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The kinetics of the reactions of C2H radical with ethane (k1), propane (k2), and n-butane (k3) are studied over the temperature range of T = 96-296 K with a pulsed Laval nozzle apparatus that utilizes a pulsed laser photolysis-chemiluminescence technique. The C2H decay profiles in the presence of both the alkane reactant and O2 are monitored by the CH(A2Δ) chemiluminescence tracer method. The results, together with available literature data, yield the following Arrhenius expressions: k1(T) = (0.51 ± 0.06) × 10−10 exp[(−76 ± 30)K/T] cm3 molecule−1 s−1 (T = 96-800 K), k2(T) = (0.98 ± 0.32) × 10−10exp[(−71 ± 60)K/T] cm3 molecule−1 s−1 (T = 96-361 K), and k3(T) = (1.23 ± 0.26) × 10−10 cm3 molecule−1 s−1 (T = 96-297 K). At T = 296 K, k1 is measured as a function of total pressure and has little or no pressure dependence. The results from this work support a direct hydrogen abstraction mechanism for the title reactions. Implications to the atmospheric chemistry of Titan are discussed.  相似文献   
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Paul Withers  S.W Bougher 《Icarus》2003,164(1):14-32
Mars Global Surveyor accelerometer observations of the martian upper atmosphere revealed large variations in density with longitude during northern hemisphere spring at altitudes of 130-160 km, all latitudes, and mid-afternoon local solar times (LSTs). This zonal structure is due to tides from the surface. The zonal structure is stable on timescales of weeks, decays with increasing altitude above 130 km, and is dominated by wave-3 (average amplitude 22% of mean density) and wave-2 (18%) harmonics. The phases of these harmonics are constant with both altitude and latitude, though their amplitudes change significantly with latitude. Near the South Pole, the phase of the wave-2 harmonic changes by 90° with a change of half a martian solar day while the wave-3 phase stays constant, suggesting diurnal and semidiurnal behaviour, respectively. We use a simple application of classical tidal theory to identify the dominant tidal modes and obtain results consistent with those of General Circulation Models. Our method is less rigorous, but simpler, than the General Circulation Models and hence complements them. Topography has a strong influence on the zonal structure.  相似文献   
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With the rapid development of space technology, earth observation technology and sky observatory technolo-gy, they have played a more and more important part in monitoring and predicting of earthquakes and volcanoes in the terres-trial land. In recent years, the related agencies have done the experiments and researches on monitoring and predicting ofearthquakes and volcanoes in the forewarning period by means of many approaches, such as satellite thermal infrared re-mote sensing (TIRS), Global Positioning System (GPS), differential interferometric synthesis aperture radar (D-INSAR),astronomical time-latitude residual anomaly, and Geographic Information Systems (GIS), etc. A quite large number of re-search foundation has been built in the fundamental theories and application methods. The experiments and researcheshave shown that these technology is efficient methods for high frequency crust movement. If the existed separate scientificforces and results are possibly assembled together to form a more complete integration monitoring system with the combina-tion of space, sky observation, ground, deep geology and macro anomaly, it will come into a new stage of monitoring andpredicting of earthquakes and volcanic eruptions.  相似文献   
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We have investigated with BeppoSAX the long term behaviour of the harder X-ray component of the supposed supermassive binary system η Car along its 5.52 year cycle. We have found that in March 1998 during egress from the last December 1997 eclipse, this component was the same as outside eclipse, but for a large (×3.5) increase of NH h , that can be attributed to the presence or formation of opaque matter in front of the source near periastron. Unexpectedly, at that time the iron 6.7 keV emission line was 40% stronger. BeppoSAX has for the first time found ahard X-ray tail extending to at least 50 keV, that cannot be adequately fitted with an additional hotter thermal component. The 2–100 keV spectrum of η Car is instead well fitted with an absorbed powerlaw spectrum with photon index 2.53, suggesting non-thermal emission as an alternative model for the core source.  相似文献   
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