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31.
Curtis M. Oldenburg 《Environmental Geology》2008,54(8):1687-1694
A screening and ranking framework (SRF) has been developed to evaluate potential geologic carbon dioxide (CO2) storage sites on the basis of health, safety, and environmental (HSE) risk arising from CO2 leakage. The approach is based on the assumption that CO2 leakage risk is dependent on three basic characteristics of a geologic CO2 storage site: (1) the potential for primary containment by the target formation; (2) the potential for secondary containment
if the primary formation leaks; and (3) the potential for attenuation and dispersion of leaking CO2 if the primary formation leaks and secondary containment fails. The framework is implemented in a spreadsheet in which users
enter numerical scores representing expert opinions or published information along with estimates of uncertainty. Applications
to three sites in California demonstrate the approach. Refinements and extensions are possible through the use of more detailed
data or model results in place of property proxies. 相似文献
32.
Laura Chiaramonte Mark D. Zoback Julio Friedmann Vicki Stamp 《Environmental Geology》2008,54(8):1667-1675
This paper reports a preliminary investigation of CO2 sequestration and seal integrity at Teapot Dome oil field, Wyoming, USA, with the objective of predicting the potential risk
of CO2 leakage along reservoir-bounding faults. CO2 injection into reservoirs creates anomalously high pore pressure at the top of the reservoir that could potentially hydraulically
fracture the caprock or trigger slip on reservoir-bounding faults. The Tensleep Formation, a Pennsylvanian age eolian sandstone
is evaluated as the target horizon for a pilot CO2 EOR-carbon storage experiment, in a three-way closure trap against a bounding fault, termed the S1 fault. A preliminary geomechanical
model of the Tensleep Formation has been developed to evaluate the potential for CO2 injection inducing slip on the S1 fault and thus threatening seal integrity. Uncertainties in the stress tensor and fault
geometry have been incorporated into the analysis using Monte Carlo simulation. The authors find that even the most pessimistic
risk scenario would require ∼10 MPa of excess pressure to cause the S1 fault to reactivate and provide a potential leakage
pathway. This would correspond to a CO2 column height of ∼1,500 m, whereas the structural closure of the Tensleep Formation in the pilot injection area does not exceed
100 m. It is therefore apparent that CO2 injection is not likely to compromise the S1 fault stability. Better constraint of the least principal stress is needed to
establish a more reliable estimate of the maximum reservoir pressure required to hydrofracture the caprock. 相似文献
33.
Wenjun Yong E. Dachs A. C. Withers E. J. Essene 《Contributions to Mineralogy and Petrology》2008,155(2):137-146
The low-temperature heat capacity (C
p) of Si-wadeite (K2Si4O9) synthesized with a piston cylinder device was measured over the range of 5–303 K using the heat capacity option of a physical
properties measurement system. The entropy of Si-wadeite at standard temperature and pressure calculated from the measured
heat capacity data is 253.8 ± 0.6 J mol−1 K−1, which is considerably larger than some of the previous estimated values. The calculated phase transition boundaries in the
system K2O–Al2O3–SiO2 are generally consistent with previous experimental results. Together with our calculated phase boundaries, seven multi-anvil
experiments at 1,400 K and 6.0–7.7 GPa suggest that no equilibrium stability field of kalsilite + coesite intervenes between
the stability field of sanidine and that of coesite + kyanite + Si-wadeite, in contrast to previous predictions. First-order
approximations were undertaken to calculate the phase diagram in the system K2Si4O9 at lower pressure and temperature. Large discrepancies were shown between the calculated diagram compared with previously
published versions, suggesting that further experimental or/and calorimetric work is needed to better constrain the low-pressure
phase relations of the K2Si4O9 polymorphs.
Electronic supplementary material The online version of this article (doi:) contains supplementary material, which is available to authorized users. 相似文献
34.
