陆丰南地区断拗转换界面厘定及其地质意义     

阙晓铭  雷永昌  张向涛  邱欣卫 《地质学报》2022,96(11):3943-3954

珠江口盆地经历裂陷阶段向拗陷阶段的转变，同期沉积地层记录了该构造变革和沉积演化过程，为厘定断拗转换界面提供了可能。基于地震反射、沉积旋回特征，识别出陆丰南地区恩平组内部存在全区可追踪对比的构造沉积转换面——T72界面，也是区分上下恩平组界面。对陆丰13洼洼间隆钻井LFA开展上下恩平组碎屑锆石U- Pb 定年、重矿物组分、元素分析，提出恩平组T72界面上下地层物源体系发生转变。结合区域沉积充填特征，表明陆丰南地区T72界面为断- 拗转换界面。具体表现为：下恩平组沉积期湖盆继承文昌期裂陷盆地特征，湖盆水体较深，物源主要为盆地内部的中生代基底凸起，沉积层序明显受盆内低凸起控制，在盆内低凸起四周发育一系列近源的辫状河三角洲，井区主要接受来自惠陆低凸起物源;上恩平组沉积期间，湖盆进入断拗过渡期，湖盆扩大、水体变浅，盆内低凸起四周的断裂活动减弱，沉积层序逐渐向盆内低凸起超覆，盆外太古宙—古生代物源组分供给不断加强，近源的三角洲砂体逐渐向远源的浅水三角洲砂体转化，同时发育宽广的滨浅湖环境，原供给物源的惠陆低凸起为水体淹没，井区接受了北部隆起外的物源。  相似文献   

张广才岭南部杨木岗组的厘定及物源分析     

任永健  张成信  孟庆伟 《地质学报》2022,96(7):2333-2347

本文通过岩石组合特征和区域对比，将张广才岭南部西蛤拉河子—大锅盔一带分布的浅变质地层重新厘定为杨木岗组。为了确定杨木岗组的形成时代和沉积物源，进行了碎屑锆石U- Pb年代学和微体古生物地层学研究。锆石大多数呈自形—半自形晶，显示典型振荡岩浆生长环带，暗示其岩浆成因。该地层中测得的两组碎屑锆石U- Pb产生多组谐和年龄，其中PM010- TW样品56个测点最小峰值(谐和)年龄为307 Ma，DB02- TW样品51个测点最小峰值(谐和)年龄为275 Ma；覆盖在杨木岗组之上的中生代二浪河组安山岩的定年结果为181. 1±0. 9 Ma，表明杨木岗组形成于早二叠世晚期。杨木岗组中获取疑源类化石组合出现了新元古代晚期—早寒武世和奥陶纪地层常见分子，结合碎屑锆石年龄结果，反映杨木岗组沉积时周围存在早古生代和中—新元古代地质体。碎屑沉积岩Al2O3/TiO2平均值为24. 44，稀土元素球粒陨石标准化曲线具有轻稀土富集、重稀土稳定和负Eu异常特征，结合碎屑锆石的年龄频数可以看出，确定杨木岗组的沉积物主要来源于沉积盆地周围的晚古生代早期中酸性火成岩，次要物源由沉积盆地周边的早古生代地质体和近地表的中—新元古代地质体提供。佳木斯地块为松嫩- 张广才岭地块上晚古生代地层的形成提供了部分物源，暗示佳木斯地块与松嫩- 张广才岭地块于早二叠世之前已完成拼合。  相似文献   

