Raman Micro-Spectroscopic Study of Sulfate Ion in the System Na2SO4 – H2O     

ZHU Dongliang  ZHU Ziang  PAN Junyi  DING Junying  NI Pei 《《地质学报》英文版》2015,89(3):887-893

This work aims to quantify sulfate ion concentrations in the system Na₂SO₄-H₂O using Raman micro-spectroscopy.Raman spectra of sodium sulfate solutions with known concentrations were collected at ambient temperature（293 K） and in the 500 cm^₁-4000 cm^-1 spectral region.The results indicate that the intensity of the SO₄^2- band increases with increasing concentrations of sulfate ion.A linear correlation was found between the concentration of SO₄^2-（c） and parameter I₁,which represents the ratio of the area of the SO₄^2- band to that of the O-H stretching band of water（A_s/A_w）:I₁=-0.00102+0.01538 c.Furthermore,we deconvoluted the O-H stretching band of water(2800 cm^-1-3800 cm^-1) at 3232 and 3430 cm^-1 into two sub-Gaussian bands,and then defined Raman intensity of the two sub-bands as A_Bi(3232 cm^-1) and A_B2(3430 cm^-1),defined the full width of half maximum（FWHM） of the two sub-bands as W_B1(3232 cm^-1) and W_B2(3430 cm^-1).A linear correlation between the concentration of SO₄^2-（c） and parameter I₂,which represents the ratio of Raman intensity of SO₄^2-（A_s）(in 981 cm^-1) to(A_B1+A_B2),was also established:I₂=-0.0111+0.3653 c.However,no correlations were found between concentration of SO₄^2-（c） and FWHM ratios,which includes the ratio of FWHM of SO₄^2-（W_s） to W_B1 W_B2 and W_B1+B2(the sum of W_B1 and W_B2),suggesting that FWHM is not suitable for quantitative studies of sulfate solutions with Raman spectroscopy.A comparison of Raman spectroscopic studies of mixed Na₂SO₄ and NaCI solutions with a constant SO₄^2- concentration and variable CI^- concentrations suggest that the I\ parameter is affected by CI^-,whereas the I₂ parameter was not.Therefore,even if the solution is not purely Na₂SO₄-H₂O,SO₄^2- concentrations can still be calculated from the Raman spectra if the H₂O band is deconvoluted into two sub-bands,making this method potentially applicable to analysis of natural fluid inclusions.  相似文献   

基于地球化学组合求异的津巴布韦奇马尼马尼地区成矿预测          下载免费PDF全文

张素荣  赵更新  杨俊泉  贺福清  张燕  俞礽安 《地质找矿论丛》2015,30(S1):172-180

如何有效地解释评价异常是化探找矿取得成功的关键,传统的地球化学异常处理方法一般是以单一元素的含量值与背景值的差异来圈定异常,因子-泛克立格求异模型则建立在矿床主成矿期元素共生组合与地球化学异常之间的对应关系。采用因子-泛克立格模型对津巴布韦东部奇马尼马尼地区进行成矿预测,结果表明:奇马尼马尼地区存在7种元素组合,分别对应于不同的岩性组合,F4和F6元素组合异常可作为区内热液成矿指示标志,与东部塔卡金矿套合程度高。利用该模型圈定了5处找矿远景区,Ⅰ号远景区为铜镍金钛铁矿成矿有利区,Ⅱ号远景区具有与塔卡金矿相似的地球化学组合背景,Ⅲ号、Ⅳ号和Ⅴ号远景区则具寻找热液型金铜矿及多金属矿的潜力。  相似文献   

Operational Evaluation of the Quantitative Precipitation Estimation by a CINRAD-SA Dual Polarization Radar System     

陈超  刘黎平  胡胜  伍志芳  吴翀  张扬 《热带气象学报(英文版)》2020,26(2):176-187

In this paper, the quantitative precipitation estimation based on hydrometeor classification (HCA-QPE) algorithm was proposed for the first operational S band dual-polarization radar promoted by the CINRAD/SA radar of China. The HCA-QPE algorithm, the localized Colorado State University-Hydrometeor Identification of Rainfall (CSU-HIDRO) and Joint Polarization Experiment (JPOLE) algorithms, and the dynamic Z-R relationships based on variational correction QPE (DRVC-QPE) algorithm were evaluated with the rainfall events from March 1 to October 30, 2017 in the Guangdong Province. The results indicated that even though the HCA-QPE algorithm did not use the observed rainfall data for correction, its estimation accuracy was better than that of the DRVC-QPE algorithm when the rainfall rate was greater than 5mm h^(-1); and the stronger the rainfall intensity, the greater the QPE improvement. And the HCA-QPE algorithm worked better than the localized CSU-HIDRO and JPOLE algorithms. This study preliminarily verified the improved accuracy of QPE by a dual-polarization radar system modified from CINRAD-SA radar.  相似文献   

