Catalytic ozonation of phenol in water with natural brucite and magnesia     

Kun HE Yuming DONG Lin YIN Aiming ZHANG Zhen LI 《中国地球化学学报》2006,25(B08):101-101

Catalytic ozonation has attracted much attention in treatment of wastewater for its mild conditions. Phenol and its ramifications are common components in a wide variety of wastewaters including those from coal conversion processes, coking plants, petroleum refineries and several chemical industries. In this paper, natural brucite and magnesia have been successfully used in catalytic ozonation of phenol. And the mechanisms of catalysis were also investigated. From Figs. 1 and 2, it can be found that both brucite and magnesia have remarkable catalysis on degradation of phenol and removal of Chemical Oxygen Demand （COD）. The pH of solutions on the process of ozonation alone, catalytic ozonation with brucites and with magnesia were 6.35-2.76, 10.18-8.52 and 10.58-10.83, respectively. It can be concluded that alkali environment plays a critical role for catalytic ozonation of phenol. We also found that the alkaline minerals reacted on the surface with oxalic acid and other low molecular-weight acids which are intermediate products in ozonation, but those intermediate products could be mineralized into carbon dioxide completely with enough ozonation time.  相似文献   

中国古代常规日食记录的整理分析   总被引：2，自引：0，他引：2  

刘次沅 《时间频率学报》2006,29(2):151-160

收集并分析了公元前8世纪到公元15世纪的中国古代密集、简略而公式化的日食记录。基于这些记录整理成一个包括938条日食记录的计算机可读形式的“常规日食记录表”。该表给出每次记录的原日期、公历日期、当时首都、所属朝代以及一部分记录所载的进一步详情。对该表的构成作了介绍,并对这些历史记录进行了初步的分析和归纳。  相似文献   

Hydrogeochemical controls on surface and groundwater chemistry in naturally acidic, porphyry-related mineralized areas, southern Rocky Mountains     

Philip L. Verplanck D. Kirk Nordstrom Geoff S. Plumlee Richard B. Wanty Dana J. Bove Jonathan S. Caine 《中国地球化学学报》2006,25(B08):231-231

In southern Rocky Mountains, catchments characterized by acidic, metalliferous waters that are relatively unaffected by human activity usually occur within areas that have active or historical mining activity. The US Geological Survey has utilized these mineralized but unmined catchments to constrain geochemical processes that control the surface- and ground-water chemistry associated with near surface acid weathering as well as to estimate premining conditions. Study areas include the upper Animas River watershed, Lake City, Mt. Emmons, and Montezuma in Colorado and Questa in New Mexico. Although host-rock lithologies range from Precambrian gneisses to Cretaceous sedimentary units to Tertiary volcanic complexes, mineralization is Tertiary in age and associated with intermediate to felsic composition, porphyritic plutons. Pyrite is ubiquitous. Variability of metal concentrations in water is caused by two main factors： mineralogy and hydrology. Parameters that potentially affect water chemistry include： host-rock lithology, intensity of hydrothermal alteration, sulfide mineralogy and chemistry, gangue mineralogy, length of flow path, precipitation, evaporation, and redox conditions. Springs and headwater streams have pH values as low as 2.5, sulfate up to 3700 mg/L and high dissolved metal concentrations （for example： Al up to 170 mg/L; Fe up to 250 mg/L; Cu up to 3.5 mg/L and Zn up to 14 mg/L）. With the exception of evaporative waters, the lowest pH values and highest Fe and Al concentrations occur in water draining the most intense hydrothermally altered areas consisting of the mineral assemblage quartz-sericite-pyrite. Stream beds tend to be coated with iron floc, and some reaches are underlain by ferricrete. When iron-rich ground water interacts with oxygenated waters in the stream or hyporheic zone, ferrous iron is oxidized to ferric iron, which is less soluble, leading to the precipitation of iron oxyhydroxides.  相似文献   

