松粉热解脂肪酸生物标志物的特征及其地球化学意义     

吉利明  陈践发  郑建京 《高校地质学报》2002,8(2):141-151

现代松粉的温－压热模拟实验中，产出的轻质烃和氯仿抽提物芳烃馏份的GC－MS分析均检出大量偶数碳优势明显的脂肪酸类分子生物标志物，轻烃主要为C16，C18烷酸及其甲，乙酯，芳烃组分相对比较复杂，包括饱和脂肪酸（酯），不饱和脂肪酸（酯）和脂肪酸内酯，前者碳数分布为C15－，C30，C16，C18碳酸（酯）相对丰度占绝对优势为特征，后者碳数分布为C20-C30,以C26，C28和C30脂肪酸内酯为主，在250℃以下样品中检测出相对丰度较高的不饱和C18碳酸（酯），脂肪酸酯化合物在极低的温度条件下便可排出，并分别在200－300℃和300－400℃之间形成两次产出高峰；花粉内质体中的游离态脂肪酸及不饱和脂肪酸形成低温阶段的第一次高峰；花粉壁脂质结构中的脂肪酸及饱和脂肪酸在较高温度阶段形成第二次高峰，原样及低温样品以脂肪酸酯为主，250℃及其以上温度条件下因水解产生较多的脂肪酸，随温率继续升高，脂肪酸酯易发生脱羰反应而生成链烷烃。400℃以后因强烈降解脂肪酸酯含量大大降低，这与350－450℃之间奇数碳优势正构烷烃在轻质烃和饱和烃中的大量产出相吻合，研究表明，植物花粉是沉积有机质中饱和及不饱和C16，C18脂肪酸酯的重要母源之一。  相似文献   

江苏淮安地区上白垩统含盐地层孢粉组合序列     

杨学英  周山富 《地层学杂志》2002,26(3):193-196,210,T004

江苏淮安地区上白垩统含盐地层含有丰富的孢粉化石 ,可划分为 3个孢粉组合 :第 孢粉组合为 Clas-sopollis- Quantonenpollenites组合 ;第 孢粉组合为 Classopollis- Lythraites组合 ,这二个组合的地质时代均为土伦期 ;第 孢粉组合为 Schizaeoisporites- Beaupreaidites组合 ,时代为土伦晚期—桑顿期。当地此时为干旱炎热的亚热带—热带气侯。  相似文献   

新疆哈密坳陷早三叠世孢粉组合及其地层意义     

尹凤娟  刘洪福  张子福 《地层学杂志》2002,26(4):259-263,271,T002

哈密坳陷早三叠世古生物记录甚少。从哈参 2井 80 1.5 m- 16 39.5 m井段的泥岩中发现了较为丰富的孢粉化石 ,并可划分为两个组合 :L imatulasporites- Cyclogranisporites- Alisporites组合和 L imatulasporites- L undbladis-pora- Taeniaesporites组合。根据孢粉组合特征及其对比 ,两组合的地质时代应属早三叠世 ,这为哈密坳陷确立下三叠统的存在提供了重要的古生物依据  相似文献   

亚洲热带山地垂直植被带对晚第四纪气候变化的响应   总被引：5，自引：2，他引：3  

郑卓 《地理研究》1999,18(1):96-104

过去一直认为热带低海拔地区晚更新世冰期的地表气温基本维持不变。孢粉分析、树线等研究结果证明,从南半球的新几内亚和赤道附近的苏门达腊,一直到我国的热带山地在末次盛冰期垂直植被带下降了500m～1600m不等。植被带的下降不仅仅与温度变化有关,其他的综合因素如高海拔紫外线辐射、大气CO₂浓度等都可能共同影响垂直植被带的分布。综合研究认为,整个亚洲地区年均温度平均下降约4℃的结果与热带非洲和美洲基本一致,并与近两年来热带海洋表层水温的研究结果和近期的气候模拟结果相吻合。  相似文献   

Climatic control of the assemblages of secondary clay minerals in the A-horizon of United States soils     

Michael E. Folkoff  Vernon Meentemeyer 《地球表面变化过程与地形》1985,10(6):621-633

The concentrations (per cent) of secondary clay minerals (mica, vermiculite, montmorillonite, chlorite and kaolinite) in the A-horizon of 99 soil sample sites were entered into a cluster program to determine the common clay mineral assemblages found in U.S. soils. Five major assemblages were identified with the most common assemblage consisting of mica, montmorillonite and kaolinite. A suite of climatic variables was determined for each of the 99 sites, including the water balance variables and Arkley's leaching index. A discriminant analysis was then used to predict the occurrence of a clay assemblage from the climate data. Sixty per cent of the sites could be correctly predicted, although not all assemblages could be predicted equally well; two assemblages could be predicted with 88 and 82 per cent accuracy. The precipitation of the wettest month and Arkley's leaching index accounted for most of the predictive power. Thus this study supports theoretical models which suggest that seasonal moisture supply is an important control of clay genesis and persistence. A residuals analysis indicated that many of the palaeosols in the data set and many of the soils from glacial parent materials possessed clay mineral assemblages not expected on the basis of modern climate.  相似文献   

