矿石中金的在线固相萃取及缝管火焰原子吸收测定   总被引：3，自引：0，他引：3  

徐淑坤  孙励敬 《岩矿测试》1994,13(3):203-206

介绍了将流动注射在线因相萃取预浓集与石英缝管火焰原子吸收相结合测定矿石中金的方法，用ＸＡＤ－８吸附树脂填充的微型柱（１００μｌ）在６ｍｌ／ｍｉｎ的流速下，从０．５ｍｏｌ／ＬＨＣｌ介质的试样溶液中浓集金氯络合物，再用乙醇洗脱，最后由火焰原子吸收检测，在采样频率为１０３样／ｈ的流速下灵敏度提高４７倍，分析精度为１．３％，检出限为１．０μｇ／Ｌ；在６５样／ｈ的采样频率下灵敏度提高９５倍，检出限可达０．７  相似文献   

Geophysical analysis of zonal tidal signals in length of day   总被引：5，自引：0，他引：5  

Benjamin Fong Chao  James B. Merriam  Yoshiaki Tamura 《Geophysical Journal International》1995,122(3):765-775

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Surface wave propagation in a transversely isotropic elastic layer overlying a liquid saturated porous solid half-space and lying under the uniform layer of liquid     

M. D. Sharma  Rajneesh Kumar  M. L. Gogna 《Pure and Applied Geophysics》1990,133(3):523-539

Dispersion of Rayleigh-type surface wave is studied in a homogeneous transversely isotropic elastic layer overlying a nondissipative liquid-saturated porous solid half-space and lying under a uniform layer of homogeneous liquid. The frequency equation in the form of ninth-order determinant is obtained.Special cases have been deduced by reducing the depth of the layers to zero and by changing the transverse isotropic layer to an isotropic layer. Dispersion curves for the phase velocity have been plotted for a particular model.  相似文献   

硅灰石、透辉石在陶瓷中的基本反应和作用   总被引：5，自引：0，他引：5       下载免费PDF全文

戴长禄  张振禹 《地质科学》1990,(4):359-366

本文以硅灰石和高岭石、透辉石和高岭石为端元组分,推导了二元假相图。根据这两个假相图,提出了四个基本固相反应。用这些基本反应以及硅灰石、透辉石的矿物学性质,说明了它们对陶瓷坯体工艺性能的作用。  相似文献   

非理想热力学混合作用对固溶体矿物热容的影响——以斜方顽火辉石-正铁辉石固溶体为例     

沙连堃 《矿物学报》1991,(1)

斜方顽火辉石-正铁辉石(MgSiO_3-FeSiO_3)中Fe~(2+)及Mg~(2+)在M_1和M_2两种非等效位置上进行非理想混合。研究表明,辉石的等压热容(C_p)强烈依赖于组成,呈非线性关系,可表示为: 低温时热容的非理想混合效应显著,随着温度的升高,等温热容曲线(空间热容曲面)从一个极大值点(峰脊)分解为两个极大值点(峰脊),且逐渐趋向于理想混合热容直线(或平面)。  相似文献   

法国Echassieres地区石英网脉中黑钨矿及其共生矿物的固溶体研究   总被引：1，自引：0，他引：1  

王汝成 《岩石矿物学杂志》1991,10(4):369-378

Echassiares石英网脉中的黑钨矿主要系钨锰矿一钨铁矿系列中的铁端员矿物一钨铁 矿，富泥但贫担，当其与妮铁矿共生时，钨铁矿可含8.91% Nb205。在该矿物中常见的元素置换 有:(1)Fe2+→Mn2+;(2)Wg6+Fe2+→Nb5+ +Fe+3 (3) 3W6+ +Fe2+ →4Nb5+。 妮铁矿呈它形，富含Ta. W,Ti。钨铁捉矿以枝状形态位于钨铁矿和妮铁矿之间，形成完整的矿物组合。Beauvoir花岗岩的侵位带入的热液交代钨铁矿是形成这种矿物组合的主要原因。同时,铅钨铁矿中的裂隙带或其边部还局部发生钨锰矿化。  相似文献   

Pyrolysis of immature Torbanite and of the resistant biopolymer (PRB A) isolated from extant alga Botryococcus braunii. Mechanism of formation and structure of torbanite     

