胶北南山口含榴辉石岩岩石学与锆石U-Pb定年的初步研究   总被引：3，自引：2，他引：1  

刘平华  刘福来  王舫  刘建辉  蔡佳 《岩石学报》2014,30(10):2951-2972

胶北南山口镁铁-超镁铁质杂岩主要由含榴辉石岩和含榴基性麻粒岩所组成,且以不规则透镜体的形式赋存于太古宙英云闪长质片麻岩之中。岩相学观察、矿物相转变分析与矿物化学研究结果表明,胶北南山口含榴辉石岩不仅普遍发育近等温减压反应结构,即石榴石+富钙流体→单斜辉石+葡萄石+榍石±钠长石与石榴石+富钙流体+二氧化碳→角闪石+葡萄石±钠长石±方解石±榍石,指示其早期可能经历了高压麻粒岩相变质作用。而且,与南山口含榴基性麻粒岩类似,在晚期降温退变过程中,它们还经历了强烈的钙质交代作用,形成富钙矿物组合:富钙铝榴石的石榴石+次透辉石质单斜辉石+钙质角闪石+葡萄石+钠长石+方解石+榍石。SHRIMP锆石U-Pb定年结果表明,胶北南山口含榴辉石岩中的岩浆锆石记录了2900~2850Ma的207Pb/206Pb年龄,指示胶北地体在中太古代晚期存在一次重要的岩浆事件,而其变质锆石还记录了1950~1800Ma的207Pb/206Pb年龄,说明胶北南山口镁铁-超镁铁质杂岩曾卷入了胶北古元古代晚期地壳造山作用。结合研究区其它地质研究资料,本文推断胶北南山口镁铁-超镁铁质杂岩可能形成于古元古代,是华北克拉通胶-辽-吉带古元古代岩系的重要组成部分,并于1950~1800Ma期间,卷入了胶-辽-吉带古元古代造山作用,先后经历了高压麻粒岩相变质作用和晚期降温与钙质交代的联合退变质作用。  相似文献   

徐淮早白垩世埃达克质岩中含橄榄石单斜辉石岩的成因及其岩石学意义          下载免费PDF全文

周群君  许文良  王清海  杨德彬  裴福萍  于洋 《地球科学》2014,39(2):141-154

报道了徐淮地区早白垩世埃达克质岩中首次发现的含橄榄石单斜辉石岩捕虏体的岩相学与矿物化学资料, 该类捕虏体显示堆积结构、块状构造, 主要由单斜辉石(~80%)、斜方辉石(~5%)、橄榄石(~5%)和普通角闪石(~10%)组成.橄榄石外侧发育有斜方辉石反应边, 角闪石沿辉石粒间分布, 呈嵌晶结构.矿物化学分析结果表明: 橄榄石的镁橄榄石分子值(Fo)=77.7~79.3, Ni=623×10-6~773×10-6; 斜方辉石的Mg#=75.6~80.2, Cr=161×10-6~684×10-6, Ni=79×10-6~708×10-6; 单斜辉石的Mg#=84.5~86.4, CaO=21.59%~23.13%, Al₂O₃=1.72%~2.44%.上述矿物与中、新生代玄武岩中橄榄石、斜方辉石和单斜辉石斑晶以及堆积成因辉石岩中的斜方辉石和单斜辉石成分类似.此外, 单斜辉石的稀土配分型式以相对富含中稀土元素的上凸型为特征, 稀土元素含量较低(∑REE=10.14×10-6~12.71×10-6), 无明显的铕异常(δEu=0.90~1.16), 类似于新生代玄武岩中单斜辉石斑晶.捕虏体中的普通角闪石的Mg#=74.0~80.4、SiO₂=43.2%~44.5%、Na₂O=2.04%~2.29%, 稀土元素分馏不明显, 显示亏损高场强元素(HFSEs, 如Nb、Ta、Zr、Hf), 富集Sr、Rb、Ba的特征, 与新生代玄武岩中角闪石捕虏晶成分不同.结合其嵌晶结构, 普通角闪石应是寄主岩浆贯入结晶的产物.综合上述特征, 可以看出含橄榄石单斜辉石捕虏体为镁铁质岩浆高压堆晶成因.结合华北克拉通东部早白垩世双峰式火山岩组合的出现, 推断含橄榄石单斜辉石岩捕虏体可能是早白垩世基性岩浆底侵的产物.   相似文献   

