A Stucture—mineralogical Study of Ringwoodite     

傅平秋  谢鸿森等 《中国地球化学学报》1990,9(2):99-104

The powder XRD analysis of ringwoodite(γ-Fe2SiO4),which was synthesized in a II-stage anvil high-pressure capsule,was made,Its unit-cell parameter was calculated:a=8.219A,After the refinements,for several cycles,of the oxygen parameter x and the occupancy rate of Si in octahedron site,i.e.,the iversion degree u,the final result is R=0.077,when x=0.379A and u=27.5%,with the structural formula (Fe1.725 Si0.275)VI(Si0.725Fe0.275)IV O4 and atomic distances(Fe,Si)VI-O=2.022 A and (Si,Fe)IV-O=1.836A,Meanwhile,the Moessbauer spectroscopic analysis of the sample was conducted and the results obtained are in good agreement with those of X-ray structural analysis ,This paper focuses on the phase transformation and the properties of bonds of α－Fe2SiO4→γ-Fe2SiO4.  相似文献   

Characterization of cristobalite in ash and dome rock from the Soufriere Hills volcano, Montserrat： Implications for respiratory health hazards     

Ben J. Williamson Claire J. Horwell 《中国地球化学学报》2006,25(B08):224-225

A link between the inhalation of respirable silicas （SiO2） and respiratory diseases such as silicosis is widely recognized. Ash from dome collapse eruptions on Montserrat has been found to contain high levels （〉20%） of silicas in the form of cristobalite, tridymite, quartz and/or amorphous silica. The toxicity of these silica polymorphs varies widely. Cristobalite and quartz （tridymite less well established） are viewed as carcinogenic to humans whereas amorphous silica generally shows a reduced biological response. In assessing the potential health effects of volcanic ash particulates it is vital to determine the types and concentration of silicas as well as their size （respirable fraction）, shape and surface properties. The aim of this study is to develop methods to assess potentially toxic respirable airborne silicas in the dome collapse ash （applicable to a range of ash types） and to develop a model to predict the levels and types of respirable silicas from future eruptions. The model is being developed by comparing dome rock with related ash from a series of previous eruption events. Mineralogical assessment using conventional scanning X-ray diffraction （XRD） was hampered by difficulties in differentiating characteristic peaks for cristobalite and tridymite in complex multi-component ash samples （containing high levels of plagioclase）. These difficulties have been largely overcome using an Enraf-Nonius PDS120 diffractometer with curved （120 degrees 20） position sensitive detector （PSD）. The determination of size, shape and elemental characteristics of ash particulate and dome rock samples has been carried out using automated analytical scanning electron microscopy. The quantification of mineral proportions using PSD-XRD was highly successful with an accuracy of 1 to 2 wt%. However, the determination of phase proportions using automated analytical SEM was problematic due to scattering effects and the multiphase nature of many of the particles.  相似文献   

Origin and three-dimensional fluorescence spectrum of the chromophoric dissolved organic matter in Yangtze estuary, East China     

Fan YANG Qinghui HUANG Jianhua LI Xiaomin ZHU 《中国地球化学学报》2006,25(B08):262-262

Dissolved organic matter （DOM） is an important chemical component in natural water. Chromophoric dissolved organic matter （CDOM）, a fraction of optical properties, plays art important role in the biogeochemical cycle of nutrients in aquatic environment. People realized that DOM cycle is crucial in the global carbon and nitrogen flux, and also is inherently related to nutrients and trace metal elements. Therefore, CDOM was concerned by scientists in global oceanography and limnology fields. Water samples were collected from three sections （North Channel, South Channel and Zhuyuan） of the Yangtze （Changjiang River） estuary in March 2006 Three-dimensional excitation emission matrix （3-DEEM） fluorescence spectra were analyzed for those filtrates through Whatman GF/F filters. Dissolved organic carbon （DOC） was also measured by TOC analyzer. The tidal variety was also taken into account. The 3-D EEM fluorescence scans suggested the fluorescence characteristics of humic acid （Ex=332-344 nm, Em=439-451 nm） and fulvic acid （Ex=250-254 nm, Em=472-478 nm） were obvious, and the fluorescence group of protein-like and tyrosine （Ex=230 nm, Em=283 nm） was also found. They are mainly composed of CDOM in the Yangtze estuary. Further data analysis, especially the fluorescence index （f 450/500）, showed that terrestrial signal was rather strong （1.41-1.65） in the surface water, however, some terrestrial CDOM signals of bottom water showed excursions （1.28-1.39）. On the other hand, anthropogenic sign was impressed in the waters of Zhuyuan, which is one of the main drain outlets of Shanghai Metropolis. DOC concentrations ranged from 2.2 mg/L to 3.4 mg/L in Zhuyuan and South Channel, and from 2.0 mg/L to 2.4 mg/L in North Channel. The tide effect played a role in the composition of the CDOM measured by 3-D fluorescence scan technology.  相似文献   

