Zircon M257 ‐ a Homogeneous Natural Reference Material for the Ion Microprobe U‐Pb Analysis of Zircon     

Lutz Nasdala  Wolfgang Hofmeister  Nicholas Norberg  James M. Martinson  Fernando Corfu  Wolfgang Dörr  Sandra L. Kamo  Allen K. Kennedy  Andreas Kronz  Peter W. Reiners  Dirk Frei  Jan Kosler  Yusheng Wan  Jens Götze  Tobias Häger  Alfred Kröner  John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265

We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for ²⁰⁶pb/²³⁸U and 0.7392 ± 0.0003 for ²⁰⁷pb/²³⁵U. Its ²⁰⁶pb/²³⁸U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ～ 840 μg g^?1 U (Th/U ～ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 10¹⁸ g^?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   

Recommended Values of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu Concentrations in Reference Material IAEA-315 (Marine Sediment) Estimated by Thermal Ionisation Mass Spectrometry, Inductively Coupled Plasma-Mass Spectrometry and Alpha Spectrometry     

Taeko Shinonaga  Helmuth Aigner  Dilani Klose  Peter Spinder  Heinz Fröschl  David Donohue 《Geostandards and Geoanalytical Research》2008,32(1):93-101

The recommended concentrations of ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu in reference material IAEA‐315 (marine sediment) were estimated by three analytical methods: isotope dilution thermal ionisation mass spectrometry (TIMS), isotope dilution inductively coupled plasma‐mass spectrometry (ICP‐MS) and alpha spectrometry. The determination of ²³⁹Pu and ²⁴⁰Pu (^239+240Pu by alpha spectrometry) was carried out with samples from randomly selected bottles using each method. Plutonium‐238 was also measured by alpha spectrometry. A plutonium‐242 reference material was used as a spike for the quantitative analysis. The influence of ²⁴²Pu in the samples was therefore calculated; however, this contribution was less than the range of uncertainty and did not influence the final results. The obtained data were statistically analysed using variance component analysis and paired comparison. The combined standard uncertainties from “method/measurement”, “bottle” and “sub‐sample” were in the order of 3 to 6%. The main contributions to the uncertainty were from the material heterogeneity and from systematic differences between methods. Based on this study with twenty‐seven analyses using 10–14 g sample mass, concentrations of (38 ± 3) Bq kg^?1, (28 ± 3) Bq kg^?1 and (66 ± 4) Bq kg^?1 are proposed as recommended values for ²³⁹Pu, ²⁴⁰Pu and ^239+240Pu, respectively, and (9.5 ± 0.4) Bq kg^?1 for ²³⁸Pu as an information value in reference material IAEA‐315. In mass concentration units, these amount to (16.4 ± 1.2) ng kg^?1, (3.3 ± 0.4) ng kg^?1 and (0.015 ± 0.003) ng kg^?1 for ²³⁹Pu, ²⁴⁰Pu and ²³⁸Pu, respectively. The certified reference materials NIST 4350B and NIST 4354 were also analysed by TIMS for quality assurance of the method used in this study.  相似文献   

基于灰色模糊聚类分析的吉林省黑土结构综合评价   总被引：1，自引：0，他引：1  

秦焱  王清  陈慧娥  范建华 《吉林大学学报(地球科学版)》2008,38(5)

通过对黑土结构指标的定量研究,确定颗粒组成、团聚性和孔隙性3个方面的9个结构指标,建立结构综合评价体系,并采用灰色模糊聚类分析法对黑土的结构进行综合评价,确定吉林黑土的结构质量及肥力状况。结果表明,肥力中-低等样品数量占总量的53%,吉林黑土总体肥力状况不容乐观。以灰色模糊聚类分析法评价土壤结构不需要建立评价的分级标准,可以根据评价对象的实际情况进行最优聚类分析,采用结构性指标对黑土肥力和退化进行评价是可行的。  相似文献   