桂北圆石山早侏罗世A型花岗岩的岩石成因及意义          下载免费PDF全文

贾小辉  王晓地  杨文强  牛志军 《地球科学》2014,39(1):21-36

桂北圆石山花岗岩中发育大量镁铁质包体.LA-ICP-MS锆石U-Pb定年结果显示, 花岗岩形成于早侏罗世(179±2 Ma).花岗岩的地球化学特征表现为硅含量均一, 富碱更富钾、相对富铁而贫镁, 具有高的104×Ga/A1比值和Zr+Nb+Ce+Y含量, 属于A型花岗岩.圆石山花岗岩具有比较均一的Sr、Nd同位素组成(I_Sr＝0.701 7~0.710 8, ε_Nd(t)＝-7.77~-4.55).镁铁质包体则显示了稍低的I_Sr值(0.705 0~0.707 1)和稍高的ε_Nd(t)值(-4.87~-2.63).花岗岩的锆石原位Hf同位素组成为: (176Hf/177Hf)_i=0.282 62~0.282 70, ε_Hf(t)=-1.68~1.17, 相应的Hf同位素两阶段模式年龄T_DM2变化于1.25~1.43 Ga之间.圆石山花岗岩可能是在伸展环境下由低成熟度的下地壳物质部分熔融所形成.自早侏罗世(~200 Ma)以来, 伸展作用是华南内陆构造背景的主体, 多期次的玄武质岩浆底侵作用可能是燕山期伸展作用的直接诱因.华南内陆早侏罗世时期可能仍处于板内“后碰撞”环境.   相似文献   

储层温度对CO2矿物封存的影响          下载免费PDF全文

卜繁婷许天福  王福刚等 《水文地质工程地质》2014,(1):101-105

在二氧化碳地质储存中,储层温度是影响CO2矿物储存量的因素之一。文章选取美国Gulf Coast地区的资料,并设置6种温度敏感性分析方案,使用TOUGHREACT/ECO2N软件模拟并分析了温度变化对CO2矿物捕集的影响,得出三个结论:长石类矿物、高岭石、绿泥石是主要的溶解矿物,方解石并非主要的溶解矿物;主要固碳矿物为铁白云石和片钠铝石,两者与绿泥石存在较好的相关性,并且沉淀量与温度变化正相关;CO2体积分数随时间变化幅度和矿物捕获总量均与温度呈正相关。通过分析储层温度对矿物捕获CO2的影响,为选取CO2储层提供温度上的考量。  相似文献   

内蒙古苏布格塔蓝闪石片岩基本特征及成因分析          下载免费PDF全文

张庆奎邵学峰  关培彦杨 宾赵明远  李安楠吕凤祥 《中国地质》2014,41(4):1205-1214

苏布格塔蓝闪石片岩赋存于奥陶纪哈拉哈河组地层中,岩石组合类型多样,据蓝闪石光学特征及电子探针分析结果,认为本区的蓝闪石属铁蓝闪石。蓝闪石片岩的标型矿物组合以蓝闪石+绿帘石+阳起石+多硅白云母+榍石为特点,由泥质碎屑岩变质重结晶形成,原岩形成环境为大陆边缘海盆地。其变质成因,属于与板块运动有关的区域低温中高压动力变质作用形成。  相似文献   

新疆霍什布拉克铅锌矿床微量元素地球化学     

李志丹  薛春纪  董新丰  王思程  张岩 《岩石矿物学杂志》2014,33(3):540-550

霍什布拉克铅锌矿床是新疆西南天山地区晚古生代碳酸盐岩容矿的重要矿床。本文采用高精度电感耦合等离子质谱(ICP-MS)对主要矿石矿物(黄铁矿、方铅矿、闪锌矿)和热液脉石矿物方解石进行了微量元素地球化学研究。研究表明,黄铁矿、方铅矿、闪锌矿、方解石具有较为相似的稀土元素特征,Eu正异常明显,弱负或弱正Ce异常指示成矿流体最初由相对氧化的条件演化为还原条件。与霍什布拉克岩体、容矿围岩的稀土元素组成进行对比后发现,硫化物及热液方解石稀土元素配分曲线部分与重结晶泥晶灰岩重合,结合前人同位素地球化学研究,认为容矿坦盖塔尔组碳酸盐岩为成矿提供了必要的成矿物质及成矿流体组分。Ga/In值显示闪锌矿为低温成矿;硫化物明显富集LREE,Hf/Sm、Nb/La和Th/La值小于1,显示铅锌成矿过程中成矿流体主体以富Cl为特征;Y/Ho、Zr/Hf和Nb/Ta值变化范围相对较小,表明成矿期流体性质相对较为稳定,基本未混入外来流体。  相似文献   