甘孜- 理塘洋可能存在北向俯冲：来自松潘- 甘孜道孚- 炉霍岩浆岩的证据     

卢雨潇  杨经绥  许志琴  连东洋 《地质学报》2022,96(7):2380-2402

松潘- 甘孜造山带巨厚的三叠系复理石沉积盖层给探讨其基底性质、俯冲- 碰撞过程和深部岩浆作用增添了难度，使得带内广泛出露的花岗质岩体和少量镁铁质岩体成为解开松潘- 甘孜造山带构造演化谜团的重要研究对象。锆石U- Pb定年结果表明道孚花岗闪长岩形成于223. 5~217. 4 Ma，炉霍二长岩结晶年龄为219. 4 Ma，辉长岩为218. 9 Ma，均属于晚三叠世岩浆活动的产物。化学成分研究结果表明，花岗质岩石都表现出I型花岗岩特征，其中炉霍二长岩具有较高的Ba、Sr含量，相对较高且均一的εHf(t)值（-3. 69~-1. 65），表明其可能来源于富集玄武质新生下地壳的熔融。道孚花岗闪长岩具有分散的εHf(t)值（-13. 51~0. 41），野外和地球化学特征指示其形成于幔源熔体与古老壳源熔体的混合。辉长岩在微量元素蜘蛛图上具有类似的模式，不同程度富集Ba、Sr、Pb、Th和U元素，出现Nb、Ta、Ti元素亏损，具有岛弧玄武岩的特征，来源于流/熔体交代的地幔楔部分熔融。综合区域已有资料，我们对甘孜- 理塘洋的演化历史提出新的认识，认为甘孜- 理塘洋不仅仅存在向南俯冲的可能性，同时也具有北向俯冲的历史，晚三叠世道孚- 炉霍岩浆岩的形成受控于甘孜- 理塘洋向北边松潘- 甘孜地块俯冲的背景之下。  相似文献   

秦岭南缘勉略带构造属性及晚古生代地质背景:来自碎屑锆石U-Pb年代学的制约     

李小兵  裴先治  李佐臣  李瑞保  裴磊  高峰  王盟 《岩石学报》2021,37(5):1444-1468

勉略构造带作为秦岭造山带内重要的构造边界,关于其构造属性及晚古生代以来的地质背景,一直是学术界争论的焦点。碎屑锆石U-Pb年代学在限定地层单元的最大沉积年龄、研究区域构造岩浆事件及约束构造地质背景等方面行之有效。基于此,通过对勉略带内五郎坪北侧两河口变沉积地层和侵入其中的变形花岗岩脉体进行LA-ICP-MS锆石U-Pb年代学研究。获得2件变形花岗岩脉的结晶年龄均为406±1Ma。碎屑锆石主年龄谱分别为422～456Ma和558～826Ma,峰值年龄为441Ma和771Ma、813Ma,次级年龄谱分别为942～1495Ma和1658～2981Ma,峰值年龄不明显。依据最小一组碎屑锆石的峰值年龄(441Ma),和侵入其中的变形花岗岩脉(406±0.6Ma),限定该变沉积地层形成时代为406～441Ma(S_1-D_1)。碎屑锆石年龄谱显示该套变沉积地层物质来源较为复杂,其中秦岭造山带及扬子板块北缘早古生代、新元古代岩浆岩为其提供了74%±的物源,古老变质基底为其提供了26%±的物源。通过与区域上已有资料对比,认为勉略构造带内晚古生代沉积地层形成环境与邻区大致相同,且本次所获得的变沉积岩碎屑锆石年龄谱也与邻区泥盆系相似。综合认为,勉略构造带与邻区在晚古生代应属同一构造环境,晚古生代"勉略海盆"应当包括整个南秦岭。  相似文献   

Sulfur Isotope Fractionation in Magmatic Systems：Models of Rayleigh Distillation and Selective Flux   总被引：2，自引：0，他引：2  