单侯井田构造发育规律及其对煤层开采的影响     

吴顺福 《中国煤炭地质》2008,20(2):1-5

从区域构造入手,对单侯井田构造进行分析,认为井田内断层发育以走向NW—NE、落差≤5m的小型正断层为主,且主要分布于大中型构造的两侧．特别是在其弧形转折带附近往往形成“羽”状雁列的小断层密集带。断层垂向上多分布于4—7号煤层之间的厚煤层发育区,其严重破坏了煤层的连续及完整性,是影响煤层开采的最主要因素之一。井田褶皱构造相对不发育,以短轴小型背、向斜为主,均属缓波状褶曲,对煤层的开采无影响或影响较小。根据井田地质构造发育程度,对其进行预测及分区评价：井田东部为强烈的构造挤压带,以发育走向NW-近EW—NE向的大型逆掩断层为特点,构造最复杂;井田西北部是相对较轻微的构造挤压带,以发育走向NE向的逆断层为特征,构造较复杂;井田南部以发育近SN或NNW向正断层为主,构造相对简单。评价结果对矿井设计及采区与工作面布置有一定的指导作用。  相似文献   

煤层气储层测井评价有关问题的讨论     

凌毅平  程夏胜 《中国煤炭地质》2008,(12):36-37

煤层气的形成和储层的特性决定了煤层气储层评价的一系列关键参数,这些参数可用常规测井方法直接或间接获得。目前常规测井方法包括自然电位、双侧向（或感应）、微电极、补偿密度、自然伽马、声波时差、声波全波列、中子孔隙率以及井径测井等。选用不同测井方法采用线性回归或体积模型等方法,可以获得煤层气储层评价参数。  相似文献   

青藏高原羌D2井海相烃源岩评价和油源对比   总被引：1，自引：0，他引：1  

刘伟  曾花森 《海相油气地质》2008,13(1):33-36

南羌塘坳陷D2井中侏罗统曲布组海相碳酸盐岩大部分为差—好烃源岩级别,少部分为非烃源岩级别,有机质母质类型以Ⅱ型为主,热演化处于成熟—高成熟阶段。油源对比分析表明,羌D2井曲布组白云岩和含沥青角砾岩中油质沥青来自该组地层灰岩烃源岩,具自生自储性质。同时,中侏罗统雀莫错组灰黑色泥页岩作为烃源层也存在提供油源的可能性。  相似文献   

中国南方含油气区构造—沉积类型及其勘探潜力   总被引：1，自引：0，他引：1  

赵喆  钟宁宁  梁狄刚  陈建平 《海相油气地质》2008,13(1):51-54

南方含油气的复杂构造区根据构造—沉积类型的不同,可将其分为四种类型。通过对不同类型典型含油气区的生烃量及非构造运动天然气散失量的化学动力学计算,认为这四种类型含油气区的油气聚集潜力从好到坏依次为:喜马拉雅运动抬升暴露型、燕山运动抬升暴露型、反复抬升—沉降型和海西—印支运动抬升暴露—后期浅埋型。主要构造运动发生越晚,对油气保存越有利。  相似文献   

封闭体系有机质与有机碳氢氮恢复动力学研究   总被引：3，自引：0，他引：3  

彭平安  秦艳  张辉  刘大永  张善文  隋风贵  李钜源  李政 《海相油气地质》2008,13(2):27-36

在封闭体系的条件下,对典型的Ⅰ、Ⅱ、Ⅲ型干酪根在热演化过程中的损失进行生烃动力学研究,获得了Ⅰ、Ⅱ、Ⅲ型干酪根的总量、有机碳、氢以及氮质量损失动力学参数。用Kinetics软件计算了封闭体系干酪根有机碳丰度、氢碳原子比和氮碳原子比的恢复系数。认为在对高成熟—过成熟干酪根进行生烃评价时,Ⅰ、Ⅲ型干酪根残余有机碳丰度需要进行恢复,而Ⅱ型干酪根残余有机碳丰度不需要恢复。三种类型干酪根的氢碳原子比均需要进行恢复。  相似文献   

雁南煤矿北二采区充水因素及开采影响评价     

于世全  任德平 《中国煤炭地质》2008,20(3):51-52

在全面分析大雁矿业集团公司雁南煤矿北二采区的水文地质条件及煤层开采矿井充水因素的基础上,计算了开采27^1号煤层时导水裂隙带发育高度．得出了北二采区各煤层工作面开采即不会受到上部砂砾含水层的影响,雁南煤矿铁路涵洞以西的胜利河冲击沟也不会受到北二采区的采动塌陷影响的结论。  相似文献   

浙闽山区茶叶生产基地评价的探讨   总被引：6，自引：0，他引：6  

华熙成 《地理研究》1994,13(3):98-103

茶叶基地的评价包括对基地的自然和经济条件的评估,应用系统分析方法,将自然和经济条件进行定量的综合评估,用综合评价值区分基地间的差异,最后定性与定量相结合,提出茶叶生产基地的合理布局.  相似文献