Possibility of degradation of phenylarsonic acid in the presence of ferrihydrite     

Yoko Shimamoto Yoshio Takahashi 《中国地球化学学报》2006,25(B08):114-114

Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid （PA） is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry （HPLC-ICP-MS）. 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS （column： Tosoh TSKgel SuperlC-AP, eluent： 0.01 M HNO3）. It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system.  相似文献   

Effects of low molecular weight organic acids on sorption and desorption behavior of p-chlorophenol by yellow earth     

Daoyong ZHANG Xiangliang PAN Shuimu LIAO Chenglin HUANG Jingmei ZHANG 《中国地球化学学报》2006,25(B08):133-133

Low molecular weight organic acids （LMWOAs） are important components of root exudates. They play an important role in immobilizing and remobilizing contaminants in rhizospheric soil. Effects of four LMWOAs on the sorption and desorption behavior of p-chlorophenol by yellow earth was studied in batch mode. The results showed that the previous application of LMWOAs to enhanced adsorption capacity of p-chlorophenol of the soil in the order of maleic acid〉malic acid〉oxalic acid〉citric acid. However, when LMWOAs were applied to soil where p-chlorophenol had been previously adsorbed, substantial p-chlorophenol was desorbed from soil by oxalic acid, whereas citric acid, malic acid and maleic acid didn＇t desorb as much p-chlorophenol from soil as deionized water.  相似文献   

Analysis of the effect of geology, soil properties, and land use on groundwater quality using multivariate statistical and GIS methods     

Jin-Soo Lee Kyung-Seok Ko Tong-Kwon Kim Jae Gon Kim Seong-Hyun Cho In-Suk Oh 《中国地球化学学报》2006,25(B08):152-152

The regional survey of groundwater used as a small water supply system was performed to know the effect of geology, soil properties and land use on groundwater quality at Nonsan City, Korea. A total of 126 groundwater samples were collected and analyzed at the study area. The multivariate statistical methods, principal components analysis and discriminant analysis, and GIS technique were used for the quantitative interpretation of groundwater quality. The study area is mainly composed of Precambrian gneiss, Jurassic granite, and Cretaceous volcanics, and metasedimentary rocks of the Ogcheon zone. The land use was grouped as paddy, upland, grassland, resident, point source, industrial area, and water system. The soil properties were classified as 4 major groups, Entisols, Alfisols, Inceptisols, and Ultisols, by the degree of development, and reclassified as 11 subgroups. The modified and simplified geologic map, soil map, and land use map were made by using ARCGIS soft-ware. The area of geology, soil property, and land use affecting the groundwater quality for each well were also calculated by ARCGIS soft-ware to acquire the quantitative parameters for multivariate statistical analysis. The monitoring results of groundwater in the study area showed that 13%-21% of the groundwater samples exceeded the portable water guideline and the main causes were turbidity, bacteria, arsenic and nitrate-N. The spatial distribution of each component showed the close relationship between groundwater quality and geology reflecting the topography, land use.  相似文献   

三江平原旱田耕作对湿地土壤理化性质的累积影响初探   总被引：4，自引：5，他引：4  

袁兆华  吕宪国  周嘉 《湿地科学》2006,4(2):133-137

在中国科学院三江平原湿地生态试验站综合实验场,对不同耕作年限的湿地土壤(0~20 cm)进行环境累积效应分析。结果表明,随着开垦时间的增加,土壤的理化性质发生渐变,物理性质方面,土壤容重和比重逐渐增大,而孔隙度和田间持水量逐年减少;化学性质方面,土壤pH值随开垦时间的增加而增加,有机质和其他养分则随开垦时间的增加而逐年降低。弃耕后土壤性质有所恢复。土壤性质在开垦初期变化较明显,而后逐渐变缓。  相似文献   

Speciation analysis and significance of ecological geochemistry     

Yaping WANG Chunxue XU Ziyi AN Suming WANG 《中国地球化学学报》2006,25(B08):205-205

Different species of one element have different activities, so it has different effects on environment and human health. To analyze qualitatively and quantitatively the speciation of a special element in sample, which is the important basis for appraising the toxicity and studying the rule of transfer and translation of elements. Since the 1970＇s, the scheme of sequential extraction has already been used at many laboratories both at home and abroard, to get the information about heavy metals＇ activity in polluted soils. Because this method has the experimental nature, many schemes of problem has taken place, the absence of consistency of these sequential extraction have been formed. Thus the complexity of the schemes, the lack of selectivity of reagent, the lack of quality control, the result mainly related to the extraction scheme used, and so on. In the face of these problems, the study of experimental methods of sequential extraction on three different soils, sediment in Dongting Lake, soil in Jiangsu Province and loess in Shanxi Province was made. Reference materials of heavy metal speciation following sequential extraction in soil and sediment had been developed. Nowadays two kinds of sequential extraction methods which are widely used are BCR （three steps） and improved Tessier methods （seven steps）. Based on three steps of BCR, water-soluble speciation and the residual speciation were increased in our research. BCR701 was determined eight times at different laboratories using BCR three steps. The results showed that determined data obtained eight times were identical to the standard value, and it is indicated that this method has good reproducibility. The stability and homogeneity experiments indicated that the preparation of three types of candidates accorded with our requirements. Eight laboratories had afforded the determined values of 12 heavy metal elements （Cu, Pb, Zn, Mn, Co, Ni, Cd, Cr, Mo, As, Sb, Hg, Se et al.） using BCR three steps. Also, these three candidates afforded the determined values by seven steps, and 12 laboratories had participated.  相似文献   

