Product study of the reaction of OH radicals with isoprene in the atmosphere simulation chamber SAPHIR     

M. Karl  H.-P. Dorn  F. Holland  R. Koppmann  D. Poppe  L. Rupp  A. Schaub  A. Wahner 《Journal of Atmospheric Chemistry》2006,55(2):167-187

Atmospheric oxidation of isoprene and its oxidation products methacrolein (MACR) and methyl vinyl ketone (MVK) have an important impact on the photochemical activity in the boundary layer, in particular in forested areas. The oxidation of isoprene by OH radicals was investigated in chamber experiments conducted under tropospheric conditions in the atmosphere simulation chamber SAPHIR at the Research Center Jülich. The aim was to determine the product yield of MVK and MACR in the OH-induced isoprene oxidation and the rate constant of their reaction with OH under real atmospheric conditions. The recently published updated degradation scheme for isoprene from Geiger et al. (2003) was used to determine rate constants and product yields. The fractional yields in the isoprene peroxy radical reaction with NO were found to be 0.41±0.03 for MVK and 0.27±0.03 for MACR. The rate coefficient for MACR with OH was found to be in very good agreement with the recommended value of IUPAC Atkinson (Atkinson et al., 2005). while the rate coefficient for MVK with OH was 27% lower.  相似文献   

水对不同岩石声波速度影响的研究   总被引：1，自引：0，他引：1  

王煜霞  许波涛 《岩土工程技术》2006,20(3):144-146

通过分析不同成因类型岩石的声波速度,提出了水对不同岩石声波速度的影响,从岩石孔隙及隐微裂隙的发育程度及岩石的水理性质解释了在水的作用下岩石声波变化规律,利用这些规律可以初步判断岩石的隐微裂隙发育程度及水理性质。  相似文献   

单液硅化灌浆法加固豫西湿陷性黄土地基施工技术和质量控制          下载免费PDF全文

罗伟 《探矿工程》2007,34(10):55-57

通过总结单液硅化灌浆法加固豫西三门峡地区湿陷性黄土地基的多个成功工程实例,介绍了该法加固本地区湿陷性黄土地基施工工艺及施工质量控制措施。  相似文献   

铝片还原-硫酸铁铵容量法测定钛铁矿中高含量     

李锟 《化工矿产地质》2007,29(2):112-114

试样经碱熔,盐酸提取的钛,在以盐酸、硫酸、磷酸组成的强酸性溶液体系中,利用铝片的强还原性,还原四价钛为三价钛。再用三价铁氧化三价钛为四价钛,过量的三价铁离子与硫氢酸根离子生成血红色络合物,根据此原理测定高含量钛。实验证明,溶液在此强酸性体系中,隔绝空气和控制时间的条件下,其含量范围在0.13%～100%内,测定结果准确度高。  相似文献   

新疆哈密大南湖地区层间氧化带特征研究     

权志高  张甲民 《地质找矿论丛》2007,22(2):113-117,124

新疆大南湖地区的层间氧化带发育层位为中侏罗统西山窑组第二、三岩性段砂砾岩,以褐黄色为主;层间氧化带具多层性,埋深31～343 m,厚度2～138 m;层间氧化带分为氧化带、氧化-还原过渡带和原生带;铀矿体主产于氧化-还原过渡带中;新构造运动形成的最终构造格架控制了层间氧化带的发育方向和基本形态,不同粒度且非致密结构的砂砾岩和冲积扇相、辫状河相沉积则决定层间氧化带发育的厚度和规模,由南向北流的承压地下水造成区内层间氧化带前锋线呈向北延伸的趋势.  相似文献   

Retrieval of the Change of Precipitable Water Vapor by GPS Technique     

WANG Yong LIU Yanping LIU Lintao XU Houze 《地球空间信息科学学报》2007,10(4):265-268

The feasibility of GPS precipitable water vapor (PWV) is discussed based on the comparison of Radiosonde and GPS PWV where the correlation coefficient is 0.94 and the RMS is 4.0 mm. PWV change in the C...  相似文献   

