Numerical Modelling of Dissolving and Driving Exploitation of Potash Salt in the Qarhan Piaya——A Coupled Model of Reactive Solute Transport and Chemical Equilibrium in a Multi-component Underground Brine System     

LI Wenpeng 《《地质学报》英文版》2008,(5)

Firstly,the macroscopic chemical equilibrium state of a series of chemical reactions between intercrystal brine and its media salt layer (salt deposit) in Qarhan Salt Lake was studied by using the Pitzer theory.The concept of macroscopic solubility product and its relation with accumulated ore dissolving ratio were presented,which are used in the numerical model of dissolving and driving exploitation of potassium salt in Qarhan Salt Lake.And secondly,with a model forming idea of transport model for reacting solutes in the multi-component fresh groundwater system in porous media being a reference,a two-dimensional transport model coupled with a series of chemical reactions in a multi-component brine porous system (salt deposits) was developed by using the Pitzer theory. Meanwhile,the model was applied to model potassium/magnesium transport in Qarban Salt Lake in order to study the transfer law of solid and liquid phases in the dissolving and driving process and to design the optimal injection/abstraction strategy for dissolving and capturing maximum Potassium/ Magnesium in the mining of salt deposits in Qarban Salt Lake.  相似文献   

城区水文循环机制与改善策略分析          下载免费PDF全文

廖朝轩  詹丽梅  陈家梁  邱奕儒 《水科学进展》2008,19(1):49-53

在城区化过程中,由于人口快速成长且集中,随之而来的建筑物、道路等不透水面密度增加,导致地下水补给减少及破坏水文循环。为了解土地利用方式改变对长期水文量影响,建立一个适宜的城区水循环模式是非常重要的。选定台湾台北的六馆抽水站集水区进行分析,模式参数经过敏感度分析、率定与验证。采用改变不同透水铺面设置比例的方案,评估其对径流量、入渗量、蒸发散量的改变。并分析设置不同比例屋顶雨水贮集系统对地表径流量及供水量的改变。所建立的城区水循环模式是评估土地利用改变造成水文量的改变的一个有效工具,并可提供决策者做为城区土地利用决策的参考。  相似文献   

刘家坪铜—锌矿区古火山机构特征及其地质意义          下载免费PDF全文

李辉 《甘肃地质》2008,(3):27-35

刘家坪黄铁矿型块状硫化物铜-锌矿床是一个面临闭坑的矿山。对矿区刘家坪组火山岩机构的研究,将是进一步寻找矿体的关键。通过野外地质调查及对刘家坪铜-锌矿区刘家坪组火山岩系的岩石矿物组合和结构构造、岩石化学成分、稀土元素地球化学特征的研究,初步确定了矿区古火山机构及其岩相构造的基本特征,建立了火山岩层序、喷发旋回和喷发类型。  相似文献   

松辽盆地白垩纪湖泊水体温度与古气候温度估算   总被引：2，自引：0，他引：2  

申家年  王庆红  何江林  卢双舫 《吉林大学学报(地球科学版)》2008,38(6)

湖泊沉积物沉积的第一场所是湖底,湖底温度的高低影响沉积有机质的保存,也影响湖底下部地层的温度。了解古水体温度尤其是古水底温度情况成为评估松辽盆地白垩系生物气勘探前景的必要研究内容之一。根据已有的古气候研究成果与现今气候对比,得出白垩纪松辽盆地年平均气温约为14~24℃。再根据水库温度的计算方法和利用已有的古纬度及古水深的研究成果计算得出,白垩纪松辽盆地古湖盆水体表面温度为17~25℃;水深大于20 m的深湖区,水底温度为6.2~12.5℃;湖底最深处温度为4.0~11.3℃;青山口组和嫩江组沉积时期,湖水分层明显,湖底温度季节性变化很小且温度较低,约为8℃。湖底的低温对松辽盆地白垩纪生物气勘探是有利的。  相似文献   

Evolution of cool skin and direct air-sea gas transfer coefficient during daytime     

Alexander V. Soloviev  Peter Schlüssel 《Boundary-Layer Meteorology》1996,77(1):45-68

Absorption of solar radiation within the thermal molecular sublayer of the ocean can modify the temperature difference across the cool skin as well as the air-sea gas transfer. Our model of renewal type is based on the assumption that the thermal and diffusive molecular sublayers below the ocean surface undergo cyclic growth and destruction, the heat and gas transfer between the successive burst events are performed by molecular diffusion. The model has been upgraded to include heating due to solar radiation. The renewal time is parameterized as a function of the surface Richardson number and the Keulegan number. A Rayleigh number criterion characterizes the convective instability of the cool skin under solar heating. Under low wind speed conditions, the solar heating can damp the convective instability, strongly increasing the renewal time and correspondingly decreasing the interfacial gas exchange. In the ocean, an additional convective instability caused by salinity flux due to evaporation becomes of importance in such cases. The new parameterization is compared with the cool skin data obtained in the western equatorial Pacific during the Tropical Ocean Global Atmosphere Coupled Ocean Atmosphere Response Experiment in February 1993. In combination with a model of the diurnal thermocline it describes main features of the field data both in nighttime and daytime. Under low wind speed conditions (< 5 m s^-1) diurnal variations of the sea surface temperature due to the formation of a diurnal thermocline were substantially larger than those across the cool skin. Under wind speeds > 5 m s^-1, diurnal variations of the surface temperature due to the variations of the thermal molecular sublayer become more important.  相似文献   