Naturally acidic and metalliferous waters at unmined volcanogenic massive sulfide deposits in the Bonnifield mining district, Alaska Range, east-central Alaska     

Robert G. Eppinger Paul H. Briggs Cynthia Dusel-Bacon Stuart A. Giles Larry P. Gough Jane M.Hammarstrom Bernard E. Hubbard 《中国地球化学学报》2006,25(B08):232-232

The Bonnifield district hosts 26 tmmined volcanogenic massive sulfide （VMS） occurrences. Environmental geochemical samples of water and stream sediment were collected at several occurrences, concentrating on the two best-exposed and largest deposits, Red Mountain （RM） and Sheep Creek （SC）. Limited samples were also collected at the poorly exposed WTF deposit. The deposits are Late Devonian to Early Mississippian, and are hosted by felsic metavolcanic and carbonaceous schist members of the Totatlanika Schist or Keevy Peak Fm. Spring and stream waters at RM and SC have pH values commonly 〈3.5 （as low as 2.4 at RM and 2.5 at SC）, high conductivity （up to 11000 μS/cm）, and very high （Is to 100s mg/L） dissolved contents of Al, Cd, Co, Cu, Fe, Ni, and Pb. Waters at RM are characterized by extremely high REE contents （summed REE median 3200 μg/L, n=33）. At both RM and SC, pyrite oxidation and dissolution produce low pH waters that interact with and dissolve bedrock minerals, resulting in acidic, metal-laden, naturally degraded streams that are mostly devoid of aquatic life. Ferricrete is common. In contrast, WTF barely produces a surficial environmental footprint, mostly due to topography and relief. RM and SC are well exposed in the areas of relatively high relief, and both exhibit extensive areas of quartz-sericite-pyrite-alteration. While WTF shares many of the same deposit-and alteration characteristics, it is concealed by tundra in a large, nearly flat area. Surface water at WTF is absent and outcrops are sparse. Even though WTF is roughly the same size as Red Mountain （both around 3 million tonnes） and has similar base- and precious-metal grades, the surficial geochemical manifestation of WTF is minimal. However, exposure through mining of the altered, mineralized rock at WTF potentially could initiate the same processes of pyrite oxidation, acid generation, and mineral dissolution that are observed naturally at RM and SC.  相似文献   

Structural Evolvement of Heating Treatment of Mg/AI-LDH and Preparation of Mineral Mesoporous Materials     

CHEN Tianhu XU Huifang WANG Yifeng QING Chengsong FAN Mingde CHEN Gang 《《地质学报》英文版》2006,80(2):170-174

Although hydrotalcite, or layered double hydroxides （LDHs）, is not a common mineral, it is an important material that can be easily synthesized in laboratory. In this study, structural evolvement and BET surface area changes of heat treated Mg/AI-LDH is evaluated by XRD, TEM and N2-BET analyses. The results indicate that the magnesium-aluminum LDH with carbonate as interlayer anion, periclase-like oxides was formed at temperatures of 400-800℃. Meanwhile, 2-3 nanometer mesoporous were formed during decomposition of LDH. However, the heat treated samples still preserve the morphology of the original LDH plates. Periclase-like formed from LDH heat treatment may re-hydrolyze and recover the structure of LDH. However, crystallinity of the recovered LDH is lower than that of the original LDH. This heat treatment will result in formation of （Mg, Al）-oxide nano-crystals and nanopores among the nano-crystals. When heating temperature exceeds 1000, the periclase-like （Mg, Al）-oxide is transformed into a composite with periclase （MgO） and spinel phases. The periclase can be re-hydrolyzed and dissolved in HCl solution. After acid treatment, the sample with a high surface area is composed of spinel nano-crystals and nanopores among them. Our results will provide a new and economic way to synthesize mesoporous materials through pathways of phase transformation of precursor materials with different composition.  相似文献   