Improved reliability in the interpretation of geochemical measurements by the quantification of uncertainty from sampling     

Michael H. Ramsey Paul D. Taylor Katy A. Boon 《中国地球化学学报》2006,25(B08):209-210

All geochemical measurements require the taking of field samples, but the uncertainty that this process causes is often ignored when assessing the reliability of the interpretation, of the geochemistry or the health implications. Recently devised methods for the estimation, optimisation and reduction of this uncertainty have been evaluated by their application to the investigation of contaminated land. Uncertainty of measurement caused by primary sampling has been estimated for a range of six different contaminated land site investigations, using an increasingly recognized procedure. These site investigations were selected to reflect a wide range of different sizes, contaminants （organic and metals）, previous land uses （e.g. tin mining, railway sidings and gas works）, intended future use （housing to nature reserves） and routinely applied sampling methods. The results showed that the uncertainty on measurements was substantial, ranging from 25% to 186% of the concentration values at the different sites. Sampling was identified as the dominant source of the uncertainty （〉70% of measurement uncertainty） in most cases. The fitness-for-purpose of the measurements was judged using the optimized contaminated land investigation （OCLI） method. This identifies the optimal level of uncertainty that reduces to overall financial loss caused by the measurement procedures and the misclassification of the contamination, caused by the uncertainty. Generally the uncertainty of the actual measurements made in these different site investigations was found to be sub-optimal, and too large by a factor of approximately two. The uncertainty is usually limited by the sampling, but this can be reduced by increasing the sample mass by a factor of 4 （predicted by sampling theory）. It is concluded that knowing the value of the uncertainty enables the interpretation to be made more reliable, and that sampling is the main factor limiting most investigations. This new approach quantifies this problem for the first time, and allows sampling procedures to be critically evaluated, and modified, to improve the reliability of the geochemical assessment.  相似文献   

Characterization of microbial communities associated with African desert dust and their implications for human and ecosystem health     

Christina A. Kellogg 《中国地球化学学报》2006,25(B08):218-219

Desert winds aerosolize several billion tons of soil-derived dust each year, including concentrated seasonal pulses from Africa and Asia. Huge dust events create an atmospheric bridge over continents and oceans, and eject a large pulse of soil-associated microorganisms into the atmosphere. These dust events might therefore have a role in expanding the biogeographical range of some microorganisms by facilitating rare long-distance dispersal events. The goal of this study is to characterize the microbes associated with African dust events and determine if they pose a risk to humans or downwind ecosystems. Air samples were collected by vacuum filtration in a source region （Mali, West Africa） during dust events and plated on R2A media to culture microorganisms. These organisms were compared to those in similar samples collected in the Caribbean during Saharan/Sahelian dust events. A high-volume liquid impinger is currently being tested in Barbados, collecting aerosol samples during African dust events. Over 100 bacteria and fungi （19 genera of bacteria and three genera of fungi） have been characterized from source region dust events.  相似文献   

Mercury behaviour during tropical weathering： Evidence from a Brazilian soil profile developed on diabase     

《中国地球化学学报》2006,25(B08):242-242

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Toxic and radioactive elements in soils and vegetation of natural and technogenic geosystems of Pribaikalye （Lake Baikal region）   总被引：1，自引：0，他引：1  

《中国地球化学学报》2006,25(B08):245-245

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Study on Kailyard soil amendment by adding compost of sludge     

Shaoqi ZHOU Weidong LU 《中国地球化学学报》2006,25(B08):252-253

Mixture of municipal sewage sludge and organic garbage, which was alternatively treated by aerobic and anaerobic composting technologies for 60 days. The characteristics of the compost are as follows： the total nitrogen （TN）, total phosphors （TP） and total potassium （TK） are 1.40%, 0.101% and 1908.32 mg/kg on dry weight basis, the contents of Cu, Ni, Cd, Cr, Pb and Zn are 131.23, 21.49, 1.31, 35.49, 72.50 and 616.76 mg/kg on dry weight basis. A basin-scale experiment was carded out by planting watercress with kailyard soil fertilizing with the compost, the results showed that the municipal sewage sludge and organic garbage compost could promote the production of watercress to different degrees, the crop biomass increased from 74.46% to 312.00% with the amount of compost fertilizing on the kaliyard soil while the amount of compost fertilizing on the kaliyard soil below 150 g per 3.75 kg kaliyard soil and decreased from 312.00% to 102.29% while the amount of compost fertilizing on it over 150 g per 3.75 kg kaliyard soil, so the optimal addition of compost in the watercress and soil was 150 g compost per 3.75 kg kailyard soil. Furthermore,  相似文献