The concentration and distribution of different mercury species in the water columns and sediment of Aha Lake     

Weiyang BAI Xinbin FENG Xuewu FU Tianrong HE Guangle QIU 《中国地球化学学报》2006,25(B08):154-154

In order to find out whether Aha Lake was polluted by the acid mining waste water or not, the concentration and distribution of different mercuryspecies in the water columns and sediment profile collected from Aha Lake were investigated. It was found that discernible seasonal variation of different mercury species in water body were obtained in the Aha Reservoir. With regards to the whole sampling periods, the concentrations of HgP in the Aha Reservoir water body were evidently correlated to the concentrations of total mercury, showing that total mercury was mostly associated with particle mercury. The concentrations of methylmercury in water body were also evidently correlated to the concentrations of dissolved mercury. The dissolved mercury evidently affects the distribution and transportation of methylmercury. However, there is no correlation between methylmercury and total mercury. The dissolved mercury, reactive mercury, dissolved methylmercury levels in the water body of high flow period were much higher than those in low flow period. The distribution, speciation and levels of mercury within the Aha Reservoir water body were governed by several factors, such as the output of river, the release of sediment . Discernible seasonal variation of total mercury and methylmercury in porewater was described during the sampling periods, with the concentrations in high flow period generally higher than those in low flow period. The methylmercury in pore water column was evidently correlated to that of the sediment. The results indicated that highly elevated MeHgD concentrations in the porewater were produced at the depths from 2 to 5 cm in the sediment profile, and decreased sharply with depth. A positive correlation has been found between MeHgD formation and sulfate reducing bacterial activity. These highly elevated concentrations of MeHgD at the intersurface between waters and sediments suggest a favorable methylation condition. Moreover,  相似文献   

Attenuation of aqueous metal transport at two natural acid rock drainage occurrences in the Yukon Territory, Canada     

Y.T. John Kwong 《中国地球化学学报》2006,25(B08):229-230

Naturally acidic drainage associated with pyritic black shale has been observed in many locations in the Yukon Territory. While not necessarily linked to known mineral deposits, most of these natural acid rock drainage occurrences show elevated dissolved concentrations of trace elements, especially zinc, nickel, copper, cadmium and arsenic. Based on field observations, microbial investigation, chemical analyses and geochemical modeling, the fate and transport of potentially deleterious elements at two natural acid drainage occurrences with slightly different settings are examined. The Macintosh Creek is a small, acidic stream （pH 2.98-3.40）, 2 km long, located in the Macmillan Pass area of east-central Yukon amidst known sedimentary exhalative massive sulfide mineralization but remains undisturbed by exploration activities. Its trace metal content is apparently derived from groundwater discharges, which gave as much as 5.0, 2.5, 0.7, 0.13 and 0.03 mg/L ofZn, Ni, Cu and As, respectively. Interaction and sorption reactions with algal mats, biofilms and iron oxyhydroxides appear to be the dominant mechanisms attenuating aqueous contaminant transport along the stream. Cryogenic precipitation further consolidates the ferricrete formation and reduces the mobility of the sorbed metals. The tributaries of the Engineering Creek along the Dempster Highway in northern Yukon drain through a series of dolomite, phyllite, argillite, limestone, black shale, sandstone and conglomerate with no known concentration of mineralization. In this area, the water chemistry fully reflects the local geology with acidic streams invariably associated with black shale occurrences. Groundwater seeps in the headwaters area of the km-180 Creek completely enclosed in black shale gave pH 3.0 and as much as 148, 39, 2.9 and 9.1 mg/L of Zn, Ni, Cu and As, respectively. Sorption with iron oxyhydroxide and organic matter appear to dominate the attenuation of contaminant transport along the stream. However, once entered into carbonate-dominated terrains, secondary carbonate minerals exercise additional geochemical control on the local water chemistry as a result of neutralization.  相似文献   

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska     

Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.  相似文献   

Influence of heavy metals and pH on sulfate reduction metabolism     

《中国地球化学学报》2006,25(B08):130-130

  相似文献   

班公湖-怒江结合带中段上三叠统确哈拉群与下伏岩系角度不整合关系的发现及意义   总被引：9，自引：9，他引：9  

陈玉禄张宽忠  李关清尼玛次仁赵守仁  陈国荣 《地质通报》2005,24(7):621-624

在位于班公湖-怒江结合带中段的西藏班戈县白拉乡拉纳沟一带，首次发现上三叠统确哈拉群与下伏岩系呈角度不整合接触。该接触关系的发现，证实在班公湖-怒江结合带内有古特提斯蛇绿岩的存在，说明以班公湖-怒江结合带为代表的新特提斯域是在古特提斯域基础上继承和发展起来的。  相似文献   