Palaeolimnological studies of the eutrophication of volcanic Lake Albano (Central Italy)     

Andrea Lami  Frank Niessen  Piero Guilizzoni  Julieta Masaferro  Claudio A. Belis 《Journal of Paleolimnology》1994,10(3):181-197

We use palaeolimnological techniques to reconstruct the eutrophication history of a volcanic lake (Lake Albano, central Italy) over the past three centuries. The presence of annual varves down to the bottom of the core (c. 1700 A.D.) indicated the lack of bioturbation and likely long-term meromixis. Sedimentation rates were estimated by varve counts (calcite/diatom couplets), indicating a mean rate of 0.15 cm yr^–1. The reconstruction of eutrophication was traced using past populations of algal and photosynthetic bacteria (through their fossil pigment), and geochemistry, as well as fossil remains of chironomids. Phaeophorbidea and the red carotenoid astaxanthin were used to detect past zooplankton development.The first sign of trophic change related to human activities is datedc. 1870 A.D. From that period onward a sharp increase of authigenic CaCO₃, nitrogen, N:P ratio, and dinoxanthin, a characteristic carotenoid of Chrysophyceae and Dinophyceae, is observed.Chironomid analyses showed the near absence of a deep water fauna throughout the core length. The populations of chironomid larvae are restricted to oxygenated littoral zones. In fact, the few fossil remains found are primarily of littoral origin, representing shallow water midges that were transported to profundal waters. The reduction of total chironomid in the uppermost layers of the core is to be related to human land uses.  相似文献   

Late Quaternary palaeolimnology of a tropical marl lake: Wallywash Great Pond,Jamaica   总被引：1，自引：0，他引：1  

F. A. Street-Perrott  P. E. Hales  R. A. Perrott  J. C. Fontes  V. R. Switsur  A. Pearson 《Journal of Paleolimnology》1993,9(1):3-22

Wallywash Great Pond (17° 57 N, 77° 48 W, 7 m a.s.l.) is the largest perennial lake in Jamaica. It occupies a fault trough within the karstic White Limestone. The Great Pond is a hardwater lake with a pH of 8.2–8.6 and an alkalinity of 3.6–3.9 meq 1^–1. Its chemistry is strongly influenced by the spring discharge from the limestone. The lake water is subject to degassing, evaporation and bicarbonate assimilation by submerged plants and algae, resulting in marl precipitation. A 9.23 m core (WGP2), taken from a water depth of 2.8 m, was analysed for magnetic susceptibility, loss-on-ignition, carbonate content, mole % MgCO₃ in calcite, and stable isotopes in the fine carbonate fraction. The chronology is based on ten¹⁴C and four U/Th dates. Four main sediment types alternate in the core: marl; organic, calcareous mud; organic mud or peat; and earthy, brown, calcareous mud. The marls represent periods of wet/warm climate during sea-level highstands and the organic deposits, shallower, swampy conditions. In contrast, the brown, calcareous muds were laid down when the lake was dry or ephemeral. The last interglacial (120 000- 106 000 yr BP) is represented by three distinct marl units. After a dry interval, stable, wet/warm conditions set in from 106 000 to 93 000 yr BP. A dry/cool climate prevailed between 93 000 and at least 9500 yr BP. Three subsequent cycles of alternating wet and dry conditions culminated in flooding of the basin by the Black River during the late Holocene. These recent events cannot be accurately dated by¹⁴C due to significant and temporally-variable inputs of dead carbon from the springs.  相似文献   

The history and impact of air pollution at Čertovo Lake,southwestern Czech Republic     

Josef Vesely  Heather Almquist-Jacobson  Lisa M. Miller  Stephen A. Norton  Peter Appleby  Aruna S. Dixit  John P. Smol 《Journal of Paleolimnology》1993,8(3):211-231

