Noble gas tracers for characterisation of flow dynamics and origin of groundwater: A case study in Switzerland     

R. Althaus  S. Klump  A. Onnis  R. Kipfer  R. Purtschert  F. Stauffer  W. Kinzelbach 《Journal of Hydrology》2009,370(1-4):64-72

The Grenchen aquifer system in the Swiss Plateau was extensively investigated in order to determine the extent of groundwater contamination and to assess the natural attenuation capacity. Environmental tracer data were applied to estimate groundwater travel times, mixing ratios, and evaluate groundwater origin. Recharge is basically possible in two distinct topographical areas, the immediate vicinity of the town of Grenchen and the elevated plateau of the first Jura Mountain ridge. Groundwater dating was performed with the ³H/³He dating method and supplemented by ⁸⁵Kr measurements. Stable isotope data (δ¹⁸O, δ²H) and dissolved noble gas concentrations allow the determination of the recharge temperature, which is correlated to the recharge elevation. Noble gas temperatures (NGT) decrease in the direction of groundwater flow and range from 10 to 13 °C in the upstream area of the town to 7–9 °C in the downstream river plain. This trend could suggest the admixture of water from the underlying limestone aquifer recharged under cooler infiltration conditions, e.g. at higher recharge elevations. However, it is shown in this study that the difference in NGT does not require such a recharge. Rather, increasing air temperatures over the last 40 years and the urban heat island effect could possibly explain most of the observed temperature shift. Furthermore, it is concluded that the downstream river plain is hydrologically disconnected from the upstream town area. Consequently most water from the town area is drained by the creek Witibach and recharge in the river plain is higher than previously assumed.  相似文献   

Study of evaporation and recharge in desert soil using environmental tracers, New Mexico, USA   总被引：4，自引：0，他引：4  

A.-R. Shurbaji  A. R. Campbell 《Environmental Geology》1997,29(3-4):147-151

 The purpose of this study is to investigate the rates and mechanisms of recharge and evaporation in soils of a desert environment using two environmental tracers (chloride and oxygen-18). The profiles of chloride concentration and oxygen-18 enrichment in soil-water, together with the depth distribution of water content in soil, reveal information about long-term recharge and instantaneous evaporation processes without needing to know the physical properties of the soil. Three holes were hand-augured, in different desert settings in southeastern New Mexico. The chloride concentration profiles were used, with the chloride mass balance method, to estimate long-term recharge rates in these three holes as 0.5, 0.8, and 2.4 mm yr^–1. Analysis using a bimodal flow and transport model shows that possibly 85% of the recharge occurs via movement of water through preferred pathways in the root zone. Preferential flow was evident in all three sampling sites. Clay layers have a noticeable effect on the development of water content distribution and thus on oxygen-18 enrichment and chloride concentration profiles. The spatial variation in clay layering partly explains the variation in recharge rate estimates. Received: 13 October 1995 · Accepted: 15 November 1995  相似文献   

Methane emission measurements in urban areas in Eastern Germany     

Joanne H. Shorter  J. Barry Mcmanus  Charles E. Kolb  Eugene J. Allwine  Brian K. Lamb  Byard W. Mosher  Robert C. Harriss  Uwe Partchatka  Horst Fischer  Geoffrey W. Harris  Paul J. Crutzen  Hans-Josef Karbach 《Journal of Atmospheric Chemistry》1996,24(2):121-140

We have investigated methane emissions from urban sources in the former East Germany using innovative measurement techniques including a mobile real-time methane instrument and tracer release experiments. Anthropogenic and biogenic sources were studied with the emphasis on methane emissions from gas system sources, including urban distribution facilities and a production plant. Methane fluxes from pressure regulating stations ranged from 0.006 to 24. l/min. Emissions from diffuse sources in urban areas were also measured with concentration maps and whole city flux experiments. The area fluxes of the two towns studied were 0.37 and 1.9 g/m²/s. The emissions from individual gas system stations and total town emissions of this study are comparable to results of similar sites examined in the United States.  相似文献   

Transport timescales for identifying seasonal variation in Bass Strait, south-eastern Australia   总被引：1，自引：0，他引：1  

Paul A. Sandery  Jochen Kmpf 《Estuarine, Coastal and Shelf Science》2007,74(4):684

