus of attention. The brackish water developed in the Loess Plateau is not only salty but also famous for its ‘bitterness’. In the present work, multi-isotope analysis (Sr, B) was combined with geochemical analysis to gain insight into the hydrogeochemical evolution and formation mechanisms of brackish water. These results demonstrate that groundwater in the headwater is influenced by carbonate weathering. After the confluence of several tributaries in the headwater, the total dissolved solids (TDS) of water is significantly increased. The dissolution of evaporates is shown to be the main source of salinity in brackish water, which also greatly affects the strontium isotopic composition of water. This includes the dissolution of Mg-rich minerals, which is the main cause of the bitterness. Furthermore, the release of calcium from the dissolution of gypsum may induce calcite precipitation and incongruent dissolution of dolomite, which also contributes to the enrichment of magnesium. The highly fractionated boron isotopic values observed in the upstream groundwater were explained by the absorption with clay minerals. The inflow of brackish groundwater is the source of river water. Then evaporation further aggravates the salinization of river water, with water quality evolving to saline conditions in the lower reach. When the river reaches the valley plain, the ⁸⁷Sr/⁸⁶Sr ratios decreases significantly, which is primarily related to erosion of the riverbanks during runoff. These results indicate that water resource sustainability could be enhanced by directing focus to mitigating salinization in the source area of the catchment.  相似文献   

Carbon dioxide,methane, and dissolved carbon dynamics in an urbanized river system     

Chao Gu  Susan Waldron  Adrian Michael Bass 《水文研究》2021,35(9):e14360

Estimates of greenhouse gas evasion from rivers have been refined over the past decades to constrain their role in global carbon cycle processes. However, despite 55% of the human population living in urban areas, urban rivers have had limited attention. We monitored carbon dynamics in an urbanized river (River Kelvin, 331 km², UK) to explore the drivers of dissolved carbon lateral and vertical export. Over a 2-year sampling period, riverine methane (CH₄) and carbon dioxide (CO₂) concentrations were consistently oversaturated with respect to atmospheric equilibria, leading to continual degassing to the atmosphere. Carbon stable isotopic compositions (δ¹³C) indicated that terrestrially derived carbon comprised most of the riverine CH₄ and dissolved CO₂ (CO₂*) load while dissolved inorganic carbon (DIC) from groundwater was the main form of riverine DIC. The dynamics of CH₄, CO₂*, and DIC in the river were primarily hydrology-controlled, that is, [CH₄] and [CO₂*] both increased with elevated discharge, total [DIC] decreased with elevated discharge while the proportion of biologically derived DIC increased with increasing discharge. The concentration of dissolved organic carbon (DOC) showed a weak relationship with river hydrology in summer and autumn and was likely influenced by the combined sewer overflows. Carbon emission to the atmosphere is estimated to be 3.10 ± 0.61 kg C·m⁻²·yr⁻¹ normalized to water surface area, with more than 99% emitted as CO₂. Annual carbon loss to the coastal estuary is approximately 4.69 ± 0.70 Gg C yr⁻¹, with annual DIC export approximately double that of DOC. Per unit area, the River Kelvin was a smaller carbon source to the atmosphere than natural rivers/streams but shows elevated fluxes of DIC and DOC under comparable conditions. This research illustrates the role urban systems may have on riverine carbon dynamics and demonstrates the potential tight link between urbanization and riverine carbon export.  相似文献   

Climate change and hydrology at the prairie margin: Historic and prospective future flows of Canada's Red Deer and other Rocky Mountain rivers          下载免费PDF全文

Laurens J. Philipsen  Karen M. Gill  Anita Shepherd  Stewart B. Rood 《水文研究》2018,32(17):2669-2684