重庆多历时极值降水的概率型优选及应用     

王颖  刘晓冉  程炳岩  孙佳 《气象科学》2020,40(4):560-568

基于重庆34个国家气象站1981—2016年5 min,24 h至3 d的过程最大雨量共18个年极值降水序列,利用线性矩法计算6种常用概率分布函数的模型参数,通过备选最优模型筛选法客观选取各站各历时极值降水的最优概率模型,并将优选结果应用于重庆不同历时百年重现期降水的计算。结果表明:模型优选方法得到的重庆各站不同历时极值降水的最优线型略有差异,广义极值分布占比最大,三参数Weibull分布次之,三参数对数正态分布第三,皮尔逊Ⅲ型和Gumbel分布相当,指数分布最差。最优线型计算的重庆不同历时百年重现期降水的空间分布大值区由短历时的点状分布向长历时的片状分布转变,渝东北的大值中心受地形影响不断向北移动。基于线性矩法的概率模型参数估计及客观的线型优选过程具有较强的可操作性和适应性,可应用于其他工程气象参数的推算中。  相似文献   

1995—2010年静止卫星云量数据检验和评价     

席琳  师春香  赵笔峰  朱晨  黄晓龙 《气象科技》2013,41(1):8-14

对利用FY2和GMS静止气象卫星建立的东亚地区气候数据集(EAGSCDR FY2 and GMS Geostationary Satellite Climate Data Record over East Asia)进行了检验和评估,使用的检验源数据包括中国地面气候资料与国际卫星云气候计划ISCCP D2月平均云量数据集.对由上述3种不同观测手段得到的多年平均总云量的空间分布特征分析结果表明:3种资料的总云量分布形势有较好的一致性,但是在40°N以北地区,ISCCP和EAGSCDR得到的总云量在量值上高于地面观测值.用地面观测资料检验华南及长江流域EAGSCDR的云检测产品的结果表明,总的准确率为82.10％,总漏判率6.85％,总误判率为11.05％,秋冬季节准确率偏低.EAGSCDR与ISCCP云量都是由卫星资料处理得到的,二者差异主要来自算法的不同,检验结果表明,EAGSCDR中的云量产品精度优于ISCCP云量,并且其时间分辨率可达到1 h,空间分辨率达到5 km,由此可见,EAGSCDR的云产品比ISCCP云产品更有优势.  相似文献   

Electronic effects in astrophysically relevant nuclear reactions     

H. Leeb  H. Oberhummer 《Astrophysics and Space Science》1995,228(1-2):87-105

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BOOK REVIEWS     

《The Professional geographer》1982,34(3):352-379

Books reviewed in this article: Aerial Photography and Remote Sensing Aerial photography and image interpretation for Resource Management . DAVID P. PAINE . Analytical Models and Techniques Spatial Processes Models and Applications A. D. CLIFF AND J. K. ORD Quantitative and Statistical Approaches to Geography: A Practical Manual JOHN A. MATTHEWS . Cartography and Maps Map Data Processing . HERBERT FREEMAN AND GOFFREDO G. PIERONI , eds. Computer-assisted Cartography: Principles and Prospects, 1982 . MARK S. MONMONIER . Cultural Navajo Architecture: Forms, History, Distributions . STEPHEN C. JETT AND VIRGINIA E . SPENCER . Rational Landscapes and Humanistic Geography . EDWARD RELPH . Economic The Structure and Control of a State Economy . W. L. L'ESPERANCE . Economic Geography . JAMES O. WHEELER AND PETER O. MULLER . The Myth of the Family Farm: Agribusiness Dominance of U.S. Agriculture . INGOLF VOCELER . Libya: The Experience of Oil . J. A. ALLEN . Geography of Public Finance, Welfare Under Fiscal Federalism and local Government Finance . ROBERT BENNETT . Environmental Management, Resources, and Systems Mountains and Man . LARRY W. PRICE . Environmental Geology . DONALD R. COATES . An Introduction to Environmental Systems . G. H. DURY . The Environment: Chinese and American Views . Edited by LAURENCE J. C. MA AND ALLEN G. NOBLE . Land Use in America . RICHARD H. JACKSON . Medical Conceptual and Methodological Issues in Medical Geography . MELINDA S. MEADE (ed.). Philosophy and Geographic Thought Birds in Egg/Eggs in Bird . GUNNAR OLSSON . PhysicaI Climatology: Selected Applications . J. E. OLIVER . Geomorphological Techniques . ANDREW GOUDIE (ed.). Political Politics, Geography and Behaviour . RICHARD MUIR AND RONAN PADDISON . The State of the World Atlas . MICHAEL KIDRON AND RONALD SECAL . Population The Population of the South . DUDLEY L. POSTON , JR . AND ROBERT H. WELLER , eds. Regional Latin America: Economic Development and Regional Differentiation . ARTHUR MORRIS . Developing the Amazon . EMILIO F. MORAN . Western Europe: A Systematic Human Geography . BRIAN W. ILBERY . Settlement Systems in Sparsely Settled Regions: The United States and Australia . RICHARD E. LONSDALEAND JOHN H. HOLMES , eds. African Perspectives: The Economic Geography of Nine African States . HARM DE BUJ AND ESMOND MARTIN , eds. Rural Nonmetropolitan America in Transition . AMOS H. HAWLEY AND SARA MILLS MAZIE , eds. Social Crime and Environment . R. NORMAN DAVIDSON . The Ghetto: Readings with Interpretations . JOE T. DARDEN , ed. Urban Urban Problems and Planning in the Developed World . MICHAEL PACIONE (ed.) Problems and Planning in Third World Cities . Edited by MICHAEL PACIONE . The City in West Europe . D. BURTENSHAW , M. BATEMAN , AND C. J. ASHWORTH .  相似文献   