A three-dimensional σ-coordinate ocean model with realistic forcing is used to derive and compare flushing time, residence time and water age distributions in Bass Strait, a broad shallow shelf sea in south-eastern Australia which exhibits seasonal variation in water mass properties and circulation. Results illustrate flushing out of most old water occurs each winter–spring period and the circulation in summer increases age of remnant older water in the Strait. A correlation between water age and salinity is found in winter which is the result of advective “erosion” of the interior water mass. The presence of an area in the south-eastern part of the interior with low flushing is suggested to result from a number of physical factors including the presence of quasi-stationary eddies which entrain age, leading to relatively older water residing there.  相似文献   

CFC Indicating Renewal of the Japan Sea Deep Water in Winter 2000–2001     

Shizuo Tsunogai  Kentaro Kawada  Shuichi Watanabe  Takafumi Aramaki 《Journal of Oceanography》2003,59(5):685-693

The distributions of CFC (chlorofluorocarbon) in the water column was determined twice in 2000 and 2001 in the northwestern Japan Sea. In 2000 the CFC-11 concentration decreased almost exponentially with depth from 6 pmol/kg at a few hundred m deep to 0.3 pmol/kg or less at the bottom of about 3400 m depth at three stations (40–41°N, 132–133°E) about 300 km off Vladivostok. In 2001 the CFC-11 concentration increased sharply up to 2 pmol/kg in the bottom water, while it did not increase at a station (42.0°N, 136.5°E) about 450 km away to the northeast. This is due to the renewal of the bottom water which is replaced by the surface water flowing down along the continental slope, as suggested by Tsunogai et al. (1999), who proposed the continental shelf pump. Furthermore, an increase in the CFC-11 concentration was observed throughout the entire water column above 3000 m depth, although the proportion of the increase was about 20%, which was one order of magnitude smaller than that in the bottom water. The increase in inventory is almost four times larger than that in the bottom water below 3000 m depth which is equivalent to about 1/6 of the total inventory found in 2000. The increase also means that 3% of the deep water was replaced by the recent surface water, or, if the turnover occurs every year, that the turnover time of the deep water to be about 30 years. This revised version was published online in July 2006 with corrections to the Cover Date.  相似文献   

Assessment of water exchange between a discharge region and the open sea – A comparison of different methodological concepts     

Kristofer Ds  Anders Engqvist 《Estuarine, Coastal and Shelf Science》2007,74(4):709

Two different methods of estimating the water exchange through the Baltic coastal region of Laxemar have been used, consisting of particle trajectories and passive tracers. Water is traced from and to a small discharge region near the coast. The discharge material in this region is treated as zero-dimensional particles or tracers with neutral buoyancy. The real discharge material could be a leakage of radio-nuclides through the sea floor from an underground repository of nuclear waste.Water exchange rates between the discharge region and the model domain are estimated using both forward and backward trajectories as well as passive tracers. The Lagrangian trajectories can account for the time evolution of the water exchange while the tracers give one average age per model grid box. Water exchange times such as residence time, age and transient times have been calculated with trajectories but only the average age (AvA) for tracers. The trajectory calculations provide a more detailed time evolution than the tracers.On the other hand the tracers are integrated “on-line” simultaneously in the sea circulation model with the same time step while the Lagrangian trajectories are integrated “off-line” from the stored model velocities with its inherent temporal resolution, presently 1 h. The sub-grid turbulence is parameterised as the Laplacian diffusion for the passive tracers and with an extra stochastic velocity for trajectories. The importance of the parameterised sub-grid turbulence for the trajectories is estimated to give an extra diffusion of the same order as the Laplacian diffusion by comparing the Lagrangian dispersions with and without parameterisation. The results of the different methods are similar but depend on the chosen diffusivity coefficient with a slightly higher correlation between trajectories and tracers when integrated with a lower diffusivity coefficient.  相似文献   

Field studies of the flow structure in a straight reach of the conwy estuary     

I. Guymer  J. R. West 《Estuarine, Coastal and Shelf Science》1991,32(6)

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Sedimentary record of redox-sensitive elements (U, Mn, Mo) in a transitory anoxic basin (the Thau lagoon, France)   总被引：4，自引：0，他引：4  

Franoise Elbaz-Poulichet  Jean Luc Seidel  Didier Jzquel  Edouard Metzger  Franois Prvot  Caroline Simonucci  Grard Sarazin  Eric Viollier  Henri Etcheber  Jean-Marie Jouanneau  Olivier Weber  Olivier Radakovitch 《Marine Chemistry》2005,95(3-4):271-281