郑永飞 《中国地球化学学报》1990,9(1):27-45

The effect of Rayleigh distillation by outgassing of SO2 and H2S on the isotopic composition of sulfur remaining in silicate melts is quantitatively modelled.A threshold mole fraction of sulfur in sulfide component of the melts is reckoned to be of critical importance in shifting the δ^34S of the melts mith respect to the original magmas.The partial equilibrium fractionation in a magmatic system is evaluated by assuming that a non-equilibrium flux of sulfur occurs between magmatic volatiles and the melts,while an equilibrium fractionation is approached between sulfate and sulfide within the melts.The results show that under high fo2 conditions,the sulfate/sulfide ratio in a melt entds to increase,and the δ^34S value of sulfur in a solidified rock might then be shifted in the positive direction.This may either be due to Rayleigh outgassing in case the mole fraction of sulfide is less than the threshold,or due to a unidirectional increase in δ^34S value of the sulfate with decreaing temperature,Conversely,at low fo2,the sulfate/sulfide ratio tends to decrease and the δ^34S value of total sulfur could be driven in the negative direction,either because of the Rayleigh outgassing in case the mole fraction of sulfide is greater than the threshold,or because of a unidirectional decrease inδ^34S value of the sulfide.To establish isotopic equilibrium between sulfate and sulfide,the HM,QFM or WM buffers in the magmatic system are suggested to provide the redox couple that could simultaneously reduce the sulfate and oxidize the sulfide.CaO present in the silicatte Melts is also called upon to participate in the chemical equilibrium between sulfate and sulfide,Consequently,the δ^34S value of an igneous rock could considerably deviate from that of its original magma due to the influence of oxygen fugacity and temperature at the time of magma solidification.  相似文献   

辽宁太古代红透山铜矿的稳定同位素地球化学特征及矿床成因     

侯可军  李延河  万德芳 《矿床地质》2006,25(Z2):167-170

文章分析了辽宁太古代红透山铜矿中硫化物的多硫同位素组成和石英的硅氧同位素组成。δ³⁴S在-0.7‰~+3.1‰，极差为3.8‰，平均值为0.21‰，与深部幔源硫相似。δ³³S≈0.52δ³⁴S，即δ³³S=0(δ³³S =δ³³S-1000[(1+ δ³⁴S/1000)0.515-1]，不具有硫同位素非质量分馏效应，表明该矿床中的硫没有经历大气循环过程。矿石中石英的δ30Si分布在-0.8‰~+0.4‰之间，δ¹⁸O分布在+8.5‰~+9.5‰之间，与海底黑烟囱及热水喷气成因硅质岩的硅氧同位素组成相似。提出红透山铜矿为海底热液喷气沉积变质成因。  相似文献   

芙蓉锡矿床及骑田岭A型花岗岩Pb同位素来源示踪     

李晓敏  胡瑞忠  毕献武  彭建堂 《矿床地质》2006,25(Z3):353-254

芙蓉超大型锡矿床与骑田岭A型花岗岩在成因上密切相关。研究表明，该矿床中几种矿石矿物的Pb同位素特征为正常铅，且具有同源性，与“南岭燕山期锡矿床”Pb同位素特征吻合。骑田岭岩体不同单元花岗岩的长石铅和全岩铅亦为正常铅，其特征与“南岭省含锡花岗岩”长石铅同位素特征相似。矿石铅和长石铅主要来源为上地壳，混有少量的下地壳和地幔源铅，且两者间也具有同源性。  相似文献   

同位素地球化学、岩石地球化学——密坑山锡矿同位素年代学研究的启示     

邱检生  蒋少涌胡建 McInnes B I A 凌洪飞 《云南地质》2006,25(4):436-437

密坑山锡矿田位于江西省会昌县西南约40km处。该区为一晚中生代破火山，火山岩为上侏罗统鸡笼嶂组流纹质凝灰熔岩及火山碎屑岩，火山口周围环状及放射状断裂发育，火山口中心为浅成相的密坑山似斑状钾长花岗岩中央岩株侵入体所充填。上世纪80年代以来，在该岩体与流纹质凝灰熔岩的内外接触带相继发现了岩背、淘锡坝、苦竹岽、矿背、上湾等一批大、中型锡多金属矿床或矿点，表明这一岩体对成矿具有重要的制约作用。  相似文献   

