Determination of cadmium(II), copper(II), manganese(II) and nickel(II) species in Antarctic seawater with complexing resins   总被引：1，自引：0，他引：1  

Raffaela Biesuz  Giancarla Alberti  Girolamo D'Agostino  Emanuele Magi  Maria Pesavento 《Marine Chemistry》2006,101(3-4):180-189

The strong species of cadmium(II), copper(II), manganese(II) and nickel(II) in an Antarctic seawater sample are investigated by a method based on the sorption of metal ions on complexing resins. The resins compete with the ligands present in the sample to combine with the metal ions. Two resins with different adsorbing strengths were used. Very stable metal complexes were investigated with the strong sorbent Chelex 100 and weaker species with the less strong resin, Amberlite CG-50. Strong species were detected for three of the considered metal ions, but not for Mn(II). Cu(II) is completely linked to species with a side reaction coefficient as high as log α_M(I) = 11.6 at pH = 7.3. The ligand concentration was found to be similar to that of the metal ion, and the conditional stability constant was around 10²⁰ M^− 1. In the considered sample, only a fraction of the metal ions Cd(II) and Ni(II) is bound to the strong ligands, with side reaction coefficients equal to log α_M(I) = 5.5 and 6.5 at pH = 7.3 for Cd(II) and Ni(II), respectively. These findings were confirmed by the test with the weaker sorbent Amberlite CG-50. It can be calculated from the sorption equilibria that neither Mn(II) nor Ni(II) is adsorbed on Amberlite CG-50 under the considered conditions and, in fact, only a negligible fraction of Mn(II) and Ni(II) was adsorbed. A noticeable fraction of Cd(II) was adsorbed on Amberlite CG-50, meaning that cadmium(II) is partially linked to weak ligands, possibly chloride, while no copper(II) was adsorbed on this resin, confirming that copper(II) is only combined in strong species. These results are similar, but not identical, to those obtained for other seawater samples examined in previous investigations.  相似文献   

Bonamia exitiosa epizootic in Ostrea chilensis from Foveaux Strait, southern New Zealand between 1986 and 1992     

Cranfield  H.J.; Dunn  A.; Doonan  I.J.; Michael  K.P. 《ICES Journal of Marine Science》2005,62(1):3-13

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The trophic spectrum: theory and application as an ecosystem indicator     

Gascuel  Didier; Bozec  Yves-Marie; Chassot  Emmanuel; Colomb  Audrey; Laurans  Martial 《ICES Journal of Marine Science》2005,62(3):443-452

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Variability in maturity and growth in a heavily exploited stock: cod (Gadus morhua L.) in the Irish Sea     

Armstrong  M.J; Gerritsen  H.D; Allen  M; McCurdy  W.J; Peel  J.A.D 《ICES Journal of Marine Science》2004,61(1):98-112

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Morphodynamics of intertidal bars on a megatidal beach, Merlimont, Northern France     

E.J. Anthony  F. Levoy 《Marine Geology》2004,208(1):73-100

The morphology, bedforms and hydrodynamics of Merlimont beach, in northern France, characterised by intertidal bars and a spring tidal range of 8.3 m, were surveyed over a 10-day experiment with variable wave conditions that included a 2-day storm with significant wave heights of up to 2.8 m. The beach exhibited two pronounced bar-trough systems located between the mean sea level and low neap tide level. Waves showed a cross-shore depth modulation, attaining maximum heights at high tide. The mean current was characterised dominantly by strong tide-induced longshore flows significantly reinforced by wind forcing during the storm, and by weaker, dominantly offshore, wave-induced flows. Vertical tidal water-level variations (tidal excursion rates) showed a bimodal distribution with a peak towards the mid-tide position and low rates near low and high water. The two bar-trough systems in the mid-tide zone remained stable in position during the experiment but showed significant local change. The absence of bar migration in spite of the relatively energetic context of this beach reflects high macro-scale bar morphological lag due to a combination of the large vertical tidal excursion rates in the mid-tide zone, the cross-shore wave structure, and the pronounced dual bar-trough system. The profile exhibited a highly variable pattern of local morphological change that showed poor correlation with wave energy levels and tidal excursion rates. Profile change reflected marked local morphodynamic feedback effects due mainly to breaks in slope associated with the bar-trough topography and with trough activity. Change was as important during low wave-energy conditions as during the storm. Strong flows in the entrenched troughs hindered cross-shore bar mobility while inducing longshore migration of medium-sized bedforms that contributed in generating short-term profile change. The large size and location of the two pronounced bars in the mid-tide zone of the beach are tentatively attributed respectively to the relatively high wave-energy levels affecting Merlimont beach, and to the cross-shore increase in wave height hinged on tidal modulation of water depths. These two large quasi-permanent bars probably originated as essentially breakpoint bars and are different from a small bar formed by swash and surf processes in the course of the experiment at the mean high water neap tide level, which is characterised by a certain degree of tidal stationarity and larger high-tide waves.  相似文献   