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge     

Bing Li  Xuefa Shi  Yaomin Yang  Jun Ye  Jingjing Gao  Wenqin Zheng 《中国地球化学学报》2014,33(4):325-335

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.  相似文献   

Mineral characteristics and their geological significance of black shales in southeastern Ordos Basin by X-ray diffraction analysis     

Zhigang Yao  Yang Yang  Huawei Ying  Yunpeng Dong 《中国地球化学学报》2014,33(1):119-124

X-ray diffraction analysis of black shale of Upper Triassic Member Chang 7 of the Yanchang Formation in southeastern Ordos Basin showed that black shales were deposited in brackish, strongly reducing, semi-deep-deep lacustrine facies, and mainly composed of quartz, feldspar, carbonate （dolomite）, clay minerals （illite and il- lite/smectite） and a certain amount of pyrite. The mineral composition characteristics of this set of black shales are similar to those of highly productive shale gas in North America, for example shallow burial, low clay mineral and abundant brittle mineral, so the strata are conducive to the development of cracks and fractures. Thus, this area is favorable for shale oil/gas exploration and development.  相似文献   

The relationship between apparent equilibrium temperature and closure temperature with application to oxygen isotope geospeedometry     

Huaiwei Ni 《中国地球化学学报》2014,33(2):125-130

Oxygen isotope fractionation between coexisting minerals in slowly cooled rocks conveys information about their cooling history. By using the fast grain boundary （FGB） model to simulate closed-system diffusive ex- change of oxygen isotopes between coexisting minerals, I show that the apparent equilibrium temperatures （Tae） by the mineral pair with the largest isotopic fractionation （PLIF） always lies between the closure temperatures （To） of those two minerals. Therefore, when the rate of oxygen diffusion and hence Tc for the PLIF chance to be comparable （such as in the case of quartz and magnetite）, Tae will serve as a good approximation of To regardless of variation in mineral proportions. The specialty of the PLIF in constraining Tac within their Tc range can be generalized to other stable isotope systems and element partitioning. By approximating Tc with Tac and inverting Dodson＇s equation, the cooling rate of plutonic or metamorphic rocks can be inferred.  相似文献   

Correlation analysis and partial least square modeling to quantify typical minerals with Chang＇E-3 visible and near-infrared imaging spectrometer＇s ground validation data     

LIU Bin  LIU Jianzhong  ZHANG Guangliang  LING Zongcheng  ZHANG Jiang  HE Zhiping  YANG Benyong  ZOU Yongliao 《中国地球化学学报》2014,33(1):86-94

In 2013, Chang＇E-3 program will develop lunar mineral resources in-situ detection. A Visible and Near-infrared Imaging Spectrometer （VNIS） has been selected as one payload of CE-3 lunar rover to achieve this goal. It is critical and urgent to evaluate VNIS＇ spectrum data quality and validate quantification methods for mineral composition before its launch. Ground validation experiment of VNIS was carried out to complete the two goals, by simulating CE-3 lunar rover＇s detection environment on lunar surface in the laboratory. Based on the hyperspectral reflectance data derived, Correlation Analysis and Partial Least Square （CA-PLS） algorithm is applied to predict abundance of four lunar typical minerals （pyroxene, plagioclase, ilmenite and olivine） in their mixture. We firstly selected a set of VNIS＇ spectral parameters which highly correlated with minerals＇ abundance by correlation analysis （CA）, and then stepwise regression method was used to find out spectral parameters which make the largest contri- butions to the mineral contents. At last, functions were derived to link minerals＇ abundance and spectral parameters by partial least square （PLS） algorithm. Not considering the effect of maturity, agglutinate and Fe~, we found that there are wonderful correlations between these four minerals and VNIS＇ spectral parameters, e.g. the abundance of pyroxene correlates positively with the mixture＇s absorption depth, the value of absorption depth added as the in- creasing of pyroxene＇s abundance. But the abundance of plagioclase correlates negatively with the spectral parame- ters of band ratio, the value of band ratio would decrease when the abundance of plagioclase increased. Similar to plagioclase, the abundance of ilmenite and olivine has a negative correlation with the mixture＇s reflectance data, if the abundance of ilmenite or olivine increase, the reflectance values of the mixture will decrease. Through model validation, better estimates of pyroxene, plagioclase and ilmenite＇s abundances are given. It is concluded that VNIS has the capability to be applied on lunar minerals＇ identification, and CA-PLS algorithm has the potential to be used on lunar surface＇s in-situ detection for minerals＇ abundance prediction.  相似文献