The South Saskatchewan River Basin of southern Alberta drains the transboundary central Rocky Mountains region and provides the focus for irrigation agriculture in Canada. Following extensive development, two tributaries, the Oldman and Bow rivers, were closed for further water allocations, whereas the Red Deer River (RDR) remains open. The RDR basin is at the northern limit of the North American Great Plains and may be suitable for agricultural expansion with a warming climate. To consider irrigation development and ecological impacts, it is important to understand the regional hydrologic consequences of climate change. To analyse historic trends that could extend into the future, we developed century‐long discharge records for the RDR, by coordinating data across hydrometric gauges, estimating annual flows from seasonal records, and undertaking flow naturalization to compensate for river regulation. Analyses indicated some coordination with the Pacific decadal oscillation and slight decline in summer and annual flows from 1912 to 2016 (?0.13%/year, Sen's slope). Another forecasting approach involved regional downscaling from the global circulation models, CGCMI‐A, ECHAM4, HadCM3, and NCAR‐CCM3. These projected slight flow decreases from the mountain headwaters versus increases from the foothills and boreal regions, resulting in a slight increase in overall river flows (+0.1%/year). Prior projections from these and other global circulation models ranged from slight decrease to slight increase, and the average projection of ?0.05%/year approached the empirical trend. Assessments of other rivers draining the central and northern Rocky Mountains revealed a geographic transition in flow patterns over the past century. Flows from the rivers in Southern Alberta declined (around ?0.15%/year), in contrast to increasing flows in north‐eastern British Columbia and the Yukon. The RDR watershed approaches this transition, and this study thus revealed regional differentiation in the hydrological consequences from climate change.  相似文献   

Formation waters discharge to rivers near oil sands projects          下载免费PDF全文

Jessica Ellis  Scott Jasechko 《水文研究》2018,32(4):533-549

Groundwater discharges in the western Canadian oil sands region impact river water quality. Mapping groundwater discharges to rivers in the oil sands region is important to target water quality monitoring efforts and to ensure injected wastewater and steam remain sequestered rather than eventually resurfacing. Saline springs composed of Pleistocene‐aged glacial meltwater exist in the region, but their spatial distribution has not been mapped comprehensively. Here we show that formation waters discharge into 3 major rivers as they flow through the Athabasca Oil Sands Region adjacent to many active oil sands projects. These discharges increase river chloride concentrations from river headwaters to downstream reaches by factors of ~23 in the Christina River, ~4 in the Clearwater River, and ~5 in the Athabasca River. Our survey provides further evidence for the substantial impact of formation water discharges on river water quality, even though they comprise less than ~2% of total streamflow. Geochemical evidence supporting formation water discharges as the leading control on river salinity include increases in river chloride concentrations, Na/(Na + Ca) ratios, Cl/(Cl + SO₄) ratios and decreases in ⁸⁷Sr/⁸⁶Sr ratios; each mixing trend is consistent with saline groundwater discharges sourced from Cretaceous or Devonian aquifers. These regional subsurface‐to‐surface connections signify that injected wastewater or steam may potentially resurface in the future, emphasizing the critical importance of mapping groundwater flow paths to understand present‐day streamflow quality and to predict the potential for injected fluids to resurface.  相似文献   

River management response to multi-decade changes in timing of reservoir inflows,Columbia River Basin,USA     

Julia A. Jones  John C. Hammond 《水文研究》2020,34(25):4814-4830

Around the world, long-term changes in the timing and magnitude of streamflow are testing the ability of large managed water resource systems constructed in the 20th century to continue to meet objectives in the 21st century. Streamflow records for unregulated rivers upstream of reservoirs can be combined with records downstream of reservoirs using a paired-watershed framework and concepts of water resource system performance to assess how reservoir management has responded to long-term change. Using publicly available data, this study quantified how the intra-annual timing of inflows and outflows of 25 major reservoirs has shifted, how management has responded, and how this has influenced reliability and vulnerability of the water resource system in the 668,000 km² Columbia River basin from 1950 to 2012. Reservoir inflows increased slightly in early spring and declined in late spring to early fall, but reservoir outflows increased in late summer from 1950 to 2012. Average inflows to reservoirs in the low flow period exceeded outflows in the1950s, but inflows are now less than outflows. Reservoirs have increased hedging, that is, they have stored more water during the spring, in order to meet the widening gap between inflows and outflows during the summer low flow period. For a given level of reliability (the fraction of time flow targets were met), vulnerability (the maximum departure from the flow target) was greater during periods with lower than average inflows. Thus, the water management system in this large river basin has adjusted to multi-decade trends of declining inflows, but vulnerability, that is, the potential for excess releases in spring and shortfalls in summer, has increased. This study demonstrates the value of combining publicly available historical data on streamflow with concepts from paired-watershed analyses and metrics of water resource performance to detect, evaluate, and manage water resource systems in large river basins.  相似文献   

