Possibility of degradation of phenylarsonic acid in the presence of ferrihydrite     

Yoko Shimamoto Yoshio Takahashi 《中国地球化学学报》2006,25(B08):114-114

Although inorganic species are predominant in natural systems, but there are many kinds of organoarsenic species such as methylated and phenylated arsenic compounds. Phenylarsonic acid （PA） is a degradation product of organoarsenics used for chemical warfare agents, which has been detected in well water at the disposal site of the agents in Japan. There are few reports studying behavior of PA in soil. In this study, PA was adsorbed onto ferrihydrite and its chemical forms were determined using high performance liquid chromatography connected to inductivity-coupled plasma mass spectrometry （HPLC-ICP-MS）. 100 mg/kg of PA was mixed with 0.03 g of 2-line ferrihydrite. For each suspension, pH was adjusted by HNO3 or NaOH. Each sample was incubated for more than 19 hours and the final pH was measured. After filtration, the chemical form of arsenic in the filtrate was measured using HPLC-ICP-MS. In addition, ferrihydrite separated by filtration was dissolved by 3 ml of 0.5 M HCI and the arsenic species in the solution was detected by HPLC-ICP-MS （column： Tosoh TSKgel SuperlC-AP, eluent： 0.01 M HNO3）. It was verified that PA is not degraded by heating in 0.5 M HCl solution. At pH 3.1, any arsenic compounds were not detected from the solution, because almost all arsenic species were adsorbed onto ferrihydrite at lower pH. At pH= 12, however, 7%-10% of inorganic arsenic was detected in the solution. In solid phase, there are some problems to determine the precise ratio of inorganic and organic species. When the solution includes Fe ion at 0.01 M level, the retention time of arsenic species drifted compared to those in standard solution, which makes it difficult to determine precisely the arsenic species adsorbed on ferrihydrite. Therefore, more study is needed to determine the ratio of inorganic and organic species in the system.  相似文献   

Application of HCA and PCA in the discrimination of not polluted tubular wells from tubular wells with incidence of anthropogenic pollution in Western Amazon Region     

《中国地球化学学报》2006,25(B08):165-165

  相似文献   

构造煤与原生结构煤的显微傅立叶红外光谱特征对比研究   总被引：3，自引：0，他引：3  

李小明曹代勇  张守仁魏迎春 《中国煤田地质》2005,17(3):9-11

通过对平顶山、郑州和南票三大矿区石炭二叠纪含煤岩系中高煤级烟煤和无烟煤的显微傅立叶红外光谱分析，探讨了原生结构煤与构造煤的有机大分子结构演化特征及其影响因素。结果表明，构造应力有利于煤中氢发生化学环境转移，使脂肪烃含量相对减少、稳定的芳香烃含量相对增加，促进煤大分子结构缩合度和有序度增加。  相似文献   

唐山：重拳打击非法采矿行为     

黄志宏 《河北国土资源》2005,(6):44-44

为进一步巩固矿业治理整顿成果，依法严厉打击非法采矿活动，近日，唐山市国土资源局与遵化市国土资源局执法人员一起，在当地公安及有关部门配合支持下，集中一周时间对遵化市石人沟铁矿周边地区及东陵地区非法采矿行为进行了集中治理整顿，执法人员坚决排除各种阻力，炸毁矿井5座，封填矿井4座，  相似文献   

营造绿色建家园——迁安拉开绿色矿山建设序幕     

岳春光 《河北国土资源》2005,(7):26-26

4月10日上午，迁安市凯达公司红石崖铁矿在矿领导的亲自指挥下，仅半天时间就调动员工百余人，在厂区尾矿坝上栽植25000株沙棘树苗。象红石崖铁矿这样，全市已有10个大中型矿山企业都在紧锣密鼓的栽植沙棘树苗，累计达60多万株。市国土资源局为了整体推进全市绿色矿山建设，在进行摸底、分析的基础上，确定磨盘铁矿、南山铁矿、凯达公司工石崖铁矿和新水一矿、二矿等具有一定代表性的10家矿山企业作为试点，因地制宜扶持他们进行绿化建设，在全市拉开了建设绿色矿山的序幕。  相似文献   

