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A. B. Kuznetsov M. A. Semikhatov A. V. Maslov I. M. Gorokhov E. M. Prasolov M. T. Krupenin I. V. Kislova 《Stratigraphy and Geological Correlation》2006,14(6):602-628
New data on Sr-and C-isotopic systematics of carbonate rocks from the Upper Riphean stratotype (Karatau Group of the southern Urals) are obtained for several southwestern sections of the Bashkirian meganticlinorium, which have not been studied before. The results obtained supplement the Sr-and C-isotopic information for the group upper horizons thus detailing chemostratigraphic characterization of the entire succession. Limestone and dolostone samples used to analyze the Sr isotope composition satisfy strict geochemical criteria of the isotopic system retentivity and have been subjected to preliminary treatment in ammonium acetate to remove secondary carbonate phases. Data on 255 samples of carbonate rocks (171 studied for the first time) show that δ13C value varies in the Karatau Group succession from ?2.8 to +5.9 ‰ V-PDB with several in-phase excursions from the general trend in all the sections studied in the area 90 × 130 km. The δ13C variation trend demarcates several levels in the carbonate succession of the Karatau Group suitable for objectives of regional stratigraphy and for C-isotope chemostratigraphic subdivision of the Upper Riphean. The results of Sr isotopic analysis of 121 samples (51 unstudied before) from the Karatau Group imply that rocks in its lower part (the Katav Formation and basal horizon of the Inzer Formation) experienced considerable secondary alterations, while limestones and dolostones of the overlying interval of the group are frequently unaltered. In the “best” samples satisfying geochemical criteria of the isotopic system retentivity, the 87Sr/86Sr initial ratio increases from 0.70521–0.70532 in the lower Inzer deposits to 0.70611 in the upper Min’yar carbonates, decreasing to <0.70600 near the top of the latter. Above the regional hiatus separating the Min’yar and Uk formation, this ratio grows from 0.70533 to 0.70605–0.70609 in the limestone succession of the last formation. 相似文献
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Anton VaksMiryam Bar-Matthews Avner AyalonBettina Schilman Mabs GilmourChris J Hawkesworth Amos FrumkinAaron Kaufman Alan Matthews 《Quaternary Research》2003,59(2):182-193
High-resolution 230Th/234U ages and δ18O and δ13C compositions of speleothems in Ma’ale Efrayim Cave located to the east of the central mountain ridge of Israel enable us to examine the nature of the rain shadow aridity during glacial and interglacial intervals. Speleothem growth occurred during marine glacial isotopic periods, with no growth during the two last marine isotope interglacial intervals and during the peak of the Last Glacial Maximum. This contrasts with speleothem growth in caves located on the western flank of the central mountain ridge, in the Eastern Mediterranean semiarid climatic zone, which continued throughout the last 240,000 yr. Thus, during glacial periods water reached both sides of the central mountain ridge. A comparison of the present-day rain and cave water isotopic compositions and amounts at the Ma’ale Efrayim Cave site with those on the western flank shows that evaporation and higher temperatures on the eastern flank are major influences on isotopic composition and the lack of rainfall. The δ18O and δ13C profiles of the speleothems deposited between 67,000 and 25,000 yr B.P. match the general trends of the isotopic profiles of Soreq Cave speleothems, suggesting a similar source (eastern Mediterranean Sea) and similar climatic conditions. Thus, during glacial periods the desert boundary effectively migrated further south or east from its present-day location on the eastern flank, whereas interglacial periods appear to have been similar to the present, with the desert boundary at the same position. The decrease in overall temperature and a consequent reduction in the evaporation to precipitation ratios on the eastern flank are viewed as the major factors controlling the decay of the rain shadow effect during glacial periods. 相似文献
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利用钾长石粉水热合成13X沸石分子筛的实验研究 总被引:11,自引:0,他引:11
对综合利用钾长石提钾工艺中的重要高附加值副产品13X沸石分子筛的合成进行了实验研究。对福建沙县的钾长石粉加入配料NaCO3进行焙烧实验,确定培烧的最佳工艺参数为:钾长石粉:NaCO3=1:1.30(摩尔比),焙烧温度为845℃,焙烧时间为150min;优化的水热合成条件为M2O/SiO2(mo1)=1.50,H2O/M2O(mo1)=40.0,合成时间为8h,晶种加入量为9.0%。对合成样品化学成分分析、X射线物相分析、红外光谱分析、扫描电镜分析表明,合成13X沸石分子筛结晶完好,性能优良.水热反应经由溶解水合反应和聚合浓缩反应两大阶段。 相似文献
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Records of stable carbon isotopes (δ13C) are presented from cores collected from four San Francisco Bay marshes and used as a proxy for changes in estuary salinity. The δ13C value of organic marsh sediments are a reflection of the relative proportion of C3 vs. C4 plants occupying the surface, and can thus be used as a proxy for vegetation change on the marsh surface. The four marshes included in this study are located along a natural salinity gradient that exists in the San Francisco Bay, and records of vegetation change at all four sites can be used to infer changes in overall estuary paleosalinity. The δ13C values complement pollen data from the same marsh sites producing a paleoclimate record for the late Holocene period in the San Francisco Bay estuary. The data indicate that there have been periods of higher-than-average salinity in the Bay estuary (reduced fresh water inflow), including 1600-1300 cal yr B.P., 1000-800 cal yr B.P., 300-200 cal yr B.P., and ca. A.D. 1950 to the present. Periods of lower-than-average salinity (increased fresh water inflow) occurred before 2000 cal yr B.P., from 1300 to 1200 cal yr B.P. and ca. 150 cal yr B.P. to A.D. 1950. A comparison of the timing of these events with records from the California coast, watershed, and beyond the larger drainage of the Bay reveals that the paleosalinity variations reflected regional precipitation. 相似文献
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Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration 总被引:1,自引:0,他引:1
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Brian McGowran 《中国地质大学学报(英文版)》2005,16(3):200-218
INTRODUCTION Microfossilsaregenerallythemostversatileand “useful”offossilsforbothcorrelationandagedeter minationandpaleoenvironmentalanalysis.Among microfossilstheforaminiferaarepre eminent(Fig. 1).Wefindinthesamesample—beitoutcropor subsurface,onshor… 相似文献
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Bruce J. MacFadden 《Quaternary Research》2005,64(2):113-124
The toxodont megaherbivores Toxodon and Mixotoxodon were endemic to South and Central America during the late Quaternary. Isotopic signatures of 47 toxodont teeth were analyzed to reconstruct diet and ancient habitat. Tooth enamel carbon isotope data from six regions of South and Central America indicate significant differences in toxodont diet and local vegetation during the late Quaternary. Toxodonts ranged ecologically from C3 forest browsers in the Amazon (mean δ13C = −13.4‰), to mixed C3 grazers and/or browsers living either in C3 grasslands, or mixed C3 forested and grassland habitats in Honduras (mean δ13C = −9.3‰), Buenos Aires province, Argentina (δ13C = −8.7‰), and Bahia, Brazil (mean δ13C = −8.6‰), to predominantly C4 grazers in northern Argentina (δ13C = −4.4‰), to specialized C4 grazers in the Chaco of Bolivia (δ13C = −0.1‰). Although these toxodonts had very high-crowned teeth classically interpreted for grazing, the isotopic data indicate that these megaherbivores had the evolutionary capacity to feed on a variety of dominant local vegetation. In the ancient Amazon region, carbon isotope data for the toxodonts indicate a C3-based tropical rainforest habitat with no evidence for grasslands as would be predicted from the Neotropical forest refugia hypothesis. 相似文献