Method of Data Reduction and Uncertainty Estimation for Platinum-Group Element Data Using Inductively Coupled Plasma-Mass Spectrometry   总被引：1，自引：0，他引：1  

James C. Ely  Clive R. Neal 《Geostandards and Geoanalytical Research》2002,26(1):31-39

A data reduction method is described for determining platinum-group element (PGE) abundances by inductively coupled plasma-mass spectrometry (ICP-MS) using external calibration or the method of standard addition. Gravimetric measurement of volumes, the analysis of reference materials and the use of procedural blanks were all used to minimise systematic errors. Internal standards were used to correct for instrument drift. A linear least squares regression model was used to calculate concentrations from drift-corrected counts per second (cps). Furthermore, mathematical manipulations also contribute to the uncertainty estimates of a procedure. Typical uncertainty estimate calculations for ICP-MS data manipulations involve: (1) Carrying standard deviations from the raw cps through the data reduction or (2) calculating a standard deviation from multiple final concentration calculations. It is demonstrated that method 2 may underestimate the uncertainty estimate of the calculated data. Methods 1 and 2 do not typically include an uncertainty estimate component from a regression model. As such models contribute to the uncertainty estimates affecting the calculated data, an uncertainty estimate component from the regression must be included in any final error calculations. Confidence intervals are used to account for uncertainty estimates from the regression model. These confidence intervals are simpler to calculate than uncertainty estimates from method 1, for example. The data reduction and uncertainty estimation method described here addresses problems of reporting PGE data from an article in the literature and addresses both precision and accuracy. The method can be applied to any analytical technique where drift corrections or regression models are used.  相似文献   

Use of Chemotaxonomy To Study the Influence of Benzalkonium Chloride on Bacterial Populations in Biodegradation Testing     

Klaus Kümmerer  Ali Al‐Ahmad  Almut Henninger 《洁净——土壤、空气、水》2002,30(4):171-178

Contradictory results are reported for the behaviour of quaternary ammonium compounds (QACs) in sewage treatment plants (STPs). QACs may sorb onto activated sludge. Only little information is available with respect to effects of QACs against bacteria in STPs. Only 5 to 15 % of bacteria present in sewage sludge can be detected by means of culture dependent microbiological methods. The shift of the bacterial populations due to effects of test compounds have not been studied up to now with culture independent methods. The microbial populations shift was studied in situ using culture independent chemotaxonomy profiling ubiquinones and polyamines. Additionally, toxic effects of QACs against bacteria present in the test vessels of the Zahn‐Wellens test (OECD 302 B) were assessed with a toxicity control in the test. The ubiquinone profiles representing changes in Gram‐negative populations mainly showed that the activated sludge was affected only in test vessels containing benzalkonium chloride. According to chemotaxonomy Acinetobacter or/and some members of Pseudomonas spp. have been selected by benzalkonium chloride after some adaptation period (8 to 12 days).  相似文献   

Simulation of individual particle movement in a gravel streambed     

J. Mikael Malmaeus  Marwan A. Hassan 《地球表面变化过程与地形》2002,27(1):81-97

A two‐dimensional simulation model of travel distances of individual particles in a gravel‐bed river is presented. The model is based on a number of rules, which include particle size, entrainment, trajectory, distance of movement and entrapment. Particle interactions are controlled by resistance fields defined about each obstacle and critical elevation defined in the model. Resistance fields, particle dropping and critical elevation rules control particle interactions. The interaction rules cause the particles to develop pebble clusters, stone cells and transverse structures (transverse ribs). The simulated travel distances of individual particles are consistent with reported field results. Individual particle travel distances were simulated using two different models; one without interactions between the individual particles and the stationary bed and one with interactions. The case without interactions demonstrates the random nature of sediment transport, and narrow ranges of travel distances. Wider ranges of travel distances, similar to those for natural situations, were obtained for the cases with interactions. The more intense the interaction between the mobile stones and the stationary ones, the wider the range of distances of travel for a given particle size. Modelling the mean travel distance yielded a result similar to that published previously, which was based on empirical data. Well developed bed‐surface structures were obtained for relatively poorly sorted sediment with intense interactions between particles. Transverse structures developed when relatively large particles were allowed to move. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

The significance of rock structure,lithology and pre‐glacial deep weathering for the shape of intermediate‐scale glacial erosional landforms     

Mats Olvmo  Magnus Johansson 《地球表面变化过程与地形》2002,27(3):251-268

The main landforms within the glacially scoured Precambrian rocks of the Swedish west coast are closely connected to the principal structural pattern and have lately been explained as mainly a result of etch processes, probably during the Mesozoic and with a possible second period of etching during the Neogene. To explore the effect of multiple glacial erosion on the rock surfaces, an island with two different lithologies and with striae from different directions was selected for a detailed study, focusing on the shape of roches moutonnées. Air‐photo interpretation of bedrock lineaments and roches moutonnées combined with detailed field mapping and striae measurements are used to interpret the structural and lithological control on the resulting shape. The study reveals a significant difference in shape between roches moutonnées in augen‐granite and orthogneiss. Low elongated and streamlined roches moutonnées occur in the gneiss area, striated by a Late Weichselian ice flow from the NE. This ice flow is subparallel with both the local dominant trend of topographically well‐expressed joints and the schistosity of the gneiss. Frequently, there are no signs of quarrying on the lee‐sides of the gneiss roches moutonnées and hence they resemble the shape of whalebacks, or ruwares, as typically associated with the exposed basal weathering surface found in tropical areas. The granite roches moutonnées were formed by an older ice flow from the ESE, which closely followed the etched WNW–ESE joint system of the granite. Late Weichselian ice flow from the NE caused only minor changes of the landforms. On the contrary, marks of the early ESE ice flow are poorly preserved in the gneiss area, where it probably never had any large effect as the flow was perpendicular to both schistosity and structures and, accordingly, also to the pre‐glacial relief. The study demonstrates that coincidence between ice flow direction and pre‐glacially etched structures is most likely to determine the effects of glacial erosion. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