华南下寒武统镍钼矿层中铜铅锌矿物的发现及意义     

陈益平  潘家永  夏菲  郭国林  陈少华  曹双林  严兆斌 《华东地质学院学报》2006,29(1):32-37

华南扬子地块是我国古热水沉积成矿作用最为发育的地区之一,其热水沉积特性最早引起我国学者的关注。华南下寒武统黑色岩系中赋存多个与热水沉积成矿作用相关的大型、超大型重晶石矿床与N i-Mo-U-V多金属富集层。进一步研究分布在华南扬子地块黑色岩系中的金属、非金属矿床成因及其地球化学特征,对认识华南乃至全球晚震旦—早寒武世生物与环境演化有着十分重要的意义。本文对华南下寒武统镍-钼富集层矿石进行电子探针研究,识别出黄铜矿、黝铜矿等铜的独立矿物;闪锌矿等锌的独立矿物;方铅矿、白铅矿等铅的独立矿物。研究表明,在镍-钼矿石中这些矿物的发现为镍-钼矿层是热水沉积作用产物提供了直接的矿物学证据。  相似文献   

四川盆地南部志留系碳酸盐泥丘储层发育特征   总被引：1，自引：0，他引：1  

赵文智  杨晓萍  Steve KERSHAW 《地质学报》2006,80(10):1615

灰泥丘主要发育在台缘斜坡及台地内部水体比较安静的缓坡环境中,缓坡环境和较弱的水动力条件是形成灰泥丘的两个重要条件。通常情况下礁、丘不相互共生。灰泥丘主要由微生物(蓝藻及其它微观藻类、细菌等)建造的,或者以微生物为主、并有其它多门类生物(珊瑚、苔藓虫、层孔虫、海绵、棘皮、头足、腕足、多门类钙藻等)参与建造的,是主要由灰泥组成、具有穹形特征的碳酸盐岩建隆。其中,灰泥是指粒径小于0.01mm或0.005mm的碳酸盐矿物,而非陆源粘土矿物,是热带、亚热带静水环境中沉积的特有产物之一,并主要由微生物通过新陈代谢、光合作用胶结固化…  相似文献   

首席科学家简介     

《地质学报》2006,80(9):I0002

侯增谦，男，河北人，1961年出生。1985和1988年分获中国地质大学矿物岩石矿床专业硕士和博士学位。1993-1994年在日本地质调查所做博士后研究，1995年晋升为研究员、博士生导师。2002年被科技部聘为国家973项目首席科学家。曾任中国地质科学院院长助理、矿产资源研究所副所长，现任中国地质科学院地质研究所所长，兼任中国矿物岩石地球化学学会理事、中国CSDP科学委员会副主任、中国ODP科学委员会委员、中国地质学会岩石专业委员会副主任、“中国科学”特约编辑等职。  相似文献   

地图科研成果荣获国家自然科学奖     

《地图》2005,(3):7-7

不久前颁布的2004年度国家自然科学奖中．由国家测绘局推荐的项目《数字地表模型的多维动态构模研究》荣获二等奖。该项目由国家基础地理信息中心陈军、香港理工大学教授李志林、以及朱庆、蒋捷、王东华等人合作完成。他们针对多维动态数字地表模型构建这一国际学术前沿问题．以地理空间实体及相互间关系的抽象与表达为主线．研究了地表空间铺盖、地物空间关系理论、数字地形精度、多维动态空间数据建模、多尺度表达等基本问题。  相似文献   

苦橄岩、苦橄玢岩的命名及特征     

戚长谋 《吉林大学学报(地球科学版)》2005,35(3):339-339

岩石学中,中文以"苦"字命名的岩石仅有苦橄岩和苦橄玢岩."苦"字是从日文转译而来,是镁的意思,因该岩石中主要造岩矿物为富镁的橄榄石.日文中镁(グト)音为Kaodao,为中文"苦"的谐音,因得译名.  相似文献