鲕粒白云岩内部溶蚀及孔隙非均质性演化研究     

谢淑云  雷蕾  焦存礼  何治亮  鲍征宇  马佳怡  张殿伟  彭守涛 《现代地质》2019,33(6):1174-1187

在地表和埋藏条件下溶蚀作用形成的次生孔隙是碳酸盐岩油气储层重要的储集空间。为探究孔隙的溶蚀改造机理及其控制因素,通过柱塞样,开展了0.2%的乙酸环境中鲕粒白云岩的溶蚀实验,实验温度和压力范围分别为40~160 ℃和10~50 MPa。实验采取连续取样获得溶液中Ca²⁺与Mg²⁺离子含量,通过CT 成像技术获取溶蚀反应前后孔隙图像并运用分形与多重分形方法定量分析孔隙在二维和三维空间上的非均质性。研究表明,溶蚀过程中,鲕粒白云岩溶蚀液中[Ca²⁺+Mg²⁺]浓度在实验开始时最低,之后稳步上升并在120 ℃、40 MPa时达到最大值,而后缓慢下降,溶蚀窗范围出现在70 ℃(20 MPa)~120 ℃(40 MPa)之间。二维和三维微观孔隙结构在空间上的分布具有显著的多重分形特征,溶蚀作用使得孔隙的不规则性减少、孔隙的奇异范围缩减。这些结果对于认识近地表和深埋藏条件下溶蚀作用对碳酸盐岩储层孔隙的改造强度及孔隙的动态演化规律具有重要的理论及实际意义。  相似文献   

月基InSAR观测地球大尺度形变能力的初步研究——以固体地球垂向潮汐形变为例     

马成龙  陈晓东  江利明  孙和平  徐建桥  董景龙  李德伟 《地球科学进展》2019,(2):164-174

从合成孔径雷达干涉测量的原理出发,针对月基InSAR观测地球宏观物理现象的大尺度、连续性、长期性、动态观测等特点,首次以固体地球垂向潮汐形变为例对月基InSAR观测地球大尺度形变现象进行了仿真模拟,分析了该技术的远程大范围观测能力。根据固体地球垂向潮汐形变的大尺度分布特征和月基雷达的超大幅宽的观测特点,采用简化月基雷达观测几何模型,选定经纬跨度均为50°的中低纬区域为模拟测区,并计算了月基雷达重访周期与雷达波束扫过选定模拟测区内各点时的垂向潮汐形变,将形变计算结果进行时间差分,得到差分相对垂向潮汐形变,即是月基InSAR可观测到的垂向潮汐形变。模拟数值结果表明,月基雷达的重访周期约为24.8 h,在30天内各点的差分垂向潮汐形变可达30 cm。鉴于目前月基InSAR的理论形变观测精度达到厘米级,因此理论上用月基InSAR技术能够观测到模拟测区固体地球大范围垂向潮汐整体形变,也能利用观测数据研究地球潮汐大范围时间和空间变化特征;另一方面模拟结果也可为月基SAR观测其他地球宏观物理现象的参数设计与模拟提供参考。  相似文献   

High‐precision Determination of Gold Mass Fractions in Geological Reference Materials by Internal Standardisation     

Huai Cheng  Zaicong Wang  Kang Chen  Keqing Zong  Zongqi Zou  Tao He  Zhaochu Hu  Mario Fischer‐Gdde  Yanhong Liu 《Geostandards and Geoanalytical Research》2019,43(4):663-680

Determination of gold abundances in natural rock is critical for applications, but very challenging. Here, we report a method for determining gold with a very low mass fraction (> 0.01 ng g^?1) in rocks. The method involves Carius tube digestion with reverse aqua regia, chromatographic separation to remove most of the sample matrix and measurement by high‐sensitivity ICP‐MS. The mono‐isotopic element gold was quantified by external calibration using an internal standardisation of gold to platinum that was precisely determined by isotope dilution. The method is robust and the obtained results are indistinguishable (< 5–10%, 2s) from those independently obtained by a standard addition technique on the same solution. The results from reference materials TDB‐1 and GPt‐2 are consistent with the certified values and those determined by HF‐aqua regia digestion, confirming the validity of the method. TDB‐1 (n = 20), GPt‐2 (n = 6), BHVO‐2 (n = 9) and other mafic RMs are homogenous for gold (10–20%, 2s) at the 2 g test portion level; however, sample heterogeneity affects some RMs. Gold and platinum‐group elements also display different extents of sample heterogeneity for different RMs. Given the homogeneity observed for TDB‐1, GPt‐2 and BHOV‐2, they are recommended as well‐suited RMs for inter‐laboratory comparison studies of gold.  相似文献   

