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61.
Stephen B. Castor 《Resource Geology》2008,58(4):337-347
Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor. 相似文献
62.
Lutz Nasdala Wolfgang Hofmeister Nicholas Norberg James M. Martinson Fernando Corfu Wolfgang Dörr Sandra L. Kamo Allen K. Kennedy Andreas Kronz Peter W. Reiners Dirk Frei Jan Kosler Yusheng Wan Jens Götze Tobias Häger Alfred Kröner John W. Valley 《Geostandards and Geoanalytical Research》2008,32(3):247-265
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ~ 840 μg g?1 U (Th/U ~ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn. 相似文献
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We have evaluated several solid state detectors which offer excellent energy resolution at room temperature for soft X-rays. For soft X-rays (< 1 keV to 20 keV), silicon P-intrinsic-N (PIN) and avalanche-mode photodiodes (APD's) have been studied. Using commercially available charge sensitive pre-amplifiers, these photodiodes provide 1 keV resolution without cooling. Their detection efficiencies are limited to about 20 keV and 15 keV, respectively. To overcome this constraint, we have studied thick (1.5 mm) PIN detectors made by Micron Semiconductor Ltd., U.K., as well as compound semiconducting materials with high Z constituents such as CZT and PbI2. PbI2 allows high detection efficiencies of photons up to 100 keV with detectors 100–300 microns thick. These new detectors offer the capability to study the low-energy spectral evolution of Gamma ray bursts (GRBs). A matrix of these detectors could be used as an image plane detector with moderate spatial resolution for imaging. 相似文献
66.
Gamma ray logging is a method routinely employed by geophysicists and environmental engineers in site geology evaluations. Modelling of gamma ray data from individual boreholes assists in the local identification of major lithological changes; modelling these data from a network of boreholes assists with lithological mapping and spatial stratigraphic correlation. In this paper we employ Bayesian spatial partition models to analyse gamma ray data spatially. In particular, a spatial partition is defined via a Voronoi tessellation and the mean intensity is assumed constant in each cell of the partition. The number of vertices generating the tessellation as well as the locations of vertices are assumed unknown, and uncertainty about these quantities is described via a hierarchical prior distribution. We describe the advantages of the spatial partition modelling approach in the context of smoothing gamma ray count data and describe an implementation that may be extended to the fitting of a more general model than a constant mean within each cell of the partition. As an illustration of the methodology we consider a data set collected from a network of eight boreholes, which is part of a geophysical study to assist in mapping the lithology of a site. Gamma ray logs are linked with geological information from cores and the spatial analysis of log data assists with predicting the lithology at unsampled locations. 相似文献
67.
Thomas O. Graff 《The Professional geographer》2006,58(1):54-64
The three largest discount chains, Kmart, Target, and Wal‐Mart, have adopted the supercenter format for expansion. This article examines the locations of and the competition among these supercenters. Wal‐Mart has the greatest number of supercenters and is driving the expansion of the supercenter format. Both Kmart and Target have clustered their supercenters in a small number of metropolitan markets. In contrast to Wal‐Mart and Kmart, Target has focused on a middle‐class rather than a blue‐collar clientele. Now Kmart is struggling following a declaration of bankruptcy. Wal‐Mart has largely defeated its supercenter competitors and now is confronting the major grocery chains for grocery sales. 相似文献
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