氮气、氧气和空气水合物的合成及其拉曼光谱特征   总被引：1，自引：0，他引：1  

刘昌岭  业渝光  卢海龙 《现代地质》2008,22(3):480-484

在-20℃和不同的压力下,在实验室内分别合成了氮气水合物(16MPa)、氧气水合物(13MPa)和空气水合物(15MPa),并对其N—N和O—O键伸缩振动的拉曼光谱特征进行了研究。结果表明,人工合成的水合物中的N—N和O—O键的拉曼位移与天然的空气水合物中的数据十分接近。在氮气水合物和空气水合物中,N—N键的拉曼峰值均为2322.4cm-1;O—O键的拉曼峰值在氧气水合物和空气水合物保持一致,均为1547.8cm-1。空气水合物分解的拉曼谱图表明,它不是氮气水合物和氧气水合物组成的混合物,而是由氮分子和氧分子共同生成的单一水合物,氮分子和氧分子同时进入水合物的大笼和小笼中。与空气中的氮、氧比例相比,水合物中氧分子明显富集,氮分子和氧分子的比例为2.4∶1。  相似文献   

我国井下水平定向钻进技术研发取得重大进展     

梅新 《煤田地质与勘探》2008,36(3):70

煤矿井下定向钻进技术是实现煤矿现代化生产和高效治理煤矿瓦斯的一项重大关键技术,近年来也一直是国际上关注和积极发展的关键技术。2008年4月初,由煤炭科学研究总院西安研究院承担的国家发改委煤矿瓦斯综合治理与利用关键技术研发和装备研制项目"井下水平长钻孔钻机研制及配套工艺开发",在陕西彬长亭南煤矿一盘区113工作面进行了现场工业性试验,  相似文献   

南京市地下管线非开挖工艺应用规划研究     

陈立川  黄宏亮  涂昌鹏 《岩土钻凿工程》2008,(6):1-4

本文通过对非开挖技术规划、管理方面所暴露出的一些问题进行分析,提出了建立非开挖管理、评价系统的思想。经过分析制定了一系列的评价指标并提出了相关建议。  相似文献   

创新工作机制完善监管体系提升首都城市建设安全质量管理和服务水平(摘选)     

北京建设委员会 《中国勘察设计》2008,(2):26-27,29

近年来,随着首都城市建设的快速发展,全市工程建设规模不断扩大,开复工面积保持在1亿平方米以上。特别是奥运、地铁等重点工程建设工期紧、工艺复杂、技术要求高、管理难度大,对我市安全质量监管工作提出了新的挑战。针对我市建筑业的形势和特点,我们按照建设部和市政府的工作要求,深入贯彻科学发展观,推进体  相似文献   

硫铅酸盐“S”型瞬凝水泥干法护壁堵漏技术研究          下载免费PDF全文

彭振斌 《探矿工程》1995,(2):41-42,60

介绍了硫铝酸盐“Ｓ”型瞬凝水泥干法者漏时使用的配方,阐述了输送工具和扫孔钻具的设计以及灌注工艺技术。  相似文献   

中国大陆自由空气重力场的初步研究   总被引：2，自引：0，他引：2       下载免费PDF全文

魏梦华  王启鸣  史志宏  殷秀华  刘占坡  张玉梅 《地震地质》1981,3(3):47

本文利用地面实测的重力资料计算并构制了从1°×1°到10°×10°平均的中国大陆自由空气重力异常图,并对这套图中所反映出来的基本事实进行了分析和解释,且就这些基本事实与大地构造、地壳均衡、地震活动的关系及其可能的地球动力学过程进行了讨论  相似文献   

Mobility of heavy metals from tailings to stream waters in local zinc smelting activities contaminated site     

Taoze LIU Yuangen YANG Bangyu LIU Xiangyang BI Feili LI 《中国地球化学学报》2006,25(B08):41-42

It has been found that stream waters were severely contaminated with wastes from a long-time smelting factory in Hezhang, Guizhou, China. The main sources of contamination are the smelting wastes stored in the open air and abandoned in the vicinity of stream. A method of lead isotope was adopted in order to identify relations between tailings and water contamination. Representative samples of tailings and stream sediments were collected. Mineralogical characterizations were conducted using XRD and TEM/SEM, while acid digestion was carried out for determining metal contents. BCR sequential leaching tests were performed in order to assess metal mobility. The tremendous ‘actual＇ and ‘potential＇ mobility of heavy metals indicates that the smelting waste and stream sediments present a considerable threat to the environment. Besides the chemical remobilization of heavy metals from the sediments and the reworking of riverbed sediments act as a secondary source of pollution. Also groundwater and stream water were sampled in specific locations and were measured.  相似文献   

Increasing of efficiency of desulphurisation processes of coals during thermal destruction     

Turchanina Oksana Satin Vladimir Derevyanko Aleksey 《中国地球化学学报》2006,25(B08):51-52

As is well known, a high content of sulphur in coals is an effect of the post-depositional history of coal seams and one of the most important criteria of its use as a fuel. Sulphur in coals can cause a serious environmental and technological problem during their utilization. This problem is very actual for the Donetsk Basin because 734 mined seams out of the total of 1009 （73%） are comprised of coals with sulphur content -2%. The chemical pre-treatment as a first stage in their processing is widely used in order to effectively obtain the thermal destruction products of coals （such as semi-coke, coke, adsorbents, etc.） and to simultaneously utilize coal wastes. Development in pre-treatment methods for high-sulphur, low-rank coals is especially desirable for reducing the sulphur contents of the solid products. The aim of the present work is to investigate the influence of coal pre-treatment on the yield and composition of thermal destruction products, and the sulphur distribution among different components of the coals of different genetic types by reductivity （low-reduced LRC and reduced RC coals）. The thermal behavior of the coals was studied by means of the Fisher method （heated to 520℃, at a rate of 7℃/min）. The composition of the semi-coking gas was investigated by means of a VTI gas analyzer. The coal samples were chemically treated directly before thermal destruction by the introduction of 1-% solutions of radical polymerization initiator AAD （acrylic acid dinitrile C8H12N4） and products of coal-tar distillation （absorber oil）. Coal pre-treatment increases the semi-coke yield and its coking ability, and changes the liquid/gaseous product ratio.  相似文献   

空气潜孔锤与气举反循环钻进组合工艺在水文水井钻探中的应用          下载免费PDF全文

赵鸿杰  孙智杰 《探矿工程》2006,33(11):52-53

阐述了空气潜孔锤与气举反循环钻进组合工艺的技术特点和施工特点，通过两口水井施工实例充分展现了其在施工效率、成井质量、洗井效果、市场竞争等方面的优越性。  相似文献   

山东淄博煤矿大口径超深基岩排水孔钻井技术          下载免费PDF全文

赵光贞  刘玉仙  李海波 《探矿工程》2006,33(8):53-54

由于第四系、二叠系、石炭系岩性复杂及缩径、坍塌、漏失等情况，山东淄博煤矿大口径超深定向排水孔成井难度大。该井采用了水泥注浆堵漏和水泥造壁稳定孔壁，应用“气举反循环＋垂钻”钻进工艺方法控制钻孔顶角，应用阶梯式组合牙轮钻头、水泥固井止水等技术方法，达到了设计要求。  相似文献