The Speciation of (CH3)2Sn2+ in Electrolyte Solution Containing the Major Components of Natural Waters     

Claudia Foti  Antonio Gianguzza  Frank J. Millero  Silvio Sammartano 《Aquatic Geochemistry》1999,5(4):381-398

Hydrolysis constants of dimethyltin(IV) cation, in different salt solutions (CaCl₂: 0.15 I 0.90; MgCl₂: 0.30 I 0.60; NaCl-–NaClO₄, NaCl-–NaNO₃ mixtures: I = 3; NaCl-–Na₂SO₄ mixtures: I = 1 mol dm^-3) were determined by potentiometric ([H⁺]-glass electrode) measurements. These data, together with previous data (De Stefano et al., 1996b) were interpreted in terms of DHT (Debye–Hückel type) and Pitzer equations. The mixed electrolyte solution results also allowed us to obtain and parameters for the Pitzer equation. Calorimetric measurements were made at different ionic strengths in order to find the temperature dependence of hydrolysis constants and of the relative interaction parameters. The body of results allows us to determine the speciation of natural waters in a wide range of ionic strengths and temperatures.  相似文献   

Magma mixing model for the genesis of middle crust in the Izu–Bonin–Mariana arc: evidence from plutonic rocks in the Mineoka-Setogawa ophiolitic mélange,central Japan     

Yuji Ichiyama  Hisatoshi Ito  Akihiro Tamura  Shoji Arai 《International Geology Review》2020,62(4):503-521

ABSTRACT

A Paleogene accretionary complex, the Mineoka–Setogawa belt is distributed adjacent to the northern portion of the collision zone between Honshu and Izu–Bonin–Mariana (IBM) arcs in central Japan, comprising a mélange of ophiolitic fragments of various sizes. The Eocene-Oligocene plutonic rocks in this belt (gabbro, diorite, and tonalite) have been interpreted as fragments brought from the deep crust beneath the IBM arc through tectonic collisions. The geochemical characteristics of the gabbro and associated basaltic dike are similar to those of the Eocene IBM tholeiitic basalt; thus, the gabbro was likely formed via the crystallization of the Eocene tholeiitic basaltic magmas, which was produced by the partial meltings of a depleted mantle wedge. A comparison with experimental results and geochemical modeling indicates that the tonalite was generated by 10–30% dehydration melting of the gabbro. Actually, Eocene–Oligocene felsic veins, which are coeval with the plutonic rocks, occur in the Mineoka–Setogawa gabbro. Plagioclase crystals in the diorite comprise Ca-rich and -poor parts in a single crystal. Their compositional characteristics are consistent with those of plagioclase in the gabbro and tonalite, respectively. The textures and chemical composition of plagioclase indicate that the diorite was formed by the mixing between mafic and silicic magmas. The whole-rock composition of the diorite also indicates the evidence for the mixing between basaltic magmas which were fractionated to variable degrees and homogeneous silicic magma. The mixing model proposed from the first direct observations of the IBM middle crust exposed on the Mineoka–Setogawa belt is applied to the genesis of the Eocene to present intermediate rocks in the IBM arc. If the continental crust were created at intra-oceanic arc settings such as the IBM arc, the magma mixing model would be one of the most likely mechanisms for the genesis of the continental crust.  相似文献   

Recognition of the hydrogeological potential using electrical sounding in the Khemisset-Tiflet region,Morocco          下载免费PDF全文

Fatima Zahra FAQIHI  Anasse BENSLIMANE  Abderrahim LAHRACH  Mohamed CHIBOUT  Mohamed EL MOKHTAR 《地下水科学与工程》2020,8(2):172-179

The low recharge of reservoirs and the increasing demand for water limit the potential of mobilized resources, especially in arid to semi-arid areas like Morocco. Integrated management is essential to safeguard this resource. In respect with this perspective, this work provides the analysis of hydrogeological potential of Khemisset-Tiflet region, which falls within the action area of the Sebou Hydraulic Basin Agency. The basis of our studies was as follows:(1) The interpretation of the existing geoelectric data;(2) application of geophysical methods for non-destructive reconnaissance and their integration into a Geographic Information System(GIS). The analysis demonstrates that: The map of the isohypses and the geoelectric cross-section of the substratum of the superficial roof aquifer show clearly a plunge associated with development of the Paleozoic roof in the South and the direction of flow of the surface water is from south to north, from the upper zone to the north of the El Kansera dam. These conclusions constitute very useful contribution for any resource management projects in this area.  相似文献   