非地转湿Q矢量的改进及其应用   总被引：16，自引：0，他引：16  

刘汉华  寿绍文  周军 《南京气象学院学报》2007,30(1):86-93

在完全考虑非绝热加热项作用的前提下,从原始方程出发,推导出改进后的非地转湿Q矢量(Qq),以及用其散度作强迫项的ω方程,将其应用于一次梅雨锋暴雨诊断分析,结果表明:改进后的非地转湿Q矢量对同时刻地面降水的反映能力较岳彩军改进的湿Q矢量(QM)、原非地转湿Q矢量(Q*)、非地转Q矢量(Q#)有显著的提高;在整个梅雨锋暴雨过程中,500 hPa高度上的Qq矢量散度辐合场的辐合强度及其辐合中心位置对同时刻的降水强度及雨区位置有非常好的指示作用;Qq矢量的垂直分布揭示了次级环流的方向和强弱,暴雨位于次级环流的上升支附近.  相似文献   

Evaluation of α- and β-pinene degradation in the detailed tropospheric chemistry mechanism,MCM v3.1, using environmental chamber data   总被引：1，自引：0，他引：1  

P. G. Pinho  C. A. Pio  W. P. L. Carter  M. E. Jenkin 《Journal of Atmospheric Chemistry》2007,57(2):171-202

  相似文献   

Evaluation of Electro-Oxidation of Textile Effluent Using Response Surface Methods     

R. Saravanathamizhan  N. Mohan  N. Balasubramanian  V. Ramamurthi  C. Ahmed Basha 《洁净——土壤、空气、水》2007,35(4):355-361

In the present investigation, treatment of textile effluent using an electrochemical technique was designed and analyzed using the Box-Behnken method. The influence of individual parameters on electro-oxidation of textile effluent has been critically examined using the response surface method (RSM), and a quadratic model for chemical oxygen demand (COD) reduction has been developed. It has been observed from the present analysis that the predicted values are in good agreement with experimental data with a correlation coefficient of 0.945.  相似文献   

A comparative mineralogical and geochemical study of sulfide mine tailings at two sites in New Mexico, USA   总被引：5，自引：0，他引：5  

Michelle P. Boulet  A. C. L. Larocque 《Environmental Geology》1998,33(2-3):130-142

A comparative study of sulfide mine tailings from two sites near Silver City in southwest New Mexico has shown the need for environmental monitoring in a geological context. The Cyprus-Piños Altos and Cleveland deposits consist of Cu and Zn skarn mineralization in the Piños Altos Mountains of New Mexico. Primary ore minerals in both deposits include chalcopyrite, sphalerite, and galena. The Cyprus-Piños Altos Mine ceased operation in 1995 and the Cleveland Mill closed in 1950. The deposits have similar mineralogical characteristics; however, the tailings are different in terms of age, degree of oxidation and method of disposal. The Cyprus-Piños Altos tailings (CPAT) are stored in a lined, bermed impoundment. They are dominantly water-saturated and exhibit no secondary-phase formation. The grains are not cemented and show no evidence of primary-mineral dissolution. The geochemical data show a predominantly primary signature. The tailings pond water is neutral to slightly alkaline (pH?from 7 to 8.3), partly as a result of processing methods. The Cleveland mill tailings (CMT) were deposited in a valley at the headwaters of an ephemeral stream. They are highly oxidized and differentially cemented. They have undergone numerous wet/dry cycles resulting in extensive oxidation. Secondary minerals predominate, and consist mainly of jarosite, goethite, hematite, and Fe-oxyhydroxides and -oxyhydroxysulfates. The pH of the stream draining the CMT is as high as 2.15. Maximum metal contents in the stream immediately downstream from the tailings are 5305?ppm Zn, 454?ppm Cu, 1.16?ppm Pb, 17.5?ppm Cd, 1.4?ppm As, and 0.01?ppm Hg.  相似文献