Molecular and isotopic fractionation of light hydrocarbons between oil and gas phases     

B. Carpentier  P. Ungerer  I. Kowalewski  C. Magnier  J.P. Courcy  A.Y. Huc 《Organic Geochemistry》1996,24(12):1115-1139

Oil-gas phase equilibria is likely to represent one of the main causes of observed compositional heterogeneities in fields. Our research has been focused mainly on the light C₁₄-hydrocarbons fraction and can be divided into two parts. The first part was performed with a fluid mixture of a Middle East crude oil and a synthetic gas, and includes PVT experiments, high resolution-gas chromatography (HR-GC) and ¹³C gas chromatography-combustion-isotopic ratio mass spectrometry (GC-C-IR-MS) analyses. Our observations show that under a given set of PT conditions there is a preferential separation of aromatics into the oil phase and isoalkanes into the gas phase. Moreover, the data from ¹³C GC-C-IRMS suggest a small isotopic fractionation between the two phases, with the gas being relatively isotopically lighter. The second part is theoretical, and uses Equation of State (EOS) calculations which successfully simulate the previous experiment.  相似文献   

土地利用空间格局的图形信息表达初步研究   总被引：15，自引：1，他引：15  

刘湘南  许红梅 《地理研究》2001,20(6):752-760

土地利用表现为在自然要素和人类活动的综合作用下的一系列异质性的图形。不同的土地利用空间格局的地学形成机制、生态功能、演化方向和对环境的影响各不相同,其空间图形也千差万别。运用景观生态学原理、地理图形信息理论,以位于中国北方农牧交错带的吉林省前郭县作为研究区,在GIS的支持下,归纳、抽象了各主要土地利用类型斑块形状及其描述参数,探讨了土地利用空间格局和空间分布的表达方法(VCM曲线),实现了土地利用空间格局图形的数量化描述和分析。其结果为从图形信息机理的角度研究土地利用格局的地学形成机制及生态功能、时空演化等方面奠定了基础  相似文献   

Historical 1942 Ecuador and 1942 Peru subduction earthquakes and earthquake cycles along Colombia-Ecuador and Peru subduction segments     

Jennifer L Sennson  Susan L. Beck 《Pure and Applied Geophysics》1996,146(1):67-101

Two large shallow earthquakes occurred in 1942 along the South American subduction zone inclose proximity to subducting oceanic ridges: The 14 May event occurred near the subducting Carnegie ridge off the coast of Ecuador, and the 24 August event occurred off the coast of southwestern Peru near the southern flank of the subducting Nazca ridge. Source parameters for these for these two historic events have been determined using long-periodP waveforms,P-wave first motions, intensities and local tsunami data.We have analyzed theP waves for these two earthquakes to constrain the focal mechanism, depth, source complexity and seismic moment. Modeling of theP waveform for both events yields a range of acceptable focal mechanisms and depths, all of which are consistent with underthrusting of the Nazca plate beneath the South American plate. The source time function for the 1942 Ecuador event has one simple pulse of moment release with a duration of 22 suconds, suggesting that most of the moment release occurred near the epicenter. The seismic moment determined from theP waves is 6–8×10²⁰N·m, corresponding ot a moment magnitude of 7.8–7.9. The reported location of the maximum intensities (IX) for this event is south of the main shock epicenter. The relocated aftershcks are in an area that is approximately 200 km by 90 km (elongated parallel to the trench) with the majority of aftershocks north of the epicenter. In contrast, the 1942 Peru event has a much longer duration and higher degree of complexity than the Ecuador earthquake, suggesting a heterogeneous rupture. Seismic moment is released in three distinct pulses over approximately 74 seconds; the largest moment release occurs 32 seconds after rupture initiation. the seismic moment as determined from theP waves for the 1942 Peru event is 10–25×10²⁰N·m, corresponding to a moment magnitude of 7.9–8.2. Aftershock locations reported by the ISS occur over a broad area surrounding the main shock. The reported locations of the maximum intensities (IX) are concentrated south of the epicenter, suggesting that at least part of the rupture was to the south.We have also examined great historic earthquakes along the Colombia-Ecuador and Peru segments of the South American subduction zone. We find that the size and rupture length of the underthrusting earthquakes vary between successive earthquake cycles. This suggests that the segmentation of the plate boundary as defined by earthquakes this century is not constant.  相似文献   

