生物炭对磷石膏中磷的固化作用     

敖翔  徐冠立  李珎  柏涵 《岩石矿物学杂志》2024,43(1):100-108

磷石膏中的磷在雨水淋滤作用下浸出,将污染堆场附近水体。本研究采用生物炭固化磷石膏中的磷,以减少其对周遭水体的污染。主要通过模拟固化实验和对照浸出实验,分析生物炭用量、反应时间和温度、初始pH值对固化效果的影响,通过XRD、SEM-EDS分析固化后的生成物。实验结果显示,在生物炭用量为25 mg时,单位固化量达到最大值13.20 mg/g;在反应温度T=293 K、初始pH=7条件下,反应平衡时间72 h时浸出液的磷平衡浓度C_e= 1.40 mg/L;温度提升有助于提高生物炭的固化效果,当T=308 K时,浸出液的磷平衡浓度C_e=0.167 mg/L;碱性条件有利于固化反应持续进行,在pH=11条件下,浸出液的磷平衡浓度C_e=0.153 mg/L。实验结果表明生物炭对磷石膏中的磷具有明显的固化效果。磷石膏中的二水硫酸钙溶解后,Ca²⁺与表面带负电的生物炭结合,在生物炭显微结构的凹陷处,化学吸附溶液中的磷酸根生成了絮状、团簇状的羟基磷灰石(HAP)沉淀,从而使浸出磷得到有效控制。  相似文献   

施工顺序对软土地坪复合地基的影响探讨     

魏海涛  蔡智 《岩土工程技术》2021,(1)

场地回填土与搅拌桩施工顺序将直接影响软土地坪复合地基的处理效果,其中沉降控制是影响地坪安全运行的关键。以近海软土地区工业厂房水泥土搅拌桩复合地基工程为例,探讨了复合地基水泥土搅拌桩、回填土两种不同施工顺序的影响因素及相应处理效果;通过数值模拟试验,计算分析了不同填土厚度下两种工况的地基固结总沉降、施工沉降、工后沉降。结果表明,采用“先土后桩”的施工顺序的施工期沉降大于“先桩后土”,但工后沉降大大减小,提高了软土地坪地基处理效果,有利于处理后地坪的安全运行,验证了前述分析结论,为合理设计方案的确定提供了重要的参考依据。  相似文献   

矿物标型六性及其在胶东金矿中的应用   总被引：2，自引：0，他引：2  

陈光远  孙岱生 《吉林地质》1990,9(3):1-8

目前矿物标型研究和应用已进入一个新的阶段。作者从哲学的高度,把国内外矿物标型特征的分散研究加以集中概括和总结,提出了“矿物标型六性”的普遍规律,即普遍性、特殊性、变化性、相应性、继承性和分带性,对矿物标型特征研究具重要的指导意义。这些规律在胶东金矿中得到广泛应用,并已取得良好效果。  相似文献   

饱和软土压缩曲线的“反常”现象     

冯铭璋  王兴涛 《上海国土资源》1990,(3):30-37

饱和软土压缩试验时,经常出现压缩曲线“反常”、压缩系数“倒大”的现象。它是土的原始结构发生破坏前后的不同压缩性的客观反映。饱和软土的结构力很微弱,唯质量好的原状土才能见到这种“反常”。应从成孔、取样、测试及资料整理等多个环节保证其工程意义。  相似文献   

Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site     

Taoze LIU Yuangen YANG Bangyu LIU Xiangyang BI Feili LI 《中国地球化学学报》2006,25(B08):41-42

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.  相似文献   

Analysis of the effect of geology, soil properties, and land use on groundwater quality using multivariate statistical and GIS methods     

Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152

The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use.  相似文献   

CFG桩复合地基褥垫层的合理厚度确定方法研究          下载免费PDF全文

贾瑞杰  隆威  於法明 《探矿工程》2006,33(4):5-7

在CFG桩复合地基设计中，褥垫层的厚度设计是一个重点，它是复合地基承载力能否全部发挥的关键因素之一。但其设计上基本是靠经验取值，缺少理论根据。从理论方面入手，推导了褥垫层厚度的理论计算方法，给出了最佳垫层厚度、桩土应力比的解析表达式。  相似文献   

土方超挖对土钉墙基坑支护安全性的影响分析          下载免费PDF全文

刘家国 《探矿工程》2006,33(5):5-7

结合某基坑支护工程实例，分析了土方超挖对土钉墙基坑支护稳定性的不利影响。  相似文献   

土钉墙与预应力锚杆联合支护技术          下载免费PDF全文

杨生彬 《探矿工程》2006,33(8):8-10,16

北京市深基坑工程中土钉墙支护技术应用比较广泛，对于边坡变形要求严格的基坑，采用土钉墙与预应力锚杆联合支护技术可有效控制变形，结合工程实例，介绍了该技术的设计思路及应用过程，说明了该技术的适用性，并就施工中遇到的问题进行分析，给出相应的处理措施。  相似文献   

复合土钉墙支护技术在某大型软土基坑围护中的应用          下载免费PDF全文

杜常春  章泽军  李飞  周喜锋 《探矿工程》2006,33(2):26-29

根据拟建建筑基坑的工程地质条件、周边环境条件、基坑开挖深度等特点综合考虑，对基坑分段采用超前微型桩支护加土钉墙、放坡加土钉墙2种复合支护方案。实践证明，该工程所采用的多种复合式支护实施方案，技术安全可靠，经济合理。  相似文献