This multi-disciplinary investigation documents the longterm effects of atmospheric pollution of metals and acids on a geologically sensitive catchment in the umava Mountains, southwestern Czech Republic, a region with a long history of human disturbance. A 30 cm long sediment core (I) from ertovo Lake was analyzed for natural and artifical radionuclides, metals, diatoms, chrysophytes, and pollen in sediments accumulated during the last 200 years. A second core (II), extending to 95 cm, included sediment judged to be free of atmospheric deposition of pollutants associated with the Industrial Revolution. Chronostratigraphic markers include several changes in the pollen assemblages corresponding to well-documented changes in land-use, and distinct distributions of ¹³⁷Cs, ¹³⁴Cs and ²⁴¹Am from weapons testing and the 1986 nuclear accident at Chernobyl, Russia. These markers corroborate the ²¹⁰Pb dating and, together, produce a reliable chronology extending back nearly to 1800 A.D.Stratigraphic profiles of Cu, Pb, and Zn in Core I are unlike any previously reported in the literature. Concentrations of Cu, Pb, and Zn remain generally above 100, 400, and 200 g g^-1, respectively, for the 200 years represented by Core I. These values are unusually high for sediments from a watershed with no known heavy-metal ore bodies. Accumulation rates for Cu, Pb, and Zn, which include both atmospheric and watershed contributions, are also high (ca 1, > 1 and > 1 g cm^-2 yr^-1, respectively) for the same period, although the anthropogenic contribution of Zn rose from nearly zero at 1800 A.D. The Cu and Pb accumulation rates rose dramatically about 1640 A.D.Accumulation rates of anthropogenically-derived Be, a relatively abundant element in the soft coals of the region, are also elevated by about 0.01 g cm^-2 yr^-1 in sediments of this period. Vanadium accumulation rates increased only since 1980 A.D., presumably along with increased consumption of oil.Diatom assemblages illustrate that the lake was acidic (pH between 4.5 and 5) through at least the past 200 years. The pH declined significantly (from ca 5 to 4) between 1960 and 1985 with a slight increase to 4.5 in the last few years. Recent diatom and chrysophyte assemblages suggest high trace metal concentrations, consistent with the present lake-water chemistry.  相似文献   

Paleohydrology and paleoclimate records in a saline prairie lake core: mineral,isotope and organic indicators     

D. R. Van Stempvoort  T. W. D. Edwards  M. S. Evans  W. M. Last 《Journal of Paleolimnology》1993,8(2):135-147

This pilot study examines the potential of obtaining a sedimentary record of paleoenvironmental/climatic/hydrologic conditions for saline Redberry Lake in southern Saskatchewan, Canada. The tools are mineralogy, stable isotopes and pigments. The upper meter of an offshore sediment core contains 10 to 20% by weight aragonite (CaCO₃), which apparently precipitated in the water column. The ¹⁸O and ¹³C of the bulk aragonite (corrected for content of detrital calcite) vary by 4 to 5. Enrichment in ¹⁸O in aragonite is significantly correlated with pigment concentrations (chlorophyll a, phaeophytin). The ¹⁸O and pigment data provide evidence for relatively dry and/or warm conditions and high limnetic productivity for the period 2500 to 1500 yrs B.P. After 1500 B.P., the climate was apparently similar to the present, with two episodes of relatively enhanced productivity, dryness and/or warmth, at around 1000 to 900 and 500 to 200 B.P. During the past century, Redberry Lake has decreased approximately 8 m in depth and its salinity has doubled. No clear sedimentary signal was observed in response to these recent hydrologic trends. These changes have not been associated with a significant climate trend in the region, but may have been induced by land use changes in the catchment.This publication is the third of a series of papers presented at the Conference on Sedimentary and Paleolimnological Records of Saline Lakes. This Conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor for this series.  相似文献   

Palaeoclimatic studies in South Shetland Islands,Antarctica, based on numerous stratigraphic variables in lake sediments     

Svante Björck  Hannelore Håkansson  Siv Olsson  Lena Barnekow  Jan Janssens 《Journal of Paleolimnology》1993,8(3):233-272

The hitherto longest found lake sediment sequence on Byers Peninsula, Livingston Island, South Shetland Islands, was analysed with respect to lithology, chronology, diatoms, Pediastrum, pollen and spores, mosses, mineralogy, and sediment chemistry. During the ca. 5000 year long development the sediments were influenced by frequent tephra fall-outs. This volcanic impact played a major role in the lake's history during two periods, 4700–4600 and 2800–2500 BP, but was of importance during the lake's entire history with considerable influence on many of the palaeoenvironmentally significant indicators. The large and complex data set was analysed and zonated with different types of multivariate analysis. This resulted in a subdivision of the sequence into 8 time periods and 21 variables. Redundancy analysis (RDA) of this data set, both without and with the tephra periods, and with 4–6 of the variables as explanatory environmental variables, reveal that climatic/environmental signals are detectable. The palaeoclimatic picture that emerged out of the tephra noise suggests that the first 100 years were characterized by mild, humid conditions. This was followed by a less mild and humid climate until ca. 4000 BP when a gradual warming seems to have started, coupled with increased humidity. These mild and humid conditions seem to have reached an optimum slightly after 3000 BP. At ca. 2500 BP a distinct climatic deterioration occurred with colder and drier conditions and long seasons with ice cover. This arid, cold phase probably reached its optimum conditions at ca. 1500 BP, when slightly warmer conditions might have prevailed for a while. Except for the modern sample with rather mild climate, the last 1400 years seem to have been fairly arid and cold, and the effects of the frequent volcanic activity during this period is only vaguely seen in the records.  相似文献