Experimental solidification of anhydrous latitic and trachytic melts at different cooling rates: The role of nucleation kinetics   总被引：1，自引：0，他引：1  

Gianluca Iezzi  Silvio Mollo  Guido Ventura  Andrea Cavallo  Claudia Romano 《Chemical Geology》2008,253(3-4):91-101

Two sets of cooling experiments were run at atmospheric conditions for two anhydrous starting latitic and trachytic melts: 1) five cooling rates (25, 12.5, 3, 0.5, and 0.125 °C/min) between 1300° and 800 °C, and 2) a 0.5 °C/min cooling rate from 1300 °C with quench temperatures at 1200°, 1100°, 1000° and 900 °C. Trachytic run-products are invariably glassy. Nucleation is also suppressed in the latitic run-products at the three highest cooling rates. Conversely, in the 0.5 and 0.125 °C/min runs, latites have a crystal content of  90 vol.%. The phases are: plagioclase, clinopyroxene, glass and iron-bearing oxide (in order of abundance). The variable quench temperatures, investigated by coupling experiments with Pt wire and Pt capsule sample containers in set 2, again did not produce crystallization of trachyte, whereas latitic samples are characterized by  10 vol.% of oxides, pyroxenes and plagioclase (in order of appearance), at temperature < 1000 °C. Effects of (preferential) heterogeneous nucleation on sample holders, of superheating degree, and chemical species loss during cooling are absent for both melt compositions. The difference of solidification paths between these two silicate melts can be ascribed only to their small chemical differences. In comparison with calculated equilibrium conditions all the experimental latitic and trachytic run-products revealed strong kinetic effects, interpretable in the light of the nucleation theory. The glass-forming ability (GFA) of trachyte is higher, whereas their critical cooling rate (Rc) is lower (< 0.125 °C/min), in comparison to latitic melts (Rc > 0.5 °C/min). The experimental results carried out in this study can be applied to lava flows and domes; trachytic lavas are able to flow for longer period with respect to latitic ones in a metastable condition. Glass-rich terrestrial lavas, i.e. obsidians, can be the result of sluggish nucleation kinetics due to the relative high polymerisation of evolved silicate melts.  相似文献   

The Ca-Eskola component in eclogitic clinopyroxene as a function of pressure, temperature and bulk composition: an experimental study to 15 GPa with possible implications for the formation of oriented SiO2-inclusions in omphacite     

Jürgen Konzett  Daniel J. Frost  Alexander Proyer  Peter Ulmer 《Contributions to Mineralogy and Petrology》2008,155(2):215-228

Experiments have been conducted in the P-T range 2.5–15 GPa and 850–1,500°C using bulk compositions in the systems SiO₂–TiO₂–Al₂O₃–Fe₂O₃–FeO–MnO–MgO–CaO–Na₂O–K₂O–P₂O₅ and SiO₂–TiO₂–Al₂O₃–MgO–CaO–Na₂O to investigate the Ca-Eskola (CaEs Ca_0.5□_0.5AlSi₂O₆) content of clinopyroxene in eclogitic assemblages containing garnet + clinopyroxene + SiO₂ ± TiO₂ ± kyanite as a function of P, T, and bulk composition. The results show that CaEs_ss in clinopyroxene increases with increasing T and is strongly bulk composition dependent whereby high CaEs-contents are favoured by bulk compositions with high normative anorthite and low diopside contents. In this study, a maximum of 18 mol% CaEs_ss was found at 6 GPa and 1,350°C in a kyanite-eclogite assemblage garnet + clinopyroxene + kyanite + rutile + coesite. By comparison, no significant increase in CaEs_ss with increasing P could be observed. If the formation of oriented SiO₂-rods frequently observed in eclogititc clinopyroxenes is due to the retrogressive breakdown of a CaEs-component then these textures are a cooling rather than a decompression phenomenon and are most likely to be found in kyanite-bearing eclogites cooled from temperatures ≥750°C. The presence of clinopyroxene with approx. 4 mol% CaEs_ss in an experiment conducted at 2.5 GPa/850°C confirms earlier suggestions based on field data that vacancy-rich clinopyroxenes are not necessarily restricted to ultrahigh pressure metamorphic conditions. Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users.  相似文献   

三峡库区生基包滑坡监测及成果分析          下载免费PDF全文

赵重  李长明  李厚芝 《探矿工程》2008,35(7):32-34,37

生基包滑坡监测属于三峡库区奉节县三期地质灾害监测预警项目之一,该滑坡位于长江左岸,临近人口稠密的安坪乡集镇,地理位置重要。三峡水库175 m蓄水后,其变形破坏特征有何表现？对航道安全运营有无潜在威胁？是否会对滑坡体上的重要建筑及村民生产生活构成危害？针对这些问题,首先分析了滑坡的工程地质特征及主要的影响因素;其次,确立以4种监测手段为主、人工巡查为辅的监测方案;通过对大地变形GPS、深部位移、滑坡推力等几种监测方法的运用及对其成果进行分析研究,以实例说明其在滑坡监测中的应用;再次,结合宏观人工巡查进行对照分析,以充分说明大地变形、深部位移和滑坡推力监测在实际运用中的可行性;最后,根据监测结论提出对生基包滑坡防治的建议。  相似文献   