Spatial and temporal variability of pore‐water pressures in residual soil slopes in a tropical climate     

R. B. Rezaur  H. Rahardjo  E. C. Leong 《地球表面变化过程与地形》2002,27(3):317-338

It is critical to understand and quantify the temporal and spatial variability in hillslope hydrological data in order to advance hillslope hydrological studies, evaluate distributed parameter hydrological models, analyse variability in hydrological response of slopes and design efficient field data sampling networks. The spatial and temporal variability of field‐measured pore‐water pressures in three residual soil slopes in Singapore was investigated using geostatistical methods. Parameters of the semivariograms, namely the range, sill and nugget effect, revealed interesting insights into the spatial structure of the temporal situation of pore‐water pressures in the slopes. While informative, mean estimates have been shown to be inadequate for modelling purposes, indicator semivariograms together with mean prediction by kriging provide a better form of model input. Results also indicate that significant temporal and spatial variability in pore‐water pressures exists in the slope profile and thereby induces variability in hydrological response of the slope. Spatial and temporal variability in pore‐water pressure decreases with increasing soil depth. The variability decreases during wet conditions as the slope approaches near saturation and the variability increases with high matric suction development following rainfall periods. Variability in pore‐water pressures is greatest at shallow depths and near the slope crest and is strongly influenced by the combined action of microclimate, vegetation and soil properties. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   

非线性地球物理反演方法:回顾与展望   总被引：19，自引：13，他引：19  

杨文采 《地球物理学进展》2002,17(2):255-261

自20世纪90年代以来，非线性地球物理反演方法已走向成熟，这些方法包括线性化迭代法，仿真淬火法，遗传算法及联合反演方法等，线性化迭代反演基于开放物理系统状态发生相变的原理，要进一步改善模型参数化的技术和迭代过程的自组织；仿真淬火法与遗传算法基于自然过程的指数率或生物演化的优生率，可以相互结合以提高解估计的分辨率与置信度；联合反演要结合岩石物理性质的统计规律，才能取得兼容地质与综合方法的应用效果，地球动力学中的反问题不仅涉及偏微分方程系数项的求解，而且涉及初始条件或初始边界的求解，对地球动力学作用过程研究特别重要。  相似文献   

Optimal placement of dampers and actuators based on stochastic approach     

Franklin Y. Cheng  Hongping Jiang  Xiaozhe Zhang Ph.D. Candidate 《地震工程与工程振动(英文版)》2002,1(2):237-249

A general method is developed for optimal application of dampers and actuators by installing them at optimal location on seismic-resistant structures. The study includes development of a statistical criterion, formulation of a general optimization problem and establishment of a solution procedure. Numerical analysis of the seismic response in time-history of controlled structures is used to verify the proposed method for optimal device application and to demonstrate the effectiveness of seismic response control with optimal device location. This study shows that the proposed method for the optimal device application is simple and general, and that the optimally applied dampers and actuators are very efficient for seismic response reduction.  相似文献   

天山西部中山带积雪变化趋势与气温和降水的关系——以巩乃斯河谷为例   总被引：12，自引：9，他引：12  

张丽旭  魏文寿 《地理科学》2002,22(1):67-71

根据位于巩乃斯河谷的天山积雪雪崩研究站近30年来的年最大雪深、月平均气温、月降水量观测记录，用平均差值法、最小二乘法、自回归滑动平均法检验了天山西部中山带积雪、冷季降水、冷季平均气温的变化趋势，结果表明，天山西部中山带积雪呈增加趋势，近30年来年平均增加1.43%，与青藏高原、南极大陆及格陵兰冰盖表面积雪积累增加相一致。天山西部中山带冷季气温和降水的变化趋势也是增加的，其中冷季降水平年平均增加0．12％，而冷季气温升高了0．8℃，积雪与冷季气温之间存在着弱的负相关关系，而与冷季降水呈显著的正相关关系。积雪的增加主要是因为气候变暖引起的冷季降水的增加对积雪增加的贡献大于由于冷季气温升高而造成积雪减少的贡献的结果。  相似文献   

Time-domain, spectral finite-element approach to transient 2-D geomagnetic induction in a spherical heterogeneous Earth     

Zden&#;k Martinec  Mark E. Everett  Jakub Velímský 《Geophysical Journal International》2003,155(1):33-43

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Sectoral Shifts and Occupational Migration in the United States     

Mark E. Reisinger 《The Professional geographer》2003,55(3):383-395

This research is grounded in notions of differential economic restructuring across employment sectors and geographic space, as well as migration selectivity by occupation. A series of unconstrained competing‐destinations models were employed to analyze the response by workers in thirteen occupational categories to sectoral employment change, average wages, and distance. As was hypothesized, workers in occupations that require high levels of education and skills are more responsive, in terms of migration, to economic opportunities in alternative labor‐market areas. However, the results do not support the hypothesis that highly educated and skilled workers migrate longer distances. Further investigation suggests that opportunities for highly educated and skilled workers may be clustering in relatively few areas that are in relatively close proximity.  相似文献