High-resolution sedimentary record of lead in the coastal mud of the East China Sea in the past one hundred and fifty years     

Yunchao HAO Zhigang GUO Dejiang FAN 《中国地球化学学报》2006,25(B08):13-13

In the East China Sea （ECS）, there are some mud areas, including the south coastal mud area, the north coastal mud area, and the mud area to the southwest of Cheju Island. X-ray fluorescence （XRF） techniques and Thermal Ionization Mass Spectrometry （TIMS） were used to study the high-resolution sedimentary record of Pb concentrations and Pb stable isotopic compositions in the past one hundred and fifty years in the coastal mud of the ECS. Pb concentrations of a ^210Pb dating S5 core in the study area have increased rapidly since 1980, and reached the maximal value with 65.08 μg/g in 2000, corresponding to the fast economic development of China since the implementation of the ＂Reform and Open Policy＂ in 1978; ^206Pb/^207Pb ratios generally had stabilized at 1.195 from 1860 to 1966, and decreased gradually from 1966 to 2000, indicating that the anthropogenic source Pb contribution to the ECS has increased gradually since 1966, especially since 1980. Pb concentrations decreased distinctly from 2000 to 2003 and ^206Pb/^207Pb ratios increased from 2001 to 2003, corresponding closely to the ban of lead gasoline from 2000 in China. From 1950 to 2003, there occurred four distinct decrease events of ^206Pb/^207Pb, possibly responding to the Changjiang River （Yangtze River） catastrophic floods in 1998, 1991, 1981 and 1954; from 1860 to 1966, there were two decrease periods of ^206Pb/^207Pb, which may respond to the catastrophic floods of Changjiang River in 1931 and 1935, and 1870. As a result of the erosion and drowning by the catastrophic floods, the anthropogenic lead accumulated in soil and water environments over a long period of time was brought into the Changjiang River, then part of them was finally transported into the ECS, which leads to changes in Pb stable isotopic composition.  相似文献   

Boron isotopic geochemistry of karst groundwater in Guiyang City, China     

Wei ZHANG Congqiang LIU Zhiqi ZHAO 《中国地球化学学报》2006,25(B08):172-172

Boron has two stable isotopes （^10B and ^11B） with relative abundances of about 20% and 80%, respectively. Boron isotopic ratios in natural materials show a huge range of variations, from -70‰ to ＋60‰, when expressed with the classical δ^11B notation. Most of these isotopic variations occur at the surface of the Earth. Hence, boron isotopic composition can be used as a sensitive tracer in geochemical study, for instance, to identify the different sources of contamination and factors controlling the salinity of groundwater. During the last decade, boron isotopes have been used to discriminate between the influences of seawater intrusion and anthropogenic discharge. But few of those researches can precisely identify the different sources of contamination. We measured the boron concentrations and boron isotopic ratios of groundwater samples collected in Guiyang City, as well as the major ions. The results indicate that the major ion composition of the groundwater in the investigated area is mainly controlled by the interactions between water and the dominant rock i.e. carbonates. All the water compositions are characterized by high concentrations of Ca^2＋, Mg^2＋, HCO3^-, SO4^2-, and NO3^-, which are the dominant contaminants. Both dissolved boron concentrations and isotopic ratios show large variations among the ground waters, from 2 μg/L to 90 μg/L and from -6‰ to ＋26‰, respectively. The boron concentrations and isotopic ratios indicate that the river across the studied city has been seriously contaminated by urban discharge. Boron concentrations of fiver water samples varied from 20 μg/L to 140 μg/L, with an average δ^11B value of ＋2.0‰. Using boron isotopic compositions and different geochemical indices allowed us to clearly identify and distinguish the two major sources of contamination, agricultural activity and urban wastewater. Both of the two sources are characterized by high boron concentrations but their boron isotopic compositions significantly differ.  相似文献