Influences of upstream reservoir stratification and downstream tidal fluctuations on the summer thermal regime of a regulated coastal river     

David Timothy West  Robert Daniel Moore 《水文研究》2020,34(24):4660-4674

This study focused on the effects of upstream reservoir thermal dynamics and downstream tidal influences on temperatures in a 25-km reach of Alouette River (coastal British Columbia, Canada) below a control dam and upstream of its confluence with Pitt River. Temperature was monitored during summer 2013 using 25 sensors. Water was released from the reservoir through a low level outlet at approximately 2.7 m³ s⁻¹, except during late spring when a higher flow was released over the dam spillway. Temperature variations in the lowest section of Alouette River, and in the lower portion of a tributary, were distinct from those further upstream due to backwatering effects associated with a semi-diurnal tide, which can cause flow reversals in Pitt River. An internal seiche was identified in the reservoir during mid-summer that resulted in oscillating releases of warmer and cooler water with an amplitude of up to 6°C and a period of approximately 12 hr. Wavelet analysis and band-pass filtering indicated that the 12-hr signal declined in strength with downstream distance, but remained detectable about 15 km below the dam. In contrast, the 24-hr diel signal increased in strength with distance below the dam. Travel times computed via cross-correlation of the 12-hr signals with that at the low level outlet were within ±10% of those estimated from measured mean velocities. Lagrangian tracking of water parcels using the derived travel times indicated that the cooling effect of periodic releases of cold water during the seiching period persisted to the lower extent of the non-tidal reach. The tidally influenced locations experienced higher temperatures than those recorded in the non-tidal portion of Alouette River, although the relative roles of heating in the upstream tidal reach versus upstream advection of water associated with tide-driven flow reversals in Pitt River require further study.  相似文献   

Accelerated continental-scale snowmelt and ecohydrological impacts in the four largest Siberian river basins in response to spring warming     

Kazuyoshi Suzuki  Tetsuya Hiyama  Koji Matsuo  Kazuhito Ichii  Yoshihiro Iijima  Dai Yamazaki 《水文研究》2020,34(19):3867-3881

River runoff from the four largest Siberian river basins (the Ob, Yenisei, Lena, and Kolyma) considerably contributes to freshwater flux into the Arctic Ocean from the Eurasian continent. However, the effects of variation in snow cover fraction on the ecohydrological variations in these basins are not well understood. In this study, we analysed the spatiotemporal variability of the maximum snow cover fraction (SCF_max) in the four Siberian river basins. We compared the SCF_max from 2000 to 2016 with data in terms of monthly temperature and precipitation, night-time surface temperatures, the terrestrial water storage anomaly (TWSA), the normalised difference vegetation index (NDVI), and river runoff. Our results exhibit a decreasing trend in the April SCF_max values since 2000, largely in response to warming air temperatures in April. We identified snowmelt water as the dominant control on the observed increase in the runoff contribution in May across all four Siberian river basins. In addition, we detected that the interannual river runoff was predominantly controlled by interannual variations in the TWSA. The NDVI in June was strongly controlled by the timing of the snowmelt along with the surface air temperature and TWSA in June. The rate of increase in the freshwater flux from the four Siberian rivers decreased from 2000 to 2016, exhibiting large interannual variations corresponding to interannual variations in the TWSA. However, we identified a clear increase trend in the freshwater flux of ~4 km³/year when analysing the long-term 39-year historical record (1978–2016). Our results suggest that continued global warming will accelerate the transition towards the earlier timing of snowmelt and spring freshwater flux into the Arctic Ocean. Our findings also highlight the effects of earlier snowmelt on ecohydrological changes in the Northern Hemisphere.  相似文献   