Late glacial — early holocene palaeosalinity in Alberta,Canada — climate implications     

Michael Hickman  Charles E. Schweger 《Journal of Paleolimnology》1993,8(2):149-161

Palaeolimnological and palynological records from climatically variable central Alberta, Canada, document periods of hypersaline lake conditions indicative of late glacial and early Holocene drought. The sensitivity of palaeolimnological indicators for inferring palaeoclimates is examined by comparing records from two sites at opposite ends of the regional precipitation gradient. Palaeosalinity is identified by the presence of Ruppia pollen, a hypersaline aquatic plant not presently growing in either lake, and diatom assemblages comprising both saline epipelic and planktonic species. Goldeye Lake (52° 27 N; 116° 12 W), in the relatively moist Rocky Mountain Foothills remained saline from its inception before ca 14500 years BP until ca 10400 years BP by which time pioneering forests had replaced tundra vegetation; however, freshwater planktonic diatoms dominated ca 12500 to 11500 years BP. However, dating problems endemic to the Foothills region make this chronology only tentative. Moore Lake (54° 30 N; 110° 30 N), in dry, east-central Alberta contained Ruppia only between ca 9000 and 6000 years BP. Freshwater diatoms dominated until ca 10000 years BP when they were succeeded by taxa characteristic of saline water. The lake remained saline until ca 6000 years BP. The late glacial period of palaeosalinity at Goldeye Lake occurred because the lake was surrounded by Cordilleran and Laurentide glacial ice, and therefore, cut off from moisture sources until the early Holocene by which time significant ice recession had occurred. Factors causing the second period of salinity remain unknown at this time. In contrast, by the early Holocene, Moore Lake was influenced by drought caused by high summer insolation induced by orbital fluctuations. Freshwater conditions were maintained through the Holocene in the Foothills region of west-central Alberta, but occurred consistently only over the last 4000 years in central and east-central Alberta. The warmer, drier climate during the early Holocene did affect lake levels in at least one headwater Foothills lake (Fairfax Lake — 52° 58 N; 116° 34 W). The severity of the drought increased in an easterly direction across the province.This publication is the fourth of a series of papers presented at the Conference on Sedimentary and Palaeolimnological Records of Saline Lakes. This Conference was held August 13–16, 1991 at the University of Saskatchewan, Saskatoon, Canada. Dr. Evans is serving as Guest Editor.  相似文献   

A late Pleistocene long pollen record from Lake Urmia, NW Iran   总被引：4，自引：0，他引：4  

Morteza Djamali  Jacques-Louis de Beaulieu  Madjid Shah-hosseini  Valrie Andrieu-Ponel  Philippe Ponel  Abdolhossein Amini  Hossein Akhani  Suzanne A.G. Leroy  Lora Stevens  Hamid Lahijani  Simon Brewer 《Quaternary Research》2008,69(3):413-420

A palynological study based on two 100-m long cores from Lake Urmia in northwestern Iran provides a vegetation record spanning 200 ka, the longest pollen record for the continental interior of the Near East. During both penultimate and last glaciations, a steppe of Artemisia and Poaceae dominated the upland vegetation with a high proportion of Chenopodiaceae in both upland and lowland saline ecosystems. While Juniperus and deciduous Quercus trees were extremely rare and restricted to some refugia, Hippophaë rhamnoides constituted an important phanerophyte, particularly during the late last glacial period. A pronounced expansion in Ephedra shrub-steppe occurred at the end of the penultimate late-glacial period but was followed by extreme aridity that favoured an Artemisia steppe. Very high lake levels, registered by both pollen and sedimentary markers, occurred during the middle of the last glaciation and late part of the penultimate glaciation. The late-glacial to early Holocene transition is represented by a succession of Hippophaë, Ephedra, Betula, Pistacia and finally Juniperus and Quercus. The last interglacial period (Eemian), slightly warmer and moister than the Holocene, was followed by two interstadial phases similar in pattern to those recorded in the marine isotope record and southern European pollen sequences.  相似文献   

