铅—试铁灵络合物吸附波及溴化十六烷基三甲基铵增敏效应的研究   总被引：1，自引：0，他引：1  

张淑云  何平 《岩矿测试》1997,16(4):313-315

在０３０ｍｏｌ／ＬＨＡｃ介质中，Ｐｂ（Ⅱ）与７＿碘＿８＿羟基喹啉＿５＿磺酸（试铁灵，Ｆｅｒｏｎ）的络合物于－０５４Ｖ（ｖｓ．ＳＣＥ）产生一尖锐的极谱波，加入溴化十六烷基三甲基铵（ＣＴＭＡＢ）显著增敏，可使极谱波增高约４倍。峰电流与Ｐｂ（Ⅱ）浓度在９６×１０－９～４８×１０－６ｍｏｌ／Ｌ呈良好的线性关系，检出限为４８×１０－９ｍｏｌ／Ｌ。用多种电化学方法研究了该极谱波的性质及电极反应机理表明，络合物组成比为ｎＰｂ（Ⅱ）∶ｎＦｅｒｏｎ＝１∶１，极谱波为吸附波，峰电流由中心离子Ｐｂ（Ⅱ）还原产生，电子转移数为２。试验了多种离子对峰电流的影响，拟定的方法用于矿样分析，结果与原结果相符。  相似文献   

Reinterpretation of the RRISP-77 Iceland shear-wave profiles   总被引：1，自引：0，他引：1  

William Menke  Bryndís Brandsdóttir  Páll Einarsson  Ingi Th. Bjarnason 《Geophysical Journal International》1996,126(1):166-172

  相似文献   

地幔流体的前缘研究   总被引：19，自引：8，他引：19  

曹荣龙 《地学前缘》1996,3(4):161-171

地幔流体是与地幔环境处于平衡的气体和挥发分。其主要化学组分为碳、氢、氧、氮、硫（ＣＨＯＮＳ）。它以富于地球内部原始组分为特征，但也包含部分再循环组分。地幔挥发分在弱还原条件下主要为ＣＯ２－Ｈ２Ｏ，强还原环境则以ＣＨ４－Ｈ２Ｏ－Ｈ２为主。地幔流体地球化学的重要性质为：（１）易溶于硅酸盐熔体；（２）净化作用；（３）再沉淀作用。近年来，有关地幔流体中稀有气体和挥发分的起源、分布及同位素组成等前缘领域的研究已取得重要进展。当前拟优先探索的问题包括气体裂化与金刚石成因，非生物成因地幔烃，地幔流体与成矿作用，以及地幔挥发分注入与地壳重熔等。  相似文献   

一种新的、快速的碳、氮、硫同位素测定手段──EA－IRMS连线分析技术   总被引：2，自引：0，他引：2  

储雪蕾 《矿物岩石地球化学通报》1996,(4)

一种新的、快速的碳、氮、硫同位素测定手段──ＥＡ－ＩＲＭＳ连线分析技术储雪蕾（中国科学院地质研究所，北京１０００２９）关键词元素分析仪－同位素比值质谱仪，连线分析碳，氮，硫同位素碳、氮、硫三种元素的稳定同位素在地学、生态学、环境科学等领域受到了重视，...  相似文献   

陕西凤县庞家河金矿床基本地质特征及成矿作用分析   总被引：5，自引：0，他引：5  

权志高 《陕西地质》1996,(2)

阐述了庞家河金矿床的地层、构造控矿特征，研究了矿床的化学成分、微量元素及矿体、矿石的基本特点，分析了矿石及矿石矿物黄铁矿的O、S、Pb稳定同位素组成；认为庞家河金矿的成矿介质水为同生建造水，成矿物质来源于围岩上沉盆统下东沟组，矿床类型为热水溶滤成因的微细浸染型。  相似文献   

