氧化锰、氧化铁、氧化铝对砷(Ⅲ)的吸附行为研究   总被引：6，自引：0，他引：6  

白德奎  朱霞萍  王艳艳  曾美兰 《岩矿测试》2010,29(1):55-60

合成了氧化锰、氧化铁、氧化铝三种矿物,以氧化铁、氧化锰为吸附剂研究了pH值、离子强度和时间等因素对吸附As(Ⅲ)的影响,并讨论了氧化锰、氧化铁、氧化铝三种矿物对As(Ⅲ)的饱和吸附容量及等温吸附实验。pH值对氧化锰吸附As(Ⅲ)几乎不影响,对氧化铁吸附As(Ⅲ)在很大的范围内(pH为3.5~8.5)影响不大,离子强度对二者吸附As(Ⅲ)的影响不大,吸附反应在0.5 h左右达到吸附平衡。在优化吸附条件下氧化锰、氧化铁、氧化铝对As(Ⅲ)的饱和吸附容量分别为48.38 mg/g、23.70 mg/g、3.52mg/g,三种合成矿物对As(Ⅲ)的饱和吸附容量:氧化锰氧化铁氧化铝。对实验数据进行Freundlich和Langmuir拟合,相关系数R均在0.98以上,吸附动力学符合Lagergren二级速率方程。  相似文献   

钛矿石物相的快速分析   总被引：1，自引：1，他引：0  

郑民奇  李邦民  程秀花 《岩矿测试》2010,29(1):61-63

钛矿石的主要矿物有金红石(TiO2),其次钛铁矿(FeO.TiO2)、榍石(CaO.TiO2.SiO2)和钛磁铁矿(FeTiO3.nFe2O3)。样品经碱熔融,过氧化氢比色测定总钛;利用电感耦合等离子体质谱法测定,氟化氢铵和盐酸溶解钛铁矿、钛磁铁矿、榍石和硅酸盐中的钛;湿法磁选、盐酸溶解钛磁铁矿中的钛;磁选后的残渣经800℃灼烧,氟化氢铵和盐酸溶解榍石和硅酸盐中的钛。方法对12个钛矿石样品进行了4种钛矿物物相分析,结果与实际地质成矿组分符合。  相似文献   

氯化法钛白粉生产项目放射性环境影响评价     

邱国华 《铀矿地质》2010,26(3):178-186

在放射性核素走向分析和环境现状调查的基础上,对某氯化法钛白粉生产项目的放射性环境影响进行了分析、预测与评价。放射性环境现状调查表明,评价因子总体在区域环境本底范围内,经分析确定了放射性敏感点。经放射性环境影响预测,工作人员和公众所受的附加剂量分别为0.59mSv/a和9.28×10-4mSv/a,均低于年有效剂量管理限值。在落实辐射防护和环境保护措施并加强放射性环境监测后,该项目的放射性环境影响符合国家有关法规和标准限值要求。  相似文献   

NO emissions as observed by SPICAV during stellar occultations     

Emilie Royer  Franck Montmessin  Jean-Loup Bertaux 《Planetary and Space Science》2010,58(10):1314-1326

Ultraviolet (UV) nightglow data from the SPICAV instrument (SPectroscopy for the Investigation of the Characteristics of the Atmosphere of Venus) onboard the Venus Express spacecraft, currently in orbit around Venus, are presented. In its extended source mode, SPICAV has shown that the Venus nightglow in the UV contains essentially Lyman-α and Nitric Oxide (NO) emissions. In the stellar mode, when the slit of the spectrometer is removed, an emission is also observed at the limb in addition to the stellar spectrum. A forward model allows us to identify this feature as being an NO emission. Due to radiative recombination of N and O atoms produced on the dayside of Venus, and transported to the nightside, NO nightglow provides important constraints to the Solar-to-Anti Solar thermospheric circulation prevailing above 90 km. The forward model presented here allows us to derive the altitude of the peak of emission of the NO layer, found at 113.5±6 km, as well as its scale height, of 3.4±1 km and its brightness. The latter is found to be very variable with emissions between 19 Kilo-Rayleigh (kR) and 540 kR. In addition, the NO nightglow is sometimes very patchy, as we are able to observe two distinct emission zones in the field of view. Finally, systematic extraction of this emission from stellar occultations extends the database of the NO emission already reported elsewhere using limb observations.  相似文献   

深源包体铁镁氧化物与金含量的回归分析     

何雨明  杨牧 《化工矿产地质》2010,32(4):206-210

超基性岩和基性岩中金原子可能以类质同像取代铁镁矿物中的铁镁原子,金原子与铁镁原子之间的这种类质同像置换使得金含量与铁镁氧化物关系密切。华北地块北缘作为我国最重要的金成矿区具有代表性的研究意义。深源包体可以排除外来壳源物质混染的影响,因此对深源包体铁镁氧化物与金含量进行回归分析旨在将铁镁氧化物与金含量的的关系由定性推向定量,以期对金元素的成矿特性获得些许新的认识。回归分析表明,华北地块北缘深源包体金含量与镁氧化物的线性关系较之与铁氧化物线性关系明显,但均呈负相关,推测是受不同程度熔融的影响并且金元素以气态形式从地核迁移入地幔,使得金原子与铁镁原子之间的类质同像取代现象不明显。  相似文献   