H2O-undersaturated melting experiments of synthesized basalt (SiO2 = 50.7 wt.%, MgO = 8.3 wt.%, Mg# = 60) were conducted at fO2 corresponding to NNO+1 and NNO−1 to clarify the effects of pressure (2–7 kbar) and H2O on fractional crystallization in island arcs. H2O content was ranged from nominally anhydrous to 4.4 wt.%. Differentiation trends, namely the liquid lines of descent, change
sensitively according to pressure-H2O relations. Tholeiitic differentiation trends are reproduced with H2O ≤ ∼2 wt.% in primary magma. With such quantities of H2O, fractional crystallization is controlled by olivine + plagioclase at 2 kbar. Increasing the pressure from 2 to ≥4 kbar
induces early crystallization of orthopyroxene instead of olivine and therefore SiO2 enrichment in the residual melts is suppressed. Increasing H2O (≥ ∼2 wt.% in primary magma) stabilizes clinopyroxene relative to orthopyroxene and/or magnetite. Although the phase relations
and proportions strongly depend on fO2 and H2O content, differentiation trends are always calc-alkaline. 相似文献
35.
Origin of Fe-Ti Oxide Ores in Mafic Intrusions: Evidence from the Panzhihua Intrusion, SW China 总被引:12,自引:0,他引:12
Pang Kwan-Nang; Zhou Mei-Fu; Lindsley Donald; Zhao Donggao; Malpas John 《Journal of Petrology》2008,49(2):295-313
Economic concentrations of Fe–Ti oxides occur as massive,conformable lenses or layers in the lower part of the Panzhihuaintrusion, Emeishan Large Igneous Province, SW China. Mineralchemistry, textures and QUILF equilibria indicate that oxidesin rocks of the intrusion were subjected to extensive subsolidusre-equilibration and exsolution. The primary oxide, reconstructedfrom compositions of titanomagnetite in the ores and associatedintergrowths, is an aluminous titanomagnetite (Usp40) with 40wt % FeO, 34 wt % Fe2O3, 16·5 wt % TiO2, 5·3 wt% Al2O3, 3·5 wt % MgO and 0·5 wt % MnO. This compositionis similar to the bulk composition of the oxide ore, as inferredfrom whole-rock data. This similarity strongly suggests thatthe ores formed from accumulation of titanomagnetite crystals,not from immiscible oxide melt as proposed in earlier studies.The occurrence of oxide ores in the lower parts of the Panzhihuaintrusion is best explained by settling and sorting of densetitanomagnetite in the ferrogabbroic parental magma. This magmamust have crystallized Fe–Ti oxides relatively early andabundantly, and is likely to have been enriched in Fe and Tibut poor in SiO2. These features are consistent with fractionationof mantle-derived melts under relatively high pressures (10kbar), followed by emplacement of the residual magma at 5 kbar.This study provides definitive field and geochemical evidencethat Fe–Ti oxide ores can form by accumulation in ferrogabbro.We suggest that many other massive Fe–Ti oxide depositsmay have formed in a similar fashion and that high concentrationsof phosphorus or carbon, or periodic fluctuation of fO2 in themagma, are of secondary importance in ore formation. KEY WORDS: ELIP; Fe–Ti oxide ore; layered intrusion; Panzhihua; QUILF 相似文献
36.
Serena C. Tarantino Michele Zema Tiziana Boffa Ballaran Paolo Ghigna 《Physics and Chemistry of Minerals》2008,35(2):71-76
High-pressure single-crystal X-ray diffraction measurements of lattice parameters of the compound Li2VOSiO4, which crystallises with a natisite-type structure, has been carried out to a pressure of 8.54(5) GPa at room temperature.
Unit-cell volume data were fitted with a second-order Birch-Murnaghan EoS (BM-EoS), simultaneously refining V
0 and K
0 using the data weighted by the uncertainties in V. The bulk modulus is K
0 = 99(1) GPa, with K′ fixed to 4. Refinements of third order equations-of-state yielded values of K′ that did not differ significantly from 4. The compressibility of the unit-cell is strongly anisotropic with the c axis (K
0(c) = 49.7 ± 0.5 GPa) approximately four times more compressible than the a axis (K
0(a) = 195 ± 3 GPa). 相似文献
37.