C. Largeau  S. Derenne  E. Casadevall  A. Kadouri  N. Sellier 《Organic Geochemistry》1986,10(4-6)

Immature Torbanite and the resistant biopolymer (PRB A) isolated from extant B. braunii were previously compared using bulk spectroscopic methods. In the present work, analysis of 400°C pyrolysis products and pyrolysis residues provided further information on their structure and possible relationships. It appears that such polymers are based upon unbranched, saturated, cross-linked hydrocarbon chains up to C₃₁. In addition to these bridging structures, a substantial part of the alkyl chains is singly bound, as esters of unbranched, saturated or cis unsaturated, even fatty acids. These esters are sterically protected, against chemical degradations, by the network of the bioand geopolymer.Quantitative and qualitative observations derived from 400°C pyrolysis confirm that the chemical structure of PRB A and immature Torbanite are closely related. The pyrolysis residues show a similar evolution and numerous common features are noted, with respect to the nature and the distribution of the major constituents of the pyrolysates (hydrocarbons and fatty acids). Accordingly, Botryococcus provides what seems to be the first example of a close structural relationship between a biopolymer produced in large amounts by an extant alga and the geopolymer of an immature kerogen. The essential role of PRB A in Torbanite formation is ascertained. Moreover, it is found that the resistant biopolymer does not undergo important structural changes during the first stages of diagenesis. Thus, owing to steric protection, the esters of immature Torbanite show a distribution quite close to the one of PRB A esters, with exclusively even constituents and a large contribution of unsaturated acids.Recent observations pointed to the possible genesis of some algal kerogens principally by selective preservation of resistant macromolecules. Such a type of formation is clearly predominant in Torbanite, where the bulk of the fossil organic matter corresponds to a selectively preserved and weakly altered, resistant biopolymer, while incorporation of lipids into the kerogen structure during diagenesis seems to play a minor role.  相似文献   

甘肃西部地区高放废物处置库场址预选调查   总被引：1，自引：0，他引：1  

刘林清  余运祥 《华东地质学院学报》1995,18(1):33-39

本文根据高放废物处置库场址选择的基本要求，对区域地质及深部构造特征、新构造运动及地震分布规律进行了调查，确定北山南带地区为稳定区。在稳定区内根据处置库有利围岩的出露情况，结合岩体工程地质特征分析，初步选出了４个以花岗岩为主体的场址预选区。经综合分析，认为在４个场址预选区中，以Ｉ号预选区的条件最优，其次是Ⅱ号预选区，再次是Ⅲ号和Ⅳ号预选区。场址区的最后确定尚待进一步调查和论证。  相似文献   

Emission of aliphatic amines from animal husbandry and their reactions: Potential source of N2O and HCN     

Gunnar W. Schade  Paul J. Crutzen 《Journal of Atmospheric Chemistry》1995,22(3):319-346

We measured the emissions of volatile aliphatic amines and ammonia produced by the manure of beef cattle, dairy cows, swine, laying hens and horses in livestock buildings. The amine emissions consisted almost exclusively of the three methylamines and correlated with those of ammonia. The molar emission ratios of the methylamines to ammonia, and data on NH₃ emissions from animal husbandry in Europe, together with global statistics on domestic animals, were used to estimate the global emissions of amines. Annual global methylamine-N input to the atmosphere from animal husbandry in 1988 was 0.15±0.06 TgN (Tg=10¹² g). Almost 3/4 of these emissions consisted of trimethylamine-N. This represents about half of all methylamine emissions to the atmosphere. Other sources are marine coastal waters and biomass burning.Possible reaction pathways for atmospheric methylamines are shown. Among various speculative but possible products N₂O and HCN are of interest because the emission of methylamines could contribute to the global budgets of these compounds. Maximum atmospheric N₂O production from methylamines are below 0.4 Tg N/year, which is less than 10% of the annual N₂O growth rate. Although we do not expect the methylamine emissions to contribute in a major way to the atmospheric N₂O budget, more studies are needed to establish this conclusion beyond doubt. Similar conclusions hold for HCN.  相似文献   

阳朔铅锌矿的环境现状与尾矿废水处理模式分析   总被引：3，自引：0，他引：3  

覃朝科  李艺  韦松  黄广宇 《矿产与地质》2005,19(1):99-102

阳朔铅锌矿的环境污染因素主要是采矿废石、选矿尾矿、废液等，主要有害物质为Pb、Cd等重金属元素和残余的选矿药剂，对环境特别是下游环境存在潜在危害。该矿通过建设规范化的尾矿库和废水处理系统，采用尾矿浆由坝体向内(上游)倒流排放沉淀尾矿砂、废水经二级多池串联自然沉淀澄清的处理模式，增强了坝体稳定安全；不使用或极少使用化学沉淀药剂，降低了治污成本。废水处理后，水质清澈无异味，达到国家工业生产污水处理二级排放标准。  相似文献