Vegetation responses to climatic variability in the Swiss Southern Alps during the Misox event at the early–mid Holocene transition     

Verushka Valsecchi  Willy Tinner 《第四纪科学杂志》2010,25(8):1248-1258

Sedimentary pollen, charcoal and plant macrofossil analyses with high resolution and precision suggest a strong shift in vegetation composition during the early to mid‐Holocene transition in the upper mountain belt. At Piano mire (1439 m above sea level (a.s.l.), Ticino, Switzerland) forests were dominated by Abies alba during the early Holocene (prior to ca. 8000 cal. a BP). Abrupt collapses of A. alba at ca. 7800–7400 cal. a BP enabled the expansion of the light‐demanding pioneer Betula. Afterwards A. alba populations regained their previous abundance in the forests. Within the dating uncertainties of our record we assume that a unique combination of wet and cold years between 8400 and 7500 cal. a BP led to repeated lethal disadvantages for Abies. Our record of Abies oscillations is in good biostratigraphic agreement with the record that has been used to define the Misox cold event (Pian di Signano, 1540 m a.s.l.), which has been previously correlated with the 8200 cal. a BP event. Given the age estimates of the Abies collapses in our well‐dated record, our results suggest that additional efforts are needed to understand the linkage between the Misox and the 8200 cal. a BP event. They imply a high sensitivity of mountain vegetation far below the tree line (～800 m) to Holocene climatic changes of about 2°C in annual air temperature. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   

Signals of tree volume and temperature in a high‐resolution record of pollen accumulation rates in northern Finland     

F. Mazier  A. B. Nielsen  A. Broström  S. Sugita  S. Hicks 《第四纪科学杂志》2012,27(6):564-574

Pollen accumulation rates (PARs) provide a potential proxy for quantitative tree volume (m³ ha^?1) reconstruction with reliable absolute pollen productivity estimates (APPEs). We obtained APPEs for pine, spruce and birch at their range limits in northern Finland under two temperature periods (‘warm’ and ‘cold’) based on long‐term pollen trap and tree volume records within a 14‐km radius of each trap. APPEs (mean ± SE; × 10⁸ grains m^?3 a^?1) tend to be higher for the ‘warm’ periods (pine 123.8 ± 24.4, birch 528.0 ± 398.4, spruce 434.3 ± 113.7) compared with the ‘cold’ periods (pine 95.5 ± 37.3, birch 317.3 ± 282.6, spruce 119.6 ± 37.6), although the difference is only significant for spruce. Using an independent temperature record and the APPEs obtained, we reconstruct a low‐frequency record of pine volume changes over the last 1000 years at Palomaa mire, where a high‐resolution record of Pinus PARs is available. Five phases are distinguished in the reconstruction: moderate pine volume, AD 1080–1170; high volume, AD 1170–1340; low volume, AD 1340–1630; very low volume, AD 1630–1810; and rising pine volume, AD 1810–1950. These phases do not coincide with periods of high or low June–July–August temperatures, and thus appear to reflect regional variations in tree volume, while high‐frequency changes within each time‐period block show variations in PARs in response to temperature. Copyright © 2012 John Wiley & Sons, Ltd.  相似文献   

Singularities in NCKFMASH (Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O)     

B. WORLEY  & R. POWELL 《Journal of Metamorphic Geology》1998,16(2):169-188

A new petrogenetic grid is presented for the system NCKFMASH (Na₂O–CaO–K₂O–FeO–MgO–Al₂O₃–SiO₂–H₂O), in which Ca is incorporated in garnet, and CaAlNa₋₁Si₋₁ solid solution is considered for both the plagioclase and white-mica structures. A compatibility diagram for plagioclase-bearing metapelitic assemblages within the NCKFMASH system also has been derived. A dominant feature of the NCKFMASH grid is the singularities and associated singular reactions which occur along plagioclase+margarite- and plagioclase+paragonite-bearing univariant equilibria. The singularities represent compositional coplanarities which occur in response to the CaAlNa₋₁Si₋₁ substitution occurring at different rates in plagioclase and white-mica. This is controlled by a fundamental difference in the mixing within the two mineral structures. The singularities give rise to a number of intriguing phase diagram features, including azeotropes. From the results presented here, it is predicted that the occurrence of margarite and paragonite in pelitic rocks is controlled by equilibria related to the singularities. The presence of these white-micas is strongly dependent upon bulk composition, and plagioclase-bearing, margarite/paragonite-free assemblages, typical of Barrovian-type terranes, are predicted for bulk compositions of Mg/(Mg+Fe)≈0.4 and Ca/(Ca+Na)≈0.4 at for example 5.5  kbar.  相似文献