Downstream fining in contrasting reaches of the sand‐bedded Yellow River     

Wanquan Ta  Haibin Wang  Xiaopeng Jia 《水文研究》2011,25(24):3693-3700

Compared to downstream fining of a gravel‐bedded river, little field evidence exists to support the process of downstream fining in large, fine sand‐bedded rivers. In fact, the typically unimodal bed sediments of these rivers are thought to produce equal mobility of coarse and fine grains that may discourage downstream fining. To investigate this topic, we drilled 200 sediment cores in the channel beds of two fine‐grained sand‐bedded reaches of the Yellow River (a desert reach and a lower reach) and identified a fine surface layer (FSL) developed over a coarse subsurface layer (CSL) in the 3‐m‐thick bed deposits. In both reaches downstream, the thickness of the FSL increased, while that of the CSL decreased. Comparison of the depth‐averaged median grain sizes of the CSL and the FSL separately in both reaches shows a distinct downstream fining dependence to the median grain size, which indicates that at a large scale of 600‐800 km, the CSL shows a significant downstream fining, but the FSL shows no significant trends in downstream variations in grain size. This result shows that fine sediment supply (<0·08 mm median grain size) from upstream, combined with lateral fine sediment inputs from tributaries and bank erosion, can cause a rapid fining of the downstream channel bed surface and can develop the FSL layer. However, in the desert reach, lateral coarse sediment supply (>0·08 mm median grain size) from wind‐borne sediments and cross‐desert tributaries can interrupt the FSL and coarsen the channel bed surface locally. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Daily river water temperature forecast model with a k‐nearest neighbour approach     

André St‐Hilaire  Taha B. M. J. Ouarda  Zoubeida Bargaoui  Anik Daigle  Laurent Bilodeau 《水文研究》2012,26(9):1302-1310

Water temperature is a key abiotic variable that modulates both water chemistry and aquatic life in rivers and streams. For this reason, numerous water temperature models have been developed in recent years. In this paper, a k‐nearest neighbour model (KNN) is proposed and validated to simulate and eventually produce a one‐day forecast of mean water temperature on the Moisie River, a watercourse with an important salmon population in eastern Canada. Numerous KNN model configurations were compared by selecting different attributes and testing different weight combinations for neighbours. It was found that the best model uses attributes that include water temperature from the two previous days and an indicator of seasonality (day of the year) to select nearest neighbours. Three neighbours were used to calculate the estimated temperature, and the weighting combination that yielded the best results was an equal weight on all three nearest neighbours. This nonparametric model provided lower Root Mean Square Errors (RMSE = 1·57 °C), Higher Nash coefficient (NTD = 0·93) and lower Relative Bias (RB = ? 1·5%) than a nonlinear regression model (RMSE = 2·45 °C, NTD = 0·83, RB = ? 3%). The k‐nearest neighbour model appears to be a promising tool to simulate of forecast water temperature where long time series are available. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献   

Serial dependence properties in multivariate streamflow simulation with independent decomposition analysis     

Taesam Lee 《水文研究》2012,26(7):961-972

Stochastic simulation of multivariate hydrologic variables has a key role in evaluating alternative designs and operation rules of hydrologic facilities. The recently developed decomposition analysis, Independent Component Analysis (ICA), allows us to apply the simple univariate time series model to each extracted component by: (1) decomposing multivariate time series into independent components with ICA; (2) modelling and generating each component independently; and (3) mixing the generated components to come back to observational domain. However, we illustrate in the current study that fitting a univariate time series model to each extracted component might end up with the underestimation of the serial dependence that the observation data might contain. A alternative for parameter estimation is suggested to preserve the serial dependence of the observation variable using the relationship between the observation variable and the decomposed variable. The case study of the Upper Colorado River basin shows that some improvement is made through the suggested alternative. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献