尕斯库勒油田N1—N2^1油藏砂西区Ⅱ油组储层非均质特征评价   总被引：1，自引：0，他引：1  

蒋晓红 《四川地质学报》2003,23(3):160-163

储层非均质特征评价是储层特征研究很重要的一部分内容，储层非均质特征是描述储层的参数变化及非均质特性，非均质性的强弱直接影响着开发方案的设计和实施。本文以尕斯库勒油田N1—N2^1油藏砂西区Ⅱ油组为例，研究储层非均质性特征。用来描述储层非均质性的特征参数主要有：连通系数、重叠系数、夹层厚度、夹层频数以及均值、最大值、最小值、变异系数、级差、非均质系数。  相似文献   

A new surface runoff parameterization with subgrid-scale soil heterogeneity for land surface models   总被引：7，自引：0，他引：7  

Xu Liang  Zhenghui Xie 《Advances in water resources》2001,24(9-10)

Soil heterogeneity plays an important role in determining surface runoff generation mechanisms. At the spatial scales represented by land surface models used in regional climate model and/or global general circulation models (GCMs) for numerical weather prediction and climate studies, both infiltration excess (Horton) and saturation excess (Dunne) runoff may be present within a studied area or a model grid cell. Proper modeling of surface runoff is essential to a reasonable representation of feedbacks in the land–atmosphere system. In this paper, a new surface runoff parameterization that dynamically represents both Horton and Dunne runoff generation mechanisms within a model grid cell is presented. The new parameterization takes into account of effects of soil heterogeneity on Horton and Dunne runoff. A series of numerical experiments are conducted to study the effects of soil heterogeneity on Horton and Dunne runoff and on soil moisture storage under different soil and precipitation conditions. The new parameterization is implemented into the current version of the hydrologically based variable infiltration capacity (VIC) land surface model and tested over three watersheds in Pennsylvania. Results show that the new parameterization plays a very important role in partitioning the water budget between surface runoff and soil moisture in the atmosphere–land coupling system. Significant underestimation of the surface runoff and overestimation of subsurface runoff and soil moisture could be resulted if the Horton runoff mechanism were not taken into account. Also, the results show that the Horton runoff mechanism should be considered within the context of subgrid-scale spatial variability of soil properties and precipitation. An assumption of time-invariant spatial distribution of potential infiltration rate may result in large errors in surface runoff and soil moisture. In addition, the total surface runoff from the new parameterization is less sensitive to the choice of the soil moisture shape parameter of the distribution.  相似文献   

Nd-isotope systematics of ∼2.7 Ga adakites, magnesian andesites, and arc basalts, Superior Province: evidence for shallow crustal recycling at Archean subduction zones     

Ali Polat  Robert Kerrich 《Earth and Planetary Science Letters》2002,202(2):345-360

An association of adakite, magnesian andesite (MA), and Nb-enriched basalt (NEB) volcanic flows, which erupted within ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts, has recently been documented in ∼2.7 Ga Wawa greenstone belts. Large, positive initial ?_Nd values (+1.95 to +2.45) of the adakites signify that their basaltic precursors, with a short crustal residence, were derived from a long-term depleted mantle source. It is likely that the adakites represent the melts of subducted late Archean oceanic crust. Initial ?_Nd values in the MA (+0.14 to +1.68), Nb-enriched basalts and andesites (NEBA) (+1.11 to +2.05), and ‘normal’ intra-oceanic arc tholeiitic to calc-alkaline basalts and andesites (+1.44 to +2.44) overlap with, but extend to lower values than, the adakites. Large, tightly clustered ?_Nd values of the adakites, together with Th/Ce and Ce/Yb systematics of the arc basalts that rule out sediment melting, place the enriched source in the sub-arc mantle. Accordingly, isotopic data for the MA, NEBA, and ‘normal’ arc basalts can be explained by melting of an isotopically heterogeneous sub-arc mantle that had been variably enriched by recycling of continental material into the shallow mantle in late Archean subduction zones up to 200 Ma prior to the 2.7 Ga arc. If the late Archean Wawa adakites, MA, and basalts were generated by similar geodynamic processes as their counterparts in Cenozoic arcs, involving subduction of young and/or hot ocean lithosphere, then it is likely that late Archean oceanic crust, and arc crust, were also created and destroyed by modern plate tectonic-like geodynamic processes. This study suggests that crustal recycling through subduction zone processes played an important role for the generation of heterogeneity in the Archean upper mantle. In addition, the results of this study indicate that the Nd-isotope compositions of Archean arc- and plume-derived volcanic rocks are not very distinct, whereas Phanerozoic plumes and intra-oceanic arcs tend to have different Nd-isotopic compositions.  相似文献   

Numerical models of the evolution of accretionary wedges and fold‐and‐thrust belts using the distinct‐element method     

D. R. Burbidge  J. Braun 《Geophysical Journal International》2002,148(3):542-561

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