Mutual effects of fluoride and phosphate on their adsorption and desorption in fluoride-contaminated softs     

Maoxu ZHU Haihua WANG Xin JIANG 《中国地球化学学报》2006,25(B08):94-95

Phosphate is one of the important nutrients for plant growth. In acidic and highly weathered soils, phosphate is ready to adsorb on Al and Fe oxides and transform into sparsely soluble Fe-P and Al-P solid phases, greatly reducing phosphate bioavailability. Aluminum and iron oxides in soils are important sinks for both phosphate and fluoride. In acidic soils, fluoride adsorption can dramatically facilitate dissolution of Al- and Fe-containing phases, which may influence the distribution and migration of both pollutants and nutrients including phosphate. To date, little information is available on mutual effects of fluoride and phosphate in fluoride-contaminated acidic soils. The objective of this study is to evaluate mutual effects of fluoride and phosphate on their adsorption/desorption in red soil, collected fi＇om Yingtan, Jiangxi Province, China, using a batch equilibrium method. The following results and conclusions were obtained. In heavily fluoride-contaminated soils, the adsorption of both fluoride and phosphate decreases with an increase in solution pH. Phosphate adsorption decreases progressively with increasing concentration of fluoride, suggesting that fluoride competes with phosphate for adsorption sites.  相似文献   

Phytoremediation of Nephrolepis auriculata （L.） for arsenic, mercury, lead and cadmium in the multiple contaminated softs     

Tianlong DENG Mengxia LIAO Zhiming PAN Caixia LIU 《中国地球化学学报》2006,25(B08):95-95

In recent years, the concentrations of heavy metals in Chinese herb of Ligusticum chuanxong Hort are overranging the standard of national port of green herbs in GAP bases of Dujiangyan City, Sichuan Province. The aim of the research is to disclose the remediation behavior ofNephrolepis auriculata （L.）, a novel pteridophyta found in our research with abundant arsenic, mercury, lead and cadmium from soils. The concentrations of arsenic, mercury, lead and cadmium in the series samples corresponding to roots, stems, leaves ofNephrolepis auriculata （L.） which had been trained in lab with a series of potted incubation experiments through the orthogonal test, were analyzed. Based on the results, methods of the range analysis and variance analysis were used, and it is demonstrated that （1） Nephrolepis auriculata （L.） has a function to beneficiate heavy metals of arsenic and lead, and can well concentrate cadmium and mercury from soils. The distributive behaviors of arsenic, mercury, lead and cadmium in N. sauriculata （L.） follow the order： roots〉leaves〉corms〉stems, stems〉leaves〉roots〉corms, roots〉stems 〉corms〉leaves, stems〉leaves〉roots〉corms; the correlations of the concentrations for arsenic, lead, cadmium and mercury in different tisses of Nephrolepis auriculata （L.） and soils were carried out. Then, the effects of pH value, contents of EDTA and humic acid in soils to arsenic and mercury accumulated by Nephrolepis auriculata （L.） were further studied.  相似文献   

Advances on bioremediation of off-contaminated soil in cold region     

Xiaoyan LIU Jingxin SUN Guocheng MAO Chunlei DAI Chun LI Qianya ZHU Yingli LI 《中国地球化学学报》2006,25(B08):96-97

Petroleum pollution in the soil is a common problem in the world. The pollution may not only cause resource waste, but also may result in environment destruction, biology subsistence crisis and human health damage gradually. Biological techniques can be used to remove and transfer petroleum contaminants in the soil. Bioremediation of petroleum-contaminated soil, which is cost-effective,safe and friendly to environment, is promising. Low temperatures and lack of available nutrients often limit the rate of microbial degradation of petroleum hydrocarbons in contaminated soils in cold region. Some scholars carried out bioremediation technology research on oily soil in cold area. Scientists attempted many measures to increase the temperature of the field. A multidisciplinary team of engineers, microbiologists and electricians has designed and installed a thermally （TIS） enhanced biopile in oil-contaminated soil in Prudhoe Bay, AK. Covered with a black plastic sheet, the pile can also improve temperature condition. Nutrient is another important factor affecting bioremediation. Because of the different constituents in the soil, the proportion of elements is different. To optimize nutrient amendments for the remediation of a long-term hydrocarbon-contaminated site at the Old Casey Station in Antarctica, results showed that the effects of nitrogen （and phosphorus） on microbial are evident. If the method of fertilizing inorganic nutrients is improper, salinity of the soil may be increased and the osmotic potential may be impacted. J.L.Walworth et al.  相似文献   