Small-scale mélange fabric between serpentinite block and matrix: Magnetic evidence from the Mitsuishi ultramafic rock body, Hokkaido, Japan     

Rie Morijiri  Mitsuru Nakagawa 《Tectonophysics》2005,398(1-2):33-44

The Mitsuishi ultramafic rock body in Hokkaido, Japan, consists mainly of serpentinized peridotites that originated from a depleted mantle. This study aims to show new evidence of small-scale mélange fabric of serpentinite matrix in the rock body. Each serpentinite block in the serpentine matrix shows large and stable intensities of natural remanent magnetization (NRM). However, the directions of serpentinite blocks' NRM in the matrix are randomly scattered. A Curie temperature (Tc) of 580 °C corresponding to pure magnetite was also observed. Additionally, there is no evidence of heating over 580 °C after serpentinization. The blocks in the matrix must have obtained crystallization remanent magnetization (CRM) during serpentinization. The directions of the blocks' characteristic remanent magnetization (ChRM) are also scattered. It shows that serpentinite blocks were magnetized prior to uplifting. The results of the study indicate that the magnetic carrier of the serpentinite blocks in the matrix is mainly composed of magnetite, and it can keep original magnetization before uplifting. The results also imply that the scattering directions of NRM indicate the presence of small-scale mélange fabric of serpentinite matrix.  相似文献   

新疆塔里木河下游(上段)地区天然草地生态脆弱性研究   总被引：3，自引：0，他引：3  

龚新梅  汪溪远  潘晓玲  师庆东 《干旱区地理》2006,29(2):230-236

塔里木河(以下简称塔河)流域是我国生态脆弱地区之一,其中塔河下游地区为严重脆弱地区。塔河下游地区广大的天然草地主要分布在绿洲-荒漠过渡带,该地带也是一个典型的生态脆弱带。依据有关生态脆弱带评价方法,结合塔河下游天然草地分布的实际状况,建立生态脆弱性评价体系。对垂直于塔河河道不同距离上的草地生态环境进行了分析,得出在距离河道500 m以上的地带草地生态环境表现为中度生态脆弱,<350 m的草地生态环境表现为一般脆弱。评价结果基本符合实际情况,对指导当地合理开发和利用草地资源具有一定的价值。  相似文献   

Age and petrogenesis of plagiogranite intrusions in the Ankara mélange, central Turkey     

Yildirim  Dilek  Peter  Thy 《Island Arc》2006,15(1):44-57

Abstract   The Ankara mélange within the Izmir–Ankara–Erzincan suture zone in north-central Turkey includes ophiolitic fragments that represent the remnants of an oceanic basement evolved between the Sakarya and Kirsehir continental blocks in the early Mesozoic. The serpentinized upper mantle peridotites and lower crustal rocks in these ophiolites are cross-cut by dolerite and plagiogranite dykes, which show mutually intrusive relations indicating their synchronous emplacement into the pre-existing oceanic lithosphere. Zircon dating (U–Pb) of a plagiogranite dyke has revealed a concordia age of ∼179 ± 15 Ma that is interpreted here as the crystallization age of this differentiated rock. A fourth fraction of the zircon separates from this rock has also shown an inherited component greater than 1.7 Ga, possibly derived from the Precambrian core of the Rhodope–Strandja Metamorphic Massif in the Balkan Peninsula. Models for plagiogranite formation were tested and it is concluded that a high extent (<70%) of anhydrous or water-undersaturated, early amphibole-free fractionation of a basaltic melt source may have readily produced the observed REE concentrations for the Ankara mélange plagiogranites. The trace element abundances and other geochemical features of the coeval dolerite dykes are similar to those of the plagiogranites, suggesting a common melt source. The Ta–Nb patterns shown by both the plagiogranite and dolerite dykes are typical of arc-related petrogenesis and can be explained by the addition of slab-derived components to a depleted mantle wedge. The Early Jurassic ophiolitic basement and the dyke intrusions were formed in a back-arc setting between the Paleo- and Neo-Tethyan domains in the eastern Mediterranean region. The Izmir–Ankara–Erzincan Sea developed in this back-arc environment and the related suture zone had a diachronous evolutionary history.  相似文献   

