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61.
A multi-layer deposited ice film was prepared through water vapor deposition on a Ni plate in a vacuum chamber at 90 K, and was used as it was or after annealing at 140 K. NO2 was adsorbed as N2O4 approximately 90 K on the ice film prepared as above, and irradiated by 193 nm excimer laser light. The time-of-flight (TOF) spectra of the desorbed species, i.e., NO2, NO, O2 and O, were measured by a quadrupole mass spectrometer. The photochemical process obeyed an one-photon process. The relative yields of the products and their TOF spectra were dependent on the preparation condition of the ice film and also varied with the continuation of the laser irradiation. From the ice film annealed at 140 K, NO2, NO and O2 were desorbed with an approximate ratio of 1:1:0.01. From the non-annealed film, the relative yield of NO2 was much smaller than that of NO. The TOF spectrum of NO from the non-annealed ice film consisted of distinctly different two components corresponding to the 1700 and 100 K translational temperature, respectively. The fast component was lost when additional ice was deposited on the adsorbed N2O4. NO was supposed to be a predissociation product from the electronically excited NO2 prepared through the photodissociation of N2O4. 相似文献
62.
Rate constants for the gas-phase reactions of OH radicals, NO3 radicals and O3 with the C7-carbonyl compounds 4-methylenehex-5-enal [CH2=CHC(=CH2)CH2CH2CHO], (3Z)- and (3E)-4-methylhexa-3,5-dienal [CH2=CHC(CH3)=CHCH2CHO] and 4-methylcyclohex-3-en-1-one, which are products of the atmospheric degradations of myrcene, Z- and E-ocimene and terpinolene, respectively, have been measured at 296 ± 2 K and atmospheric pressure of air using relative rate methods. The rate constants obtained (in cm3 molecule–1 s–1 units) were: for 4-methylenehex-5-enal, (1.55 ± 0.15) × 10–10, (4.75 ± 0.35) × 10–13 and (1.46 ± 0.12) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; for (3Z)-4-methylhexa-3,5-dienal: (1.61 ± 0.35) × 10–10, (2.17 ± 0.30) × 10–12, and (4.13 ± 0.81) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; for (3E)-4-methylhexa-3,5-dienal: (2.52 ± 0.65) × 10–10, (1.75 ± 0.27) × 10–12, and (5.36 ± 0.28) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively; and for 4-methylcyclohex-3-en-1-one: (1.10 ± 0.19) × 10–10, (1.81 ± 0.35) × 10–12, and (6.98 ± 0.40) × 10–17 for the OH radical, NO3 radical and O3 reactions, respectively. These carbonyl compounds are all reactive in the troposphere, with daytime reaction with the OH radical and nighttime reaction with the NO3 radical being predicted to dominate as loss processes and with estimated lifetimes of about an hour or less. 相似文献
63.
Norbert Schwarzenbeck Ron Erley Belinda S. Mc Swain Peter A. Wilderer Robert L. Irvine 《洁净——土壤、空气、水》2004,32(1):16-24
Aerobic granular sludge was successfully cultivated in a sequencing batch reactor (SBR) treating wastewater from the malting process with a high content of particulate organic matter. At an organic loading rate of 3.2 kg/(m3 d) CODtotal and an influent particle concentration of 0.95 g/L MLSS an average removal of 50% in CODtotal and 80% in CODdissolved could be achieved. A comparison of granular and flocculent sludge grown under the same operating conditions showed no significant difference in removal efficiency although granules exhibited a higher metabolic activity in terms of specific oxygen uptake rate (rO2, X). Two distinct mechanisms of particle removal were observed for granular sludge: during initial granule formation, particles were incorporated into the biofilm matrix. For mature granules, a high level of protozoa growth on the granule surface accounted for the ability to remove particulate COD. Combined evaluation of the development in MLSS content and sludge bed settling rate (i.e., mean derivative of the normalized sludge volume) was found to be an adequate method for monitoring the characteristic settling properties of a granulizing sludge bed. By means of this method, a distinct substrate gradient out of several operating conditions was concluded to have the biggest impact on the formation of aerobic granular sludge. 相似文献
64.
In a survey in Greece from 1987 to 2000 hepatotoxic cyanobacterial blooms were observed in 9 out of 33 freshwaters. Microcystins (MCYSTs) were detected by HPLC in 7 of these lakes, and the total MCYST concentration per scum dry weight ranged from 50.3 to 1638 ± 464 μg g—1. Cyanobacterial genera (Microcystis, Anabaena, Anabaenopsis, Aphanizomenon, Cylindrospermopsis) with known toxin producing taxa were present in 31 freshwaters. From our data and a review of the literature, it would appear that Mediterranean countries are more likely 1) to have toxic cyanobacterial blooms consisting of Microcystis spp. and 2) to have higher intracellular MCYST concentrations. A case study in Lake Kastoria is used to highlight seasonal patterns of cyanobacterial and MCYST‐LR occurrence and to assess cyanotoxin risk. Cyanobacterial biovolume was high (> 11 μL L—1) throughout the year and was in excess of Guidance Level 2 (10 μL L—1) proposed by WHO for recreational waters and Alert Level 2 for drinking water. Further, surface water samples from April to November exceeded Guidance Level 3, with the potential for acute cyanobacterial poisoning. Intracellular MCYST‐LR concentrations (max 3186 μg L—1) exceeded the WHO guideline for drinking water (1 μg L—1) from September to November with a high risk of adverse health effects. Preliminary evidence indicates that in 3 lakes microcystins are accumulated in some aquatic organisms. Generally, a high risk level can be deduced from the data for the Mediterranean region. 相似文献
65.