Comparison of antimony behavior with arsenic under various soil redox conditions     

Satoshi Mitsunobu Teppei Harada Yoshio Takahashi 《中国地球化学学报》2006,25(B08):98-99

Antimony （Sb） is a toxic element and belongs to group 15 of the periodic table, under arsenic （As）. The geochemical behavior of Sb in the environment is still largely unknown. Since the behavior of Sb in the environment depends on its oxidation state, Sb analysis in environmental samples requires quantitative measurement of Sb （Ⅲ） and Sb （Ⅴ）. The aim of this study is the speciation of Sb in both solid and water phases to understand the reaction and dynamics of Sb in soil-water system. Accordingly, we employed X-ray absorption fine structure （XAFS） analysis to determine the Sb and As species in soil in laboratory and natural systems, while we also determined the oxidation states in soil water by the conventional HPLC-ICP-MS method. Natural soil and soil water samples containing Sb and As were collected around the Ichinokawa mine pithead, Ehime, Japan. To observe the species under various redox conditions, the soil and soil water samples were collected at four depths. Soil containing Sb and As were incubated for 7 days at 25℃ to observe their oxidation states under various redox condition by changing the total amount of water in the soil. Antimony K-edge XAFS spectra were measured at the beamline BL01B 1 at SPring-8 （Hyogo, Japan） and K-edge XAFS spectra of As, Fe, and Mn at the beamline BL12C in Photon Factory, KEK （Thukuba, Japan）. In the natural soil-water system, Sb was present exclusively as Sb （Ⅴ） over a wide redox range （from Eh=-140 to 360 mV; pH 8）, while As was present as a mixture of As （Ⅲ） and As （Ⅴ）. This trend was confirmed in the laboratory experiments. These results suggest that Sb （Ⅴ） is a very stable form in the environment and that Sb is oxidized under more oxic condition than As. Combining the results of Fe and Mn XAFS analyses and a positive correlation among Sb, As, and Fe abundances in the soil, the host phases of Sb and As in soil were Fe （Ⅲ） hydroxide. EXAFS analyses of Sb and As are also consistent with this fact. Under reducing conditions, the concentrations of As in the soil water increased whereas those of Sb decreased in both the natural and laboratory systems.  相似文献   

Isolation and characterization of phenanthrene-degrading strain Sphingomonas sp. GY2B     

Xueqin TAO Guining LU Zhi DANG Chen YANG Xiaoyun YI 《中国地球化学学报》2006,25(B08):109-109

Polycyclic aromatic hydrocarbons （PAHs） are of great concern since most of them have been shown to be toxic, mutagenic, and carcinogenic. Bioremediation, based on certain species of microorganisms, is regarded as an alternative method to detoxify or remove PAHs from the contaminated sites. Phenanthrene has been often used as a model substance for microbial metabolism of ＂bay-region＂ and ＂K-region＂ containing carcinogenic PAH. The focus of the present study is to isolate and identify microorganisms which could use phenanthrene as the sole carbon and energy source. Such microorganisms are expected to be of interest as a source organism for the bioremediation of PAHs polluted soils. The bacterial consortia were enriched from PAH contaminated soils with water-silicon oil biphasic systems. An aerobic bacterial strain efficiently utilizing phenanthrene as the sole carbon and energy source was isolated from bacterial consortia GY2 and identified as Sphingomonas sp. strain GY2B. Strain GY2B was susceptible to some common used antibiotics such as cefuroxime, chloramphenicol, erythromycin and tetracycline and intermediate susceptible to amoxycillin. Moreover, no plasmids could be isolated from strain GY2B using the standard alkaline-SDS method. At pH 7.4 and 30℃ strain GY2B had an optimal growth condition and in this condition above 99.8% phenanthrene was degraded under initial concentration of 100 mg/L. The addition of low concentration of glucose （10-200 mg/L） in MSM containing 100 mg/L phenanthrene could enhance the growth of strain GY2B, while the high concentration of glucose （〉500 mg/L） could exert an inhibitive effect on cell growth. Besides phenanthrene, strain GY2B could also use naphthalene, phenol, 1-hydroxy-2-naphthoic acid, 2-naphthol, salicylic acid and catechol as the sole carbon and energy source. The growth of strain GY2B on salicylic acid and catechol showed that the degradation of phenanthrene might follow salicylate pathway.  相似文献   