吐哈盆地侏罗纪煤中主要组分结构特征与生烃性分析   总被引：10，自引：0，他引：10  

孙旭光  陈建平  王延斌 《沉积学报》2002,20(4):721-726

在高纯度煤岩显微组分分离富集的基础上,应用透射式显微傅里叶红外光谱技术 (Micro FTIR),对吐哈盆地侏罗纪煤中的主要组分-镜质体、丝质体、角质体、藻类体的结构组成进行了测定。结果表明 :藻类体主要由长链脂族结构组成,芳香结构含量相对较少;角质体和基质镜质体中含有较丰富的芳香结构以及长链脂族结构;而丝质体则主要由芳香结构组成,脂族结构含量很少。显微组分的这种结构特征决定了藻类体具有很高的生烃潜力、角质体和镜质体的生烃潜力中等、而丝质体的生烃潜力则很低。对于吐哈盆地煤成油来说,由于藻类体主要由长链脂族结构组成,并且生烃潜力也高,因此其具有高的液态烃产率、丝质体的产油率最小、角质体和镜质体的液态烃产率中等。由于镜质体是本区煤中含量最高的组分。因此,对于吐哈盆地所形成的具有工业规模的油田来说,镜质体应该是主要的贡献组分之一。但对于富含藻类体的厚层状烛藻煤,由于它类型好,品质高、生烃潜力大、以中长链脂族结构为主,是煤成油最理想的源岩。  相似文献   

对鞍山式铁矿(条带状含铁石英岩)尾矿中含金的几点认识和探讨     

王书丹 《吉林地质》2002,(2)

鞍山式铁矿尾矿中含有金，它是各种地质作用的综合产物，也是火山沉积的中基性岩本身含有微量金造成的。建议开采该类型铁矿的同时研究回收铁矿尾矿中的金，加强矿床的综合利用，提高企业经济效益。  相似文献   

张八岭构造带两种类型金矿次显微金赋存状态的质子探针分析     

黄德志  邱瑞龙等 《地质地球化学》2002,30(3):19-26

金属硫化物中次显微金的赋存状态已引起人们的重视。张八岭构造带蚀变构造岩型和石英脉型两类金矿金属硫化物中次显微金质子探针分析显示，Au与As、Fe、S、Cu、Pb呈正相关关系，Au以显微包裹体形式存在于金属硫化物中。与蚀变构造岩型金矿相比，晚期的石英脉型金矿可见自然金含量较高，硫化物中显微包裹体金含量较低，可能预示中低温热液金矿中，不仅普遍存在时空分异的金属硫化物中的类质同象金和自然金，还可能存在一定程度的时空分异的自然金和次显微包裹体金。  相似文献   

Isotopic Ages of the Carbonatitic Volcanic Rocks in the Kunyang Rift Zone in Central Yunnan, China     

ZHANGYongbei WANGGuilan NIEJianfeng ZHAOChongshun XUChengyan QIUJiaxiang WangHao 《《地质学报》英文版》2003,77(2):204-211

The Mesoproterozoic Kunyang rift, which is located on the western margin of the Yangtze platform and the southern section of the Kangdian axis, is a rare massive Precambrian iron-copper polymetallic mineralization zone in China. The Mesoproterozoic Wulu (Wuding-Lufeng) basin in the middle of the rift is an elliptic basin controlled by a ring fracture system. Moreover, volcanic activities in the basin display zonation of an outer ring, a middle ring and an inner ring with carbonatitic volcanic rocks and sub-volcanic dykes discovered in the outer and middle rings. The Sm-Nd isochron ages have been determined for the outer-ring carbonatitic lavas (1685 Ma) and basaltic porphyrite of the radiating dyke swarm (1645 Ma) and the Rb-Sr isochron ages for the out-ring carbonatitic lavas (893 Ma) and the middle-ring dykes (1048 Ma). In combination of the U-Pb concordant ages of zircon (1743 Ma) in trachy-andesite of the corresponding period and stratum (1569 Ma) of the Etouchang Formation, as well as the Rb-Sr iso  相似文献   

卫东庄韧性剪切带显微构造解析及运动学特征     

吴玉门 《新疆地质》2003,21(2):243-244,T001

卫东庄韧性剪切带位于库鲁克塔格地区辛格尔大断裂以北,大地构造位于塔里木构造北缘活动带之南天山古生代陆缘盆地东段(图1).受塔里木构造运动的影响u, 在辛格尔大断裂两侧,不同时代地层构造变形强烈,构造样式复杂.本文主要以该断裂北侧卫东庄韧性剪切带Ⅳ、Ⅴ、ⅩⅦ号剖面的岩石学、地质学资料为基础,研究其运动学特征并探讨东天山地区塔里木北缘活动带,构造变形性质及运动规律.卫东庄韧性剪切带呈狭长带状,EW向分布,长约30 km,东段宽3.0 km,中段宽4.0 km,西段宽2.0 km.主要由下元古界阿牙克托格拉克岩组(Pt1aa.)、大树沟片麻杂岩(Pt1Dsc…  相似文献