On the characterization of aerosols using the Ångström exponent in the Athens area   总被引：2，自引：0，他引：2  

D.G. Kaskaoutis  H.D Kambezidis  A.D. Adamopoulos  P.A. Kassomenos 《Journal of Atmospheric and Solar》2006,68(18):2147-2163

Ground-based spectroradiometric measurements were taken in the atmosphere of Athens during May 1995 in order to investigate various atmospheric conditions. This study focuses on the Ångström exponent α, which is the slope of the logarithm of the aerosol optical depth (AOD) versus the logarithm of the wavelength, lnλ, and is commonly used to characterize the wavelength dependence of AOD and to provide some basic information on the aerosol size distribution. Using the Volz method, Ångström exponent values, α, were derived in five narrow spectral bands, 340–380, 380–440, 440–500, 500–670 and 670–870 nm. Also using both Volz and least-squares fit methods α values were derived for the whole spectrum 340-870 nm.The results show that α depends strongly on the wavelength interval used due to the curvature of the lnAOD versus lnλ line. Using the spectral dependence of the Ångström exponent and the relationship between α computed in different spectral bands with AOD, an attempt to investigate on the aerosol types is made. The results obtained are rather contradictory and the determination of a dominant aerosol type in the Athens area is not clear. Nevertheless, in the most cases the anthropogenic aerosols seem to be the dominant type with rather significant contributions of coarse-mode particles due to particle growing or due to mixing processes with other aerosol types.  相似文献   

基坑围护设计与实测分析比较     

陈传水  陆少连  鲁绍林 《浙江国土资源》2002,18(1):64-67

通过不同围护软件分析计算并与实测结果进行比较 ,指出土层水平抗力系数“m”取值的关键性 ,基坑开挖是一个动态而复杂的过程 ,理论计算会有一定的差距  相似文献   

Obtaining the free frequencies of the non‐rigid Earth     

Juan Getino  José M. Farto  José M. Ferrándiz 《Celestial Mechanics and Dynamical Astronomy》1998,71(2):95-108

In this paper, the mathematical algorithm elaborated by González, Getino and Farto (1998) is applied to four different nonrigid Earth models, in order to obtain the analytical expressions of the corresponding free frequencies. The solutions are studied, and the contributions of the different considered effects are evaluated. A numerical integration is also carried out, showing the validity of the obtained analytical solutions.  相似文献   

Average attenuation of 0.7–5.0  Hz Lg waves and magnitude scale determination for the region bounding the western branch of the East African Rift     

Richard W. Ferdinand 《Geophysical Journal International》1998,134(3):818-830

The investigation of L g attenuation characteristics in the region bounding the western branch of the East African rift system using digital recordings from a seismic network located along the rift between Lake Rukwa and Lake Malawi is reported. A set of 24 recordings of L g waves from 12 regional earthquakes has been used for the determination of anelastic attenuation, Q _Lg , and regional body-wave magnitude, m _{b Lg} , scale. The events used have body-wave magnitudes, m _b , between 4.6 and 5.5, which have been determined teleseismically and listed in ISC bulletins. The data were time-domain displacement amplitudes measured at 10 different frequencies (0.7–5.0  Hz). Q _Lg and its frequency dependence, η , in the region can be represented in the form Q _Lg = (186.2 ± 6.5)  f  ^(0.78±0.05). This model is in agreement with models established in other active tectonic regions. The L g -wave-based magnitude formula for the region is given by m _{b Lg} = log   A + (3.76 ± 0.38)  log   D − (5.72 ± 1.06), where A is a half-peak-to-peak maximum amplitude of the 1  s L g wave amplitude in microns and D is the epicentral distance in kilometres. Magnitude results for the 12 regional earthquakes tested are in good agreement with the ISC body-wave magnitude scale.  相似文献