Desorption of zinc by kaolin from Suzhou, China     

Shengli WANG 《中国地球化学学报》2006,25(B08):124-125

Heavy metals in soils may adversely affect environmental quality. This paper studied the influence of copper concentration, pH, temperature, and the ratio of solid to solution on the desorption of Zn in kaolin from Suzhou, China in a background solution of 0.01M CaC12 by batch extraction experiments. At 0, 5, 50, 100 mg/L Cu concentrations, for each 0.5, increase in pH between about 1.80 and 3.04 percent desorption decreasing by 3.80%, 13.87%, 9.97%, and 7.65%, respectively. The pH 50 （ pH at 50% Zn desorption） was found to follow the sequence of Cu （5mg/L, pH 50=2.60）.  相似文献   

广西八一锰矿区土壤和主要农作物重金属含量的研究   总被引：7，自引：0，他引：7  

赖燕平  李明顺  杨胜香  陈春强  李艺 《矿产与地质》2006,20(6):651-655

对广西八一锰矿废弃地土壤基本理化性质及重金属全量(浓HC l 浓HNO3 HF HC lO4消解)、有效态含量(0.1MHC l浸提)和主要农作物重金属含量(浓HNO3 HC lO4消解)进行了测定(AA S)。结果表明:土壤营养缺乏和重金属污染是本矿区生态恢复面临的主要问题。土壤中全磷和全氮含量低于正常指标,且部分C/N比值偏高,同时土壤存在严重的Cd污染,并可能受到M n污染。在锰矿恢复区种植的主要农作物中,部分样品中Pb、M n含量与全部样品的C r、Cd含量超出了植物正常含量范围。农作物的食用部分中Cd、C r、Pb含量普遍超过国家食品限量卫生标准,不宜食用。  相似文献   

Study on the mechanism of transport of heavy metals in soil in western suburb of Beijing     

李宏艳王金生  滕彦国王震宇 《中国地球化学学报》2006,25(2):173-177

1 IntroductionIncorporation of potentially toxic metals ( e.g.Cd, Cu, Cr, Pb, Hg, As, Se, Zn, Ni) into soils ei-ther through sewage-sludge irrigation or some othersources of pollution (e.g. atmospheric deposition, ap-plication of agri-chemicals) has posed…  相似文献   

土壤中铊污染及防治对策     

刘敬勇 《矿物岩石地球化学通报》2007,26(Z1)

铊的丰度很低(0.75 mg/kg),相对比较而言,铊造成环境污染问题没有像As、Cd、Pb、Hg等元素普遍,目前Tl尚未纳入各级环保部门的监测范围,尤其在我国土壤研究中常常排斥在研究对象之外.含铊资源在利用过程中会向环境排放大量的铊,并通过大气、水体或食物链直接或间接地进入土壤并威胁着人类的健康.  相似文献   

江西南昌-樟树地区农业土壤环境质量评价     

詹天卫  鄢新华  谢勇  李幼华  戴君扬  毛大发 《物探与化探》2007,31(3):261-264

在研究区内,由于各种自然地质作用及人类活动综合影响,使作物营养有益元素及有毒、有害组分在区内表层土壤中的分布存在明显的不均衡性.以土壤中元素的含量分布为主要依据,在分析南昌-樟树地区土壤污染现状、农作物营养有益元素丰缺现状的基础上,对区内农业土壤环境质量进行了评价,并按环境质量的优劣划分了A、B、C、D共4个等级.  相似文献