长期天气变化与地球自转速度的若干关系   总被引：7，自引：0，他引：7  

钱维宏 《地理学报》1988,(1)

本文应用1820—1983年的地球自转变化率资料,分析出地球自转变化存在准44个月、准11年、准24年和准49年的周期。南方涛动指数的变化,大气活动中心位置的移动,赤道东太平洋海温的异常等,都能从地球自转速度变化思期中找到关系。已经发现,在地转长期(准24年和准49年周期)加(减)速时,南方涛动指数减弱(增强),大气活动中心向西北(东南)移动,非洲干旱区降水偏多(偏少);同时发现:在地转短期(准44个月周期)加(减)速时,赤道东太平洋海温降低(升高)。本文讨论微机在地理学上的应用,介绍可以从英美市场获得的地理软件,并检讨微机在英美地理教学和研究上的一些限制,以促进其在国内地理学上的应用。现存的软件和硬件基本上可以满足地理教学和研究上的大部分需要。随着微机价格的降低,体积的缩小,计算速度、内外存储器容量以及可携带性的增加,其实际应用将会更广。微机已逐渐成为地理教学和研究中不可缺少的工具。  相似文献   

BOOK REVIEWS     

《The Professional geographer》1986,38(3):295-316

Book Reviewed in this article: Marine Resources of Kuwait: Their Role in the Development of Non-oil Resources . Fatimah H. Y. al -Abdul -Razzak Recollections of a Revolution: Geography as Spatial Science . Mark Billinge , Derek Gregory and Ron Martin Entre l'Eden et l'Utopie . Luc Bureau Developments in Political Geography . M. A. Busteed The Elements of Graphing Data . William S. Cleveland Rural Resource Management . Paul J. Cloke and Chris C. Park Third World Atlas . Ben Crow and Alan Thomas Exploitation, Conservation, Preservation: A Geographic Perspective on Natural Resource Use . Susan L. Cutter , Hilary Lambert Renwick, and William H. Renwick . Wine Regions of the Southern Hemisphere . Harm Jan de Blij Regional Development: Problems and Policies in Eastern and Western Europe . George Demko The Geographer at Work . Peter R. Gould Change in the Amazon Basin . John Hemming Geography Since the Second World War . R. J. Johnston and P. Claval Urbanization in China: Town and Countryside in a Developing Economy 1949–2000 A.D. , R. J. R. Kirkby Transport and Communications for Pacific Microstates: Issues in Organisation and Management . Christopher C. Kissling Fluvial Forms and Processes . David Knighton The Urban Millennium . Josef W. Konvitz Technological Transition in Cartography . Mark Stephen Monmonier Field Guide to Soils and the Environment: Applications of Soil Surveys . Gerald W. Olson Northern Australia: The Arenas of Life and Ecosystems on Half a Continent . Don Parkes A Killing Rain: The Global Threat of Acid Rain . Thomas Pawlick From the Family Farm to Agribusiness: The Irrigation Crusade in California and the West, 1850–1931 . Donald J. Pisani Hybrid Maize Diffusion in Kenya . Franz -Michael Rundquist Warning and Response to the Mount St. Helens Eruption . Thomas F. Saarinen and James L. Sell Coastal Geomorphology in Australia . B. G. Thom Tropical Rain Forests of the Far East , 2nd ed . T. C. Whitmore The Dark Side of the Earth . Robert Muir Wood Categorical Data Analysis for Geographers and Environmental Scientists , Neil Wrigley  相似文献   

格网DEM上径流长度计算误差的定量分析   总被引：1，自引：0，他引：1  

刘学军  晋蓓  胡加佩  马锦绢 《武汉大学学报(信息科学版)》2012,37(7):757-761,779

基于格网DEM的径流长度的计算误差主要来源于DEM数据和流径提取算法。通过数据独立的误差分析方法,定量分析流径提取算法模型产生的误差。首先选取5种数学曲面作为模拟DEM数据源,计算出径流长度,以由曲面公式推导的径流长度公式计算的径流长度作为理论真值,通过两者的对比,分析误差及其空间分布。结果表明,汇水区的径流长度计算精度明显高于分水区;分水区的径流长度含有一定的系统误差。  相似文献