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21.
A palaeotemperature reconstruction based on periglacial phenomena in Europe north of approximately 51 °N, is compared with high‐resolution regional climate model simulations of the marine oxygen isotope Stage 3 (Stage 3) palaeoclimate. The experiments represent Stage 3 warm (interstadial), Stage 3 cold (stadial) and Last Glacial Maximum climatic conditions. The palaeotemperature reconstruction deviates considerably for the Stage 3 cold climate experiments, with mismatches up to 11 °C for the mean annual air temperature and up to 15 °C for the winter temperature. However, in this reconstruction various factors linking climate and permafrost have not been taken into account. In particular a relatively thin snow cover and high climatic variability of the glacial climate could have influenced temperature limits for ice‐wedge growth. Based on modelling the 0 °C mean annual ground temperature proves to be an appropriate upper temperature limit. Using this limit, mismatches with the Stage 3 cold climate experiments have been reduced but still remain. We therefore assume that the Stage 3 ice wedges were generated during short (decadal time‐scale) intervals of extreme cold climate, below the mean temperatures indicated by the Stage 3 cold climate model simulations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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Summary. An assessment is made of the bias of fitting constrained layered-earth models to transient electromagnetic data obtained over 3-D structures. In this assessment we use the central-loop configuration and show that accurate estimates of the depth of burial of 3-D structures can be obtained with layered-earth model fitting. However, layered-earth interpretations are not reliable for estimating depth extents and resistivities of 3-D structures. When layered earths are used for interpretation, it is advantageous in some cases to use data based on the magnetic field instead of the voltage. A magnetic-field definition of apparent resistivity, in contrast to a definition based on the voltage, eliminates apparent-resistivity overshoots and undershoots in the data. A resistivity undershoot in the data can produce an extraneous and misleading layer in an interpretation of a 3-D resistive structure. Due to 3-D effects, apparent-resistivity soundings (magnetic field and voltage) may rise so steeply at late times that it may not be possible to fit a sounding to a reasonable layered-earth model. Truncating such a sounding, over a buried conductor, allows for a reasonable layered-earth fit and an accurate estimate of the depth to the conductor. However, the resistivity of the conductor is overestimated.
Measurements of the horizontal field in the central-loop configuration can map 3-D structures, provided the sensor is located accurately at the centre of the transmitting loop. Horizontal-field calculations show that the transients peak on the flanks of a 3-D structure, but are depressed over the structure's centre. Weak transient responses flanked by two large transient responses, which are opposite in sign, locate the structure. The sign reversal is caused by a corresponding reversal in the currents that are channelled through or deflected away from conductive or resistive structures, respectively.  相似文献   
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Stable oxygen isotope analysis and measurement of several dissolved cations and anions of bulk meltwater samples have provided information about the hydrochemical environment of the glacial hydrological system at Imersuaq Glacier, an outlet tongue from the Greenland ice‐sheet, West Greenland. The samples were collected at frequent intervals during the period 20–28 July 2000 in a small (<20 L s?1) englacial meltwater outlet at the glacier margin. The results document the following findings: (i) a marked diurnal variation of δ18O is related to the composition of oxygen isotope provenances, mainly near‐marginal local superimposed ice and basal up‐sheared ice further up‐glacier; (ii) a relationship is seen between all base cations (Na+, K+, Ca2+, Mg2+), SO42? and δ18O, indicating that solute acquisition is provided by solid–solution contact with the up‐sheared ice—as the relationship with Cl? is weak the influence of seasalt‐derived solutes is small in the area; (iii) when the melt rate is high, two diurnal maxima of δ18O values and solute concentrations are measured, and it is suggested that a snow meltwater component is responsible for the second maximum of δ18O—a short residence time leads to a delayed decrease in ion concentrations. Copyright © 2003 John Wiley & Sons, Ltd.  相似文献   