2000年夏季莱州湾生态环境要素的分布特征   总被引：1，自引：0，他引：1  

高会旺  吴德星  白洁  石金辉  李正炎  江文胜 《中国海洋大学学报(自然科学版)》2003,33(2):185-191

论文依据 2 0 0 0年夏季 8月 2 9日至 9月 2日莱州湾的 1次综合性生态环境调查资料 ,给出了表、中、底 3层的平均温度、盐度、主要营养盐浓度及其比例和叶绿素 a浓度 ,分析了莱州湾的温盐结构、主要营养盐和叶绿素 a的分布特征。由于莱州湾的水深较浅 ,各要素的垂直分布都比较均匀。生态环境要素的水平分布表现为小清河口为高温、低盐、高营养盐和高叶绿素 a浓度区 ,小清河口东测的湾顶区域为高温、高盐、相对低的营养盐和叶绿素 a浓度区。此次观测到的盐度较 1997年以前有明显升高。莱州湾各层平均的 N/ P和 Si/ N分别为 16.73和 1.67,都比 1998～ 1999年渤海中部的值大 ,但 N/ P比 1992 ,1995和 1996年莱州湾的 N/ P明显偏低。叶绿素 a浓度与硅酸盐浓度之间有较好的相关关系 (α=0 .0 1) ,表、中、底 3层叶绿素 a浓度同硅酸盐浓度的线性相关系数分别为 :0 .5 4 ,0 .68和 0 .67  相似文献   

台湾海峡毛颚动物分布的初步研究   总被引：9，自引：0，他引：9  

蒋玫  王云龙  徐兆礼 《台湾海峡》2003,22(2):150-154

本文分析了台湾海峡毛颚动物的种类组成、数量分布特征，并就其与环境因素的关系进行了初步探讨．结果显示与台湾海峡西部、东海等邻近海域相比，本区毛颚动物具种数少，数量小，季节变化幅度较小等特点．它的数量分布状况与闽斯沿岸流、南海西南季风漂流以及黑潮支流在本区运动消长有关。  相似文献   

埕岛油田海上石油平台基础冲刷研究   总被引：6，自引：1，他引：6  

仲德林  刘建立 《海岸工程》2003,22(2):37-43

海洋石油平台的建立会改变平台周围的水动力条件，其中平台的基础及与之连接的海底管缆(输油管道、注水管道、海底电缆等)附近产生冲刷现象，对平台和海底管缆的安全造成威胁。根据对研究区典型平台的4次实洲水深并结合以往资料，分析了埕岛油田海上石油平台基础冲刷的过程及其规律。  相似文献   

南海西部表层沉积物钙质浮游生物分布与碳酸盐溶解   总被引：1，自引：0，他引：1  

陈芳  李学杰  陈超云  郑凯清  黄雪华 《海洋地质与第四纪地质》2003,23(2):33-38

对南海西部300多个表层沉积样品中的浮游有孔虫和钙质超微化石定量分析表明，几乎所有样品均含浮游有孔虫、钙质超微化石，但丰度相差十分悬殊，浮游有孔虫丰度介于0．5～36673个／g之间，钙质超微化石丰度为0～1725个／10个视域，两者的分布规律相似。在陆坡区钙质浮游生物最富集，尤其在西沙群岛西南、南沙西部礁滩附近海区丰度最高；向深海盆区和陆架浅水区，钙质浮游生物丰度均下降。但从两者的丰度分布来看，其溶解程度不同，浮游有孔虫更容易溶解，在200～2000m水深区，丰度最高，2000m以下丰度锐减；而钙质超微化石的最富集区在500～3000m，且3000m以下仍较丰富。从碳酸盐的分布来看，本区碳酸盐的临界补偿深度(CCrD)为3500m，而CCD大于4300m，碳酸盐的溶解主要由有孔虫和钙质超微化石构成。  相似文献   

胶州湾东岸滩涂环境的遥感监测   总被引：3，自引：1，他引：3  

王珍岩  张慧霞  郜昂 《海洋科学》2003,27(8):8-10

利用低潮位陆地卫星TM影像对胶州湾东岸碱厂白水分布与扩散进行监测。对研究区的子区影像在ENVI中进行增强、变换处理，提取白水、白泥分布与扩散信息，制作大比例尺影像地图，在GIS软件中计算其面积。结合实地验证和历史数据，分析表明，该污染源10多年来面积扩大了4倍，  相似文献