CO2地质埋存渗漏风险及补救对策 总被引:7,自引:1,他引:6
目前,将CO2埋存于地下深部地质构造(如油气藏、煤层、地下含水层及岩溶盐腔)的减排方案能有效地减缓温室效应而备受关注。无论什么储集体,我们都希望CO2在地下埋存的时间越长越好。然而,对于一项具体工程的实施,必然存在一些客观和主观因素造成CO2渗漏,比如废弃井的不完善或不合理处理、地层断裂系统和水动力系统以及地震所造成的渗漏等等。存在渗漏就可能会对周围人和生态环境造成危害。因此,进行CO2地质埋存的风险评估是相当有必要的,是我们能长期有效安全地进行该项减排方案必不可少的基础和保证。本文即想从建立一套完整的风险评估、管理和监测体系的角度并以加拿大Weyburn油田为例,深入分析CO2地质埋存中可能存在的渗漏风险和途径,建立CO2渗漏风险评估机制,并针对具体的渗漏可能性提出相应的补救对策,为全球范围内,尤其对我国刚刚开展CO2地质埋存研究工作提供一些有益的思路。 相似文献
38.
桃山铀矿田桃山断裂及其保矿作用 总被引:2,自引:0,他引:2
桃山铀矿田位于江西省中部,断裂构造发育,既有成矿构造,也有保矿构造,其中斜贯桃山矿田的桃山断裂即是一保矿构造,它形成于车免近时期,走向北东,倾向南东,右行正断,并具铰链断层性质,上盘地块掀斜下落,致使上盘成矿壳层向NW和NE倾斜,由于倾末端的侵蚀深度较小,保矿条件较好,加强这些地带的铀矿勘查和评价具有重要意义。 相似文献
39.
位于辽东湾西部低凸起北端的JZ20-2超压凝析气田,离供烃中心较远,压力系数却达到1.56~1.7,这在我国东部裂谷盆地比较少见。经过综合分析,作者认为JZ20-2凝析气田异常高压的形成与其所处的特殊地质背景紧密相关,辽中凹陷沙河街组三段超压凝析油气沿不整合面、砂体输导通道向辽东湾西部低凸起的运移、充注和能量的侧向传递是JZ20-2凝析气田异常高压形成的根本原因,而上覆东营组二段下亚段-东营组三段巨厚的强超压泥岩封盖和辽西3号边界断层侧向遮挡共同构成的优越封闭环境是超压保存的必要条件。本文分析了该气田超压特征及其远距离超压侧向传递的成因机制,不仅有助于揭示辽东湾西部低凸起超压流体运移聚集的规律和成藏作用,而且可能提供了一个超压远距离侧向传递的典型实例。 相似文献
40.
河南省洛宁县寨凹钼矿床流体包裹体研究及矿床成因 总被引:10,自引:0,他引:10
寨凹钼矿床位于华北克拉通南缘的熊耳地体.矿床定位受马超营断裂带的次级断裂控制,矿体呈脉状贼存于太华超群石板沟组黑云角闪斜长片麻岩中。成矿过程包括3个阶段:石英-辉钼矿阶段(I)、石英-多金属硫化物阶段(Ⅱ)、石英-碳酸盐阶段(Ⅲ),其中,I阶段为主成矿阶段。寨凹钼矿床可见2类流体包裹体,即水溶液型和含子晶包裹体;激光拉曼指示包裹体成分主要为H2O。从早到晚,流体包裹体均一温度从I阶段100~260℃,经Ⅱ阶段110~160℃.变化为Ⅲ阶段120—180℃.矿床总体属于低温热液矿床:流体包裹体盐度从I阶段的2~25wt%NaCl.eqv演化至Ⅱ阶段的6—30wt%NaCl.eqv.然后降为Ⅲ阶段的7~25wt%NaCl.eqv。I阶段均一温度范围宽广、流体包裹体盐度由双峰式演化为单峰式以及包裹体温度-盐度双变图的负相关性指示了流体混合是主要的成矿机制。寨凹钼矿流体包裹体以高密度、高盐度的低温低压流体为特征,是含CaCl,流体参与成矿的结果,热的岩浆流体与冷的含CaCl,的卤水的混合.导致了辉钼矿的沉淀。寨凹钼矿床地质和流体包裹体特征与侵入岩相关的成矿系统一致.指示其成因类型为与侵入岩有关的钼矿床. 相似文献