Limnological characteristics of Lake Burdur in Lake District in south‐western Turkey are presented. It is a deep, tectonic (estimated max. depth 100 m), athalassic, highly alkaline, and saline lake. A set of physical and chemical variables was monitored, phyto‐ and zooplankton was sampled from surface layer of the lake during 1997. Physico‐chemical variables indicated that the lake is hyposaline and composed of some hydrochemically different water layers formed by groundwater sources located on the bottom of the lake. The phytoplankton composition of Lake Burdur consisted of Cyanophyta, Chlorophyta, Bacillariophyta, Dinophyta, and Chrysophyta. The abundance and number of species of Chlorophyta and Cyanophyta were higher than the other taxa. The zooplankton composition of the Lake consisted of Rhizopoda, Rotifera, and Crustacea. Number of species of Rotifera was higher than the other taxa. The diversities of the phyto‐ and zooplankton were calculated according to the Shannon‐Weaver diversity index. The diversity of each group was found to be low in the lake. 相似文献
66.
67.
使用1994年7月至1996年12月大气CH4和地面风现场连续观测资料,分析了瓦里关全球大气本底基准站(36°17′N, 100°54′E,海拔3816 m)地面风变化对大气CH4本底浓度的影响。结果表明,水平风向、风速和垂直风向、风速的变化对大气CH4观测值的影响在春、夏、秋、冬季有明显不同,水平风向NE—ENE—E为CH4测量最主要的局地影响非本底扇区,静风及水平风速大于10 m/s、垂直风速大于±1 m/s对观测结果都有较大影响;由的统计平均还给出了此段期间瓦里关大气CH4在不同季节的浓度分布范围和日变化类型,并分析了可能成因;将地面风数据作为大气CH4本底资料的过滤因子之一,提出了适用于不同使用目的和要求的我国内陆高原大气CH4本底数据筛选方法,本底数据留存率约为原始资料量的50%。 相似文献
68.
多普勒雷达资料4DVAR同化反演的模拟研究 总被引:21,自引:5,他引:21
利用Sun等建立的同化模式和四维变分同化方法对多普勒雷达资料反演大气风场、热力场和微物理场进行了模拟试验研究.反演的基本思路是将4DVAR同化方法应用到三维云模式,定义价值函数表征雷达资料与模式预报结果之间的差别,通过极小化价值函数得到反演场,价值函数相对模式控制变量的梯度由伴随模式求取.试验结果表明,4DVAR同化技术能够从单(双)多普勒雷达资料反演大气三维风场、热力场和微物理场.各个变量反演精度高低与同化过程中变量受约束的大小程度呈正相关.速度场和雨水场反演精度较高,温度场、云水和水汽的反演精度次之,温度场的准确反演需要较长的同化时间.价值函数中加入背景场,哪怕是单点探空给出的平均场信息也有利于提高反演精度.在采用单部多普勒雷达资料进行反演时,速度场的反演误差较大.反演区相对雷达站的位置变化对速度场反演结果有一定的影响,而对其他变量的反演影响很小.两个时次的雷达观测资料基本足够提供反演所需的时间演变信息,同化更多时次的雷达资料,反演效果改进很小.雷达观测资料的缺值会显著降低同化效果,甚至可能导致同化失败,引入背景场可以改善这一状况.4DVAR同化技术对于雷达观测资料误差不太敏感.利用双多普勒雷达合成风场提供水平风场边界条件是比较准确可靠的.在反演主体离边界较远时,VAD风场也基本可用作水平风场边界条件.微物理场的反演对模式中的微物理参数化方案较敏感. 相似文献
69.
70.
文章对采自贵州从低海拔的东部到高海拔的西部且大致平行的石灰岩和砂岩两地带均生长的3种C4草本植物,即巴茅(Miscanthusfloridulus)、白茅(Imperatacylindrica)和类芦(Neyraudiareynaudiana),以及相对应的土壤表层样品,进行了营养元素和C同位素组成分析;研究营养元素含量随着海拔的不同而出现的变化趋势,以及这些元素之间的相互协变作用,尤其是Ca和N之间的相互协变作用对植物的N含量、C/N比值和δ13C值的影响,以了解植物的C/N比值(指示植物残留物质量的一种标志)与土壤有机C积累的关系。研究结果表明,植物的N含量和δ13C值具有随海拔的上升而显著增大趋势,而植物的C/N比值在砂岩地区虽有减小的趋势,在石灰岩地带则没有。对所研究的C4草本植物来说,在土壤pH值为5.8的中性条件下显示出Ca的最大吸收,因此,Ca与其他营养元素之间的协变模式在两种土壤类型中表现出相反的倾向,并存在土壤交换性Ca的边界浓度:当土壤可交换性Ca的含量为2.24mg/g,相应土壤的pH值在5.8以下时,随着土壤可交换性Ca浓度的增大,植物的N含量上升,而植物的C/N比值会显著降低;当Ca在边界浓度以上时,随着土壤可交换性Ca浓度的增大,植物的N含量下降,而植物的C/N比值有增加的趋势。由此可见,植物残留物的N含量和C/N比值受Ca元素含量的相 相似文献