公用微机硬盘信息保护的一种有效方法   总被引：1，自引：0，他引：1  

张玉彪 《中国海洋大学学报(自然科学版)》1994,(Z2)

介绍一种保护公用微机硬盘信息的有效方法．不仅可以预防各种计算机病毒，更重要的是可以防止人为操作对硬盘信息的破坏。适用于学校等开放性微机实验室的信息安全与保护．  相似文献   

海水叶绿素α浓度遥感测量的实验研究     

张绪琴  傅克忖  牟敦彩 《海洋科学进展》1992,(1)

本文描述了1989年11月在青岛即墨岙山养殖基地所做的海水叶绿素σ浓度遥感测量的基础实验。该实验获得了高浓度叶绿素α含量的海水反射光谱。该反射光谱的特征波段为:波谷在485nm;波峰在450nm 和535nm;“节点”在572nm.根据该实验数据选取了叶绿素α浓度两种双波段估算模式.分析结果表明;两种模式的精度都在50%以上,且双波段反射率的差值法优于双波段反射率比值法.  相似文献   

The European vision for oceans and seas—Social and political dimensions of the Green Paper on Maritime Policy for the EU     

Juan Luis Suárez de Vivero 《Marine Policy》2007

The EU Green Paper on Maritime Policy is the European response to the new generation of ocean strategies based on science, technology and innovation aimed at new objectives, such as the strengthening of security and access to new resources. The European character of the proposal is found in the presence of social, cultural and historical elements, what is called the “European vision”. The viability of a European vision of the oceans and the idea of maritime empire as an extension of the current concept of empire within the general context of emerging ocean strategies are the elements offered up for debate on this European Union initiative.  相似文献   

黄、渤海沿岸海冰测点代表性浅析     

彭垣 《海岸工程》1994,(4)

通过分析１９８０年以后的海冰资料和卫星云图照片，对黄、渤海沿岸１１个海冰测点的历史变迁进行了评述，浅析了测点的优劣及使用资料时应注意的事项。  相似文献   

海上浮动软管的三维静态分析     

孟浩龙  张海明等 《海洋工程》2003,21(1):109-112

提出了海上浮动软管的三维静态分析模型。在四级海情下，对输送柴油的软管求得了解析解，得出了软管在侧向和垂直方向的偏移及其所受的拉力，认为此时的软管是不安全的。  相似文献   

An Experimental Study of Several Special Issues Regarding the Ice Force on Conical Structures     

SHI  Qing-zeng 《中国海洋工程》2002,16(4):561-568

The effect of the cone spacing of a conieal structure on the ice force is studied by model experiments. The ice force reduction coefficient presented in this paper expresses the relationship between the ice force and the arrangement of cones. The experiments prove that the mode of the ice failure before the boundary of upward-downward bending cone (UDBC) is crushing. A conclusion can also be drawn from the experiments that the ice force on the boundary of UDBC is by far less than that on a vertical pile with the same diameter. Moreover, the ice force frequencies on upright and inve-rted cones are obtained under the field condition of the platform JZ20-2, respectively. The results show that the alterna-tion of the ice force on UDBC can hardly induce resonance of platform JZ20-2.  相似文献   

排铅奶粉对在岗交警体内粪铅排除作用     

于广利  管华诗  李桂玲  李辉  陈娥功  周斌  梁强 《中国海洋大学学报(自然科学版)》1997,(2)

研究了青岛市南、市北、四方三区交警在服用排铅奶粉（ＬｅａｄＥｘｃｒｅｔｉｎｇＭｉｌｋＰｏｗ－ｄｅｒ，ＬＥＭＰ）前后，体内粪铅含量变化情况。实验结果表明，服用ＬＥＭＰ后，粪铅含量先呈上升趋势，达到最高值后，又呈下降趋势。在整个实验过程中，粪铅含量四方区最高，而市南区最低。服用ＬＥＭＰ前，三区交警粪铅平均含量为０．６８７ｍｇ／ｋｇ，服用７ｄ后达到峰值（１．９６ｍｇ／ｋｇ，Ｐ＜０．０１），第１５ｄ降到１．６１（ｍｇ／ｋｇ）（Ｐ＜０．０５），表明ＬＥＭＰ能排除体内铅起到预防铅中毒的作用  相似文献