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31.
柱撑蒙脱石制备与表征 总被引:47,自引:2,他引:47
本文采用多种方法制备keggin离子,并探索出制备稳定keggin离子的适宜酸碱度,用此柱化剂制备出层间距为2.4~2.5nm的柱撑蒙脱石。应用X射线走向衍射技术、红外光谱、差热分析对往撑蒙脱石进行表征,用BET、吡啶吸附考察了其表面物理化学性质。结果表明,用Keggin离子制备出的柱撑蒙脱石其层间距在自然状态下为2.4~2.5nm,350C灼烧,层间距稳℃定在1.8nm,且具有耐热性能好、较大的比表面积和较强的Lewis酸位中心等特点. 相似文献
32.
矿物流体包裹体中的羧酸曾贻善刘家齐(北京大学地质系,北京100871)(地矿部宜昌地质矿产研究所,宜昌443003)关键词矿物包裹体浸取液羧酸离子色谱分析分子中含有羧基官能团(—COOH)的物质称为羧酸。Fein[1]和Shock[2]曾概述羧酸在自... 相似文献
33.
34.
黄铁矿型结构的晶体化学 总被引:2,自引:0,他引:2
本文根据特征离子坐标变化的特点,对黄铁矿型结构微变规律性进行了讨论,作了一些规律图,总结出:成分的变化控制着u值的变化,u值的变化影响着晶体结构微变化。u值发生变化,MX6反三方柱的顶面和底面中3轴相向或相背移动,u值增加愈接近正八面体,u值发生变化,X(M3X)三方锥底面的方位不变,但锥顶(X7)和锥体内的(X1)的坐标要变化,它们会沿着锥的中轴线相向或相背移动,形成扁平型的三方锥,最后得出:当 相似文献
35.
万红 《华北地质矿产杂志》1996,11(2):267-272
在实验条件下,选择几种有代表性的无机离子,并保持一定的浓度和PH值,研究了各无机离子烷化剂对DNATm值的影响。结果表明,有益元素与有害元素对DNATm值高低的影响明显不同。 相似文献
36.
在分散度不同的区域内进行区域采样用于水中硫酸根离子的测定,结果令人满意。应用此方法测定硫酸根离子的线性范围为200.0~3000mg/L;进样频率为120次/h;相对标准偏差为1.70% 相似文献
37.
Yin Xiulan China Institute of Geo-environmental Monitoring Beijing China Hu Ping Faculty of Earth Sciences China University of Geosciences Wuhan China Northeastern Illinois University Chicago IL USA Li Dien Division of Earth Environmental Sciences Los Alamos National Laboratory Los Alamos NM USA 《中国地质大学学报(英文版)》2004,15(4):355-360
The sorption of Eu species onto nano-size silica-water interfaces was investigated using fluorescence spectroscopy for Ph ranges of 1-8.5 and an initial Eu concentration (Ceu) of 2×10-4 M. The sorption rate of Eu was initially low, but significantly increased at Ph>4. The sorption density of Eu species on a silica surface was ~1.58×10-7 mol/m2 when the dissolved Eu species were completely sorbed onto silica-water interfaces at Ph=~5.8. The sorbed Eu species at Ph<6 is aquo Eu3 , which is sorbed onto silica-water interfaces as an outer-sphere complex at Ph<5, but may be sorbed as an inner-sphere bidentate complex at 5相似文献
38.
The identification of marine source rocks in the Tarim Basin is debated vigorously. The intention of this paper is to investigate the asphahenes in heavy oils from the Lunnan and Tabe oilfields and Well TD2 with ruthenium-ions-catalyzed oxidation technique (RICO), in order to explore its role in oil-oil and oil-source correlations, The RICO products included n-alkanoic acids, α,ω-di-n-alkanoic acids, branched alkanoic acids, tricyclic terpanoic acids, hopanoic acids, gammacerane carboxylic acid , regular sterane carboxylic acids and 4-methylsterane carboxylic acids. The n-alkyl chains and biomarkers bounded on the asphaltenes were of unsusceptibility to biodegradation. The distribution and absolute concentrations of n-alkanoic acids in the RICO products of heavy oils from the Lunnan and Tabe oilfields are different from those of Well TD2. The biomarkers bounded on the asphahenes, especially steranes, have a distribution trend similar to that of the counterparts in saturates. The sterane carboxylic acids and 4-methylsterane carboxylic acids in the RICO products of heavy oils from the Lunnan and Tahe oilfields, dominated by C30 sterane and C31 4-methylsterane carboxylic acids, respectively, are significantly different from those of the heavy oils of Well TD2, whose dominating sterane and 4-methylsterane carboxylic acids are C28 sterane and C29 4-methylsterane acids, respectively. The RICO products of the asphaltenes further indicate that the Middle-Upper Ordovician may be the main source rocks for heavy oils from the Lunnan and Tabe oilfields. 相似文献
39.
Water soluble components of PM10 Chongqing, China 总被引:1,自引:0,他引:1
The concentrations of water soluble ions (Na+, NH4
+, K+, Mg2+, Ca2+, NO3
-, Cl-, and SO
4
2-
) in PM10 samples collected on cellulose filters by a medium-volume cascade impactor were determined, which were obtained from three
kinds of areas in Chongqing: industrial area (Jiulongpo district), commercial and residential area (Jiangbei district) and
background area (Jinyun Mountain in the Beibei district). The results showed that except for the background site, the annual
average values of PM10 are 23% – 61% higher than the national air quality standard (GradeII) (0.1 mg/m3), even that the value of the control site is still 20% higher than American standard (0.05 mg/m3). This implied that serious pollution of fine particles occurred in Chongqing. Nine kinds of soluble ions in water of PM10 were analyzed by ion chromatography (IC) and the annual average concentrations follow the order of [SO
4
2-
] > [NO3
-] > [Cl-] > [F-], and [Ca2+] > [NH4
+] > [K+] > [Na+] > [Mg2+]. Their values were different in these areas: the industrial area > the commercial and living area > the control area. As
for NH4
+, K+, Ca2+, NO3
- and SO
4
2-
, their seasonal average concentrations show a similar variation trend: the values in spring and fall were higher than those
in summer and winter. The seasonal average concentrations of [Cl-], [F-], [Na+] and [Mg2+] are much lower than those of other ions. However, the concentrations of [Na+] changed more greatly in different seasons than those of the other three ions. Correlation coefficients showed that the three
areas have been polluted by coal smoke and dust to different extents, while some local resources of pollution should be taken
into consideration as well. 相似文献
40.
不同浓度的Na2SO4水溶液的拉曼光谱显示了SO42-的四个拉曼活性带:980 cm-1处的SO42-的对称伸缩振动模式v1带,1 106 cm-1处的反对称伸缩振动模式v3带,448 cm-1处的变形振动模式v2带和617 cm-1处的变形振动模式v4带。482 cm-1处的肩膀峰是由于NaSO4-离子对的形成对448 cm-1的v2带的影响而形成的SO42-的一个新的振动峰。浓Na2SO4水溶液中,水共享离子对[Na+.H2O.SO42-]-是主要的离子对物种。随着Na2SO4水溶液浓度的增加,Na+和SO42-的相互作用增强,NaSO4-离子对所占的摩尔分数增加。 相似文献