三种类型烃-烃不混溶包裹体组合的特征和热力学条件的计算     

刘斌 《岩石学报》2005,21(5):1416-1424

在自然界广泛分布着烃-烃不混溶体系中捕获的流体包裹体,由于这些包裹体具有复杂的组成和相态,因此不混溶包裹体组合的判别和热力学参数的计算常常难以进行。根据烃-烃不混溶体系中两个端员组分流体包裹体室温下的相态特征和在温度-压力平面图上等容线交点显示的位置,划分成三种类型流体包裹体组合,本介绍了三种类型流体包裹体组合特征,叙述了不混溶烃-烃包裹体组合的测定和判别方法,并且阐述均一化包裹体相态方程和气-液平衡常数原理和方法与此同时列举了自然界简单的三种类型不混溶烃-烃包裹体组合的测定、判别和计算的几个实例,利用相态方程和气-液平衡常数,不但精确地计算出包裹体均一压力,并且精确地计算出流体密度和体积等热力学参数。最后,利用均一成气相和液相的两种包裹体在 p-T 平面图上等容线交点同样计算出流体包裹体组合的捕获温度和压力。  相似文献   

内蒙古武川西乌兰不浪高级区岩石及其形成环境     

张玉清  许立权  贾和义  刘颖璠  王弢 《华北地质》2005,28(2):71-78

西乌兰不浪高级变质的兴和岩群是1：5万、1：25万区域地质调查时从海西期岩体和五台群中重新厘定出来的地质体。通过野外宏观地质特征、岩石化学、地球化学等综合分析，认为西乌兰不浪地区高级区岩石不只是由表壳岩组成，还有大量的TTG岩系、紫苏花岗岩、脉岩和岩墙，它们是不同构造环境、不同时代的构造拼合体。其中表壳岩称为兴和岩群，为一套火山-沉积岩系，形成于活动大陆边缘。  相似文献   

Windows应用经验点滴     

樊予江 《沙漠与绿洲气象(新疆气象)》2005,28(2):32-34

3721的“网上助手”插件给不少使用者带来了烦恼，最大的问题在于一旦安装上它，就再也找不到一个简单的干净卸载方法，在使用它自己提供的卸载程序卸载后，部分程序依然驻留，启动时仍然加载，依然监视、改写注册表，加之对3721公司的其它一些行为的不满，所以它被很多人戏称为3721病毒。对于普通用户而言，也许这不算什么，但对于想升级到SP2的XP用户而言，这简直就是一个灾难。由于在xp的SP2中，增加的安全特性中包含有恶意网站屏蔽的相关功能及弹出窗口的过滤器，不卸载干净3721的“网上助手”就有可能无法升级XP。  相似文献   

贵州暴雨的湿位涡诊断分析   总被引：4，自引：0，他引：4  

刘开宇  赵重安  牟佳  王世权 《贵州气象》2005,29(6):15-18

应用湿位涡理论，对2004年贵州的6次暴雨过程进行分析，讨论了湿位涡与贵州暴雨的关系，结果表明暴雨的发展与湿位涡的变化有很好的对应关系：0e面陡立且南侧暖湿气流活跃，易导致湿斜压涡度发展，密集区内暴雨容易发生。湿空气对流活动层仅能达到500～600hPa之间。对流层高层及平流层高位势涡度下传有利于位势不稳定能量的释放，从而造成强对流天气。对流层低层湿正压项负值区的移动反映了强对流过程位势不稳定能量的释放过程，湿斜压项的高值中心区与暴雨的落区相一致，为暴雨强度和落区的预报提供了一定的参考。  相似文献   

贵阳市一次强雷暴天气环境场分析     

万雪丽 《贵州气象》2005,29(Z1):35-36

从天气学角度出发,对2005年4月28日晚贵阳市区遭受的强雷暴天气进行环境场分析,得出这次强雷暴天气是高原东侧短波槽在低层切变线上扰动生成局地中小尺度气旋形成强烈的对流天气.强雷暴天气产生前地面持续的增温,低层扰动逆温层的存在,使得大气低层积聚大量不稳定能量,同时持续加强的西南暖湿气流为强雷暴天气的发生提供了充足的水汽.  相似文献