浙江古代青瓷(1127～1279年)的化学组成及其意义     

彭子成  梁宝鎏  余君岳  郑培凯  李德卉 《地质学报》2006,80(10):1632

本文用ENGLE-型微探针能量色散X荧光光谱(EDXRF)技术测定了一批青釉瓷残片中的16种元素氧化物的含量,其残片来自浙江杭州地区的南宋郊坛窑和老虎洞窑。由主量元素判别方程的Q值表明,两类青釉瓷均属官窑制品。主成分统计分析看出,郊坛官窑与老虎洞官窑的瓷釉成分有明显不同,但其胎质成分的分布,却有部分的重叠,这显示了当时两处官窑的工匠们在使用胎料中的交往。从釉层、过渡层、和胎层的Al2O3和CaO的含量数据表明,郊坛官窑和老虎洞官窑的青釉瓷制品,分别存有厚度为120～140μm和230～240μm的过渡层,表明两处使用釉料和烧制工艺上的…  相似文献   

参量阵浅地层剖面测量技术 在近岸海洋工程的应用效果   总被引：1，自引：0，他引：1  

褚宏宪  赵铁虎  史慧杰  张晓波  杨源 《物探与化探》2005,29(6):526-529,532

介绍了海底浅地层声学探测技术的发展情况, 简述了新型参量阵声纳探测的原理和特点, 通过SES-96参量阵测深或浅地层剖面系统在山东半岛海区的应用实例, 对此新型参量阵声纳技术的应用效果进行了分析评价。  相似文献   

岩石三轴强度试验   总被引：2，自引：0，他引：2  

李广平王玉玲  蔡玉贞 《岩矿测试》2005,24(1):75-78

通过自制岩石三轴压力室和配备液压泵与现有万能材料试验机组成岩石三轴试验系统，进行岩石三轴强度试验研究，并与其它方法比对，结果相近，满足了科研和生产的需要。  相似文献   

微量相X射线衍射定量分析的一种简便方法     

何泽能李振山  斯永敏 《岩矿测试》2005,24(2):81-86

阐述了关于微量相X射线衍射定量分析的一种简便方法———近似线性关系法,它适用于二相体系(或基体吸收系数基本恒定的多相体系)材料中微量相的定量分析。该方法不需要在待测样品中加入参考物相,分析时仅需对一条衍射线进行测定,因而分析时间很短,其测定结果与实际含量的相对误差为-10.2%～ 21.4%,与外标法和内标法的测量结果的精度相当。  相似文献   

理学3080E3型X射线荧光光谱仪维修实例   总被引：2，自引：0，他引：2  

唐晓慧 《岩矿测试》2005,24(3):237-238

介绍理学3080E3型X射线荧光光谱仪样品驱动单元及高压发生器部分的故障现象及维修实例。  相似文献   

4120型地阻仪使用注意事项          下载免费PDF全文

(王小永  王兰 《陕西气象》2005,(3):39-39

防雷接地检测仪表 41 2 0需要接 2 2 0 V交流电 ,也不需要打地桩。机房检测时使用 41 2 0型地阻仪进行测试很方便。41 2 0型测试时要求 :2 0 V交流电 ,认相序 ,测试插座为单相三线有保护接地。检测过程中 ,常碰到测试插座为两孔无保护接地 ,相序也不对。有的单位机房装有漏电保  相似文献   

飓风中的涡旋罗斯贝波   总被引：6，自引：2，他引：6  

钟科  康建伟  余清平 《气象学报》2002,60(4):436-441

文中从柱坐标系下的正压无辐散涡度方程出发,用WKBJ方法求解方程,发现在飓风中存在类似于行星罗斯贝波的涡旋罗斯贝波,这种波的形成主要是由于飓风中基态涡度垂直分量的径向梯度所决定。利用一次飓风过程的精确数值模拟所输出高分辨的资料,计算了飓风中径向涡度梯度的分布,指出这类波动主要存在于眼墙和眼心中。波动结构分析表明,波动能量具有径向频散,这有可能是飓风暖心结构的一种形成机制。最后用波射线法讨论了定常涡旋罗斯贝波的径向频散  相似文献