碳酸盐岩红色风化壳中的氧化铁矿物   总被引：6，自引：0，他引：6       下载免费PDF全文

朱立军  李景阳 《地质科学》2001,36(4):395-401

氧化铁矿物是碳酸盐岩红色风化壳的主要矿物成分和重要结构单元。运用X射线衍射、透射电镜、扫描电镜、穆斯堡尔谱和电子探针等方法对碳酸盐岩红色风化壳中的氧化铁矿物进行了系统研究。碳酸盐岩红色风化壳中的氧化铁矿物主要有针铁矿、赤铁矿和磁赤铁矿。氧化铁矿物组合、含量和化学成分随成土环境和风化强度在剖面中呈明显的规律性变化,这为碳酸盐岩风化成土作用、红色风化壳成因与环境问题的深入研究提供了重要的矿物学依据。  相似文献   

黔东北地区氧化锰矿的成因类型及找矿方向     

何明华 《贵州地质》2001,18(3):168-173

黔东北地区的氧化锰矿床系风化矿床，按其成因可进一步分为残积矿床和淋积矿床两种。前者在区域上分布相对较广，是由原生菱锰矿床经次生风化而成，呈带状延伸；后者是由锰质对原矿层附近围岩淋滤加积而成。本文探讨了不同类型矿床的特征和分布规律，同时还对该区氧化锰矿的成矿机理、控矿因素和区域找矿方向作了粗浅分析。  相似文献   

用原子吸收仪进行钛的紫外分光光度测定   总被引：1，自引：0，他引：1  

杨重九 《岩矿测试》2001,20(3):234-236

在原子吸收仪上添置了一个自制的简易比色皿托架，成功地利用原子吸收仪进行TiO2与二安替比林甲烷显色的分光光度测定。  相似文献   

Bacterial biogas production in coastal systems affected by freshwater inputs   总被引：2，自引：0，他引：2  

D. Marty  P. Bonin  V. Michotey  M. Bianchi 《Continental Shelf Research》2001,21(18-19)

The concentrations of two greenhouse gases, nitrous oxide (N₂O) and methane (CH₄), and the bacterial processes involved in their production (nitrification and denitrification for N₂O, and methanogenesis for CH₄), were determined in surface waters of two coastal areas under the influence of freshwater inputs, on one part in the Gulf of Lions and the Rhone River plume, in northwestern Mediterranean Sea, and on the other part in the inner Thermaikos Gulf, in Aegean Sea, eastern Mediterranean Sea. High concentrations of dissolved CH₄ and N₂O were recorded in the surface waters of Gulf of Lions and Gulf of Thermaikos, up to 1300 nM for CH₄, and 40 nM for N₂O. No direct relationship could be found between the concentration and production of the biogases, as they may also be produced in deep water or bottom sediment in shallow areas, or derived from anthropogenic activity or ship contamination in polluted areas. Irrespective of the origin of CH₄ and N₂O, the presence of extremely high concentrations of these two gases in superficial seawater implies that they can easily escape to the atmosphere; consequently, these nearshore waters enriched in greenhouse gases may play an important role in the increase in atmospheric concentration of both CH₄ and N₂O.  相似文献   

Ground Based FTIR Measurements of Stratospheric Species from Harestua, Norway During Sesame and Comparison with Models     

B. Galle  J. Mellqvist  D.W. Arlander  I. Fløisand  M.P. Chipperfield  A.M. Lee 《Journal of Atmospheric Chemistry》1999,32(1):147-164

Vertical columns of HF, HCl, HNO3, ClONO2, N2O, ClO and COF2 were measured at Harestua, Norway (60.22° N, 10.75° E, Elevation 600 a.s.l.) beginning on 24 November 1994 and concluding on 1 May 1995 during Phase-III of the SESAME (Second European Stratospheric Arctic and Mid-latitude Experiment) measurement campaign. The vertical columns of HCl, HNO3 and ClONO2 measured on 81 days were compared with columns calculated by the 3-D Cambridge model SLIMCAT. In addition the results were also interpreted by comparison with a photochemical trajectory model. Good agreement was seen for HCl while the nitrogen compounds showed larger discrepancies, especially for ClONO2. Evidence for chlorine activation was seen with 65% reduction of the chlorine reservoirs (HCl + ClONO2) while the levels of ClO were greatly enhanced. Interpretation of the loss with the trajectory model indicated condensation of chlorine on PSCs. The vertical column ratio of COF2 and HF was measured to 0.21 outside the vortex and a factor of two lower inside. The recovery of ClONO2 was seen to be much faster than that of HCl in the early spring.  相似文献