In order to further document the relation between redox conditions and the sedimentary record of Mn, U and Mo in a transitory anoxic water basin, their distribution has been studied along two profiles in the Thau lagoon (France). Sediments and pore-water have been sampled at two contrasting sites located, respectively, in the shellfish-farming area and in the centre of the lagoon. In the shellfish-farming area, the particulate organic carbon (POC) data indicate a more rapid organic matter mineralisation compared to the centre of the lagoon. This results in a sharper redox gradient characterized by the appearance of H₂S in pore-water a few millimetres below the sediment–water interface. In the centre of the lagoon, H₂S appears at a depth of 35 cm.In both cores, sedimentary Mn is relatively depleted through out the whole sedimentary column and varies with the proportion of clay minerals. After an initial release into solution at the sediment–water interface in relation to Mn-oxide reductive dissolution, authigenic U is immobilized when sulphides appear. Despite the occurrence of anoxic conditions at the sediment–water interface at the site influenced by shellfish farming, the burial of U is reduced by bioturbation, which raises reducing sediments to the surface. In the centre of the lagoon, Mo profiles reflect continuous diffusion into pore water and immobilization at 15 cm probably in anoxic microenvironments. At shellfish farms, dissolved Mo undergoes removal with sulphides but contrary to U, sedimentary Mo does not appear to be strongly affected by bioturbation. The profile indicates an increase in the frequency of anoxia crises during the second half of the 20th century.  相似文献   

Carbon dioxide flux techniques performed during GasEx-98   总被引：2，自引：0，他引：2  

Wade R. McGillis  James B. Edson  Jonathan D. Ware  John W. H. Dacey  Jeffrey E. Hare  Christopher W. Fairall  Rik Wanninkhof 《Marine Chemistry》2001,75(4):851

A comprehensive study of air–sea interactions focused on improving the quantification of CO₂ fluxes and gas transfer velocities was performed within a large open ocean CO₂ sink region in the North Atlantic. This study, GasEx-98, included shipboard measurements of direct covariance CO₂ fluxes, atmospheric CO₂ profiles, atmospheric DMS profiles, water column mass balances of CO₂, and measurements of deliberate SF₆–³He tracers, along with air–sea momentum, heat, and water vapor fluxes. The large air–sea differences in partial pressure of CO₂ caused by a springtime algal bloom provided high signals for accurate CO₂ flux measurements. Measurements were performed over a wind speed range of 1–16 m s⁻¹ during the three-week process study. This first comparison between the novel air-side and more conventional water column measurements of air–sea gas transfer show a general agreement between independent air–sea gas flux techniques. These new advances in open ocean air–sea gas flux measurements demonstrate the progress in the ability to quantify air–sea CO₂ fluxes on short time scales. This capability will help improve the understanding of processes controlling the air–sea fluxes, which in turn will improve our ability to make regional and global CO₂ flux estimates.  相似文献   

The influence of local hydrogeologic forcings on near‐stream event water recharge and retention (Upper San Pedro River,Arizona)     

Scott C. Simpson  Thomas Meixner 《水文研究》2013,27(4):617-627

The rise in stream stage during high flow events (floods) can induce losing stream conditions, even along stream reaches that are gaining during baseflow conditions. The aquifer response to flood events can affect the geochemical composition of both near‐stream groundwater and post‐event streamflow, but the amount and persistence of recharged floodwater may differ as a function of local hydrogeologic forcings. As a result, this study focuses on how vertical flood recharge varies under different hydrogeologic forcings and the significance that recharge processes can have on groundwater and streamflow composition after floods. River and shallow groundwater samples were collected along three reaches of the Upper San Pedro River (Arizona, USA) before, during and after the 2009 and 2010 summer monsoon seasons. Tracer data from these samples indicate that subsurface floodwater propagation and residence times are strongly controlled by the direction and magnitude of the dominant stream–aquifer gradient. A reach that is typically strongly gaining shows minimal floodwater retention shortly after large events, whereas the moderately gaining and losing reaches can retain recharged floodwater from smaller events for longer periods. The moderately gaining reach likely returned flood recharge to the river as flow declined. These results indicate that reach‐scale differences in hydrogeologic forcing can control (i) the amount of local flood recharge during events and (ii) the duration of its subsurface retention and possible return to the stream during low‐flow periods. Our observations also suggest that the presence of floodwater in year‐round baseflow is not due to long‐term storage beneath the streambed along predominantly gaining reaches, so three alternative mechanisms are suggested: (i) repeated flooding that drives lateral redistribution of previously recharged floodwater, (ii) vertical recharge on the floodplain during overbank flow events and (iii) temporal variability in the stream–aquifer gradient due to seasonally varying water demands of riparian vegetation. Copyright © 2011 John Wiley & Sons, Ltd.  相似文献