极谱催化波测定天然水中微量锗的研究     

甘树才  曹淑琴 《世界地质》1996,15(3):101-104

系统研究了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４－Ｖ体系报道极谱催化波的影响因素，测定了Ｇｅ－ＡＲＳ－Ｈ２Ｃ２Ｏ４三元配合物的配合比为１：２：１。实验初步证明了该体系催化波为具有吸附性质的平行催化波。本法检出限为０．１４ｍｇ．ｍＬ＾－１，相对标准偏差小于９．８９％，标准回收率为９３．７０％－１０９．０％，０－５０ｍｇ．ｍＬ＾－１的锗具有良好的线性关系。  相似文献   

Interpretation of S-wave data from Tai’an-Xinzhou DSS profile and its relationship with Xingtai earthquakes     

Song-Yan Song  Xue-Song Zhou  Chun-Yong Wang  Xian-Kang Zhang  Jian-Li Song  Yi Gong 《地震学报(英文版)》1997,10(1):15-25

On the basis of S wave information from Tai’an-Xinzhou DSS profile and with reference to the results from P-wave interpretation, the 2-D structures, including S-wave velocity V _s, ratio γ between V _p and V _s; and Poisson’ s ratio σ, are calculated; the structural configuration of the profile is presented and the relevant inferences are drawn from the above results. Upwarping mantle districts (V _s≈4.30 km/s) and sloping mantle districts (V _s≈4.50 km/s) of the profile with velocity difference about −4% at the top of upper mantle are divided according to the differences of V _s, γ and σ in different media and structures, also with reference to the information of their neighbouring regions; the existence of Niujiaqiao-Dongwang high-angle ultra-crustal fault zone is reaffirmed; the properties of low and high velocity blocks (zones) including the crust-mantle transitionalzone and the boudary indicators of North China rift valley are discussed. A comprehensive study is conducted on the relation of the interpretation results with earthquakes. It is concluded that the mantle upwarps, thermal material upwells through the high-angle fault, the primary hypocenter was located at the crust-mantle juncture 30.0∼33.0 km deep, and additional stress excited the M _S=6.8 and M _S=7.2 earthquakes at specific locations around 9.0 km below Niujiaqiao-Dongwang, the earthquakes took place around the high-angle ultra-crustal fault and centered in the brittle media and rock strata with low γ and low σ values. This subject is part of the 85-907-02 key project during the “8th Five-Year Plan” from the State Science and Technology Commission.  相似文献   

Biodegradability of the Anti-tumour Agents 5-Fluorouracil,Cytarabine, and Gemcitabine: Impact of the Chemical Structure and Synergistic Toxicity with Hospital Effluent     

K. Kümmerer  A. Al-Ahmad 《洁净——土壤、空气、水》1997,25(4):166-172

Most anti-tumour agents are known to be carcinogenic, mutagenic, teratogenic, embryotoxic or fetotoxic. Only little is known about the environmental impact of pharmaceuticals. Unmetabolized active substances are excreted and will show up in municipal wastewater. Therefore, we examined the biodegradability of the widely used anti-tumour agent 5-fluorouracil (5-FU), also as an example for assessing the impact of hospital effluent on the biodegradation of a test compound. The biodegradability of the structurally similar anti-tumour agents cytarabine and gemcitabine was also examined. Test systems used were the closed bottle test (OECD 301 D) and the modified Zahn-Wellens test (OECD 302 B). 5-FU was not biodegradable in the closed bottle test (CBT) nor in the Zahn-Wellens test (ZWT). At the highest concentration of 5-FU, with hospital effluent an inhibition of the degradation of substances present in hospital effluent was observed, probably as a result of a synergistic effect by 5-FU with antibiotics present in hospital sewage. Gemcitabine was biodegraded 42% in the CBT. The prolongation of the test period to 40 days only improved the result to 45%. In the ZWT, the biodegradation of gemcitabine was 50%. Cytarabine was partially biodegraded in the CBT (