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Development of a 3D GIS and its application to karst areas   总被引:1,自引:0,他引:1  
There is a growing interest in modeling and analyzing karst phenomena in three dimensions. This paper integrates geology, groundwater hydrology, geographic information system (GIS), database management system (DBMS), visualization and data mining to study karst features in Huaibei, China. The 3D geo-objects retrieved from the karst area are analyzed and mapped into different abstract levels. The spatial relationships among the objects are constructed by a dual-linker. The shapes of the 3D objects and the topological models with attributes are stored and maintained in the DBMS. Spatial analysis was then used to integrate the data in the DBMS and the 3D model to form a virtual reality (VR) to provide analytical functions such as distribution analysis, correlation query, and probability assessment. The research successfully implements 3D modeling and analyses in the karst area, and meanwhile provides an efficient tool for government policy-makers to set out restrictions on water resource development in the area.  相似文献   
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This paper presents an example of application of the double solid reactant method (DSRM) of Accornero and Marini (Environmental Geology, 2007a), an effective way for modeling the fate of several dissolved trace elements during water–rock interaction. The EQ3/6 software package was used for simulating the irreversible water–rock mass transfer accompanying the generation of the groundwaters of the Porto Plain shallow aquifer, starting from a degassed diluted crateric steam condensate. Reaction path modeling was performed in reaction progress mode and under closed-system conditions. The simulations assumed: (1) bulk dissolution (i.e., without any constraint on the kinetics of dissolution/precipitation reactions) of a single solid phase, a leucite-latitic glass, and (2) precipitation of amorphous silica, barite, alunite, jarosite, anhydrite, kaolinite, a solid mixture of smectites, fluorite, a solid mixture of hydroxides, illite-K, a solid mixture of saponites, a solid mixture of trigonal carbonates and a solid mixture of orthorhombic carbonates. Analytical concentrations of major chemical elements and several trace elements (Cr, Mn, Fe, Ni, Cu, Zn, As, Sr and Ba) in groundwaters were satisfactorily reproduced. In addition to these simulations, similar runs for a rhyolite, a latite and a trachyte permitted to calculate major oxide contents for the authigenic paragenesis which are comparable, to a first approximation, with the corresponding data measured for local altered rocks belonging to the silicic, advanced argillic and intermediate argillic alteration facies. The important role played by both the solid mixture of trigonal carbonates as sequestrator of Mn, Zn, Cu and Ni and the solid mixture of orthorhombic carbonates as scavenger of Sr and Ba is emphasized.
Luigi Marini (Corresponding author)Email:
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The EPR spectra of Maxixe-type beryl contain a large number of overlapping signals. The angular dependence of the 1:3:3:1 signal typical for the CH3 radical shows that this radical is located at the center of the channel cavity with its symmetry axis parallel to the crystal c-axis and is rotating around this axis. Its EPR spectrum is axially symmetric with g // = 2.00263, g  = 2.00249 and A// = 2.288 mT, A = 2.256 mT. These anisotropies have the opposite signs of those found for surface-adsorbed methyl radicals. Hydrogen atoms are located at position 2a at the center of the beryl cavity and the EPR parameters of the narrow doublet signal are A 0 = 1,407 MHz and g = 2.00230. Another doublet signal, which is broader and has axial symmetry with g // = 2.00265, g  = 2.00625 and A// = 0.895 mT, A = 0.885 mT, could come from a HCO3 radical. One narrow and easily saturated signal with g // = 2.00227 and g  = 2.00386 is interpreted to arise from a carbon monoxide radical in the beryl channel, oriented with its axis parallel to the crystal c-axis. Additional weak doublet lines, which have similar g values as the carbon monoxide radical, are created by nearby hydrogens. A powder spectrum with g // = 2.0017 and g  = 2.0004 appears upon UV irradiation of the single crystal and is easily saturated. This spectrum is interpreted to arise from a carbon dioxide radical, which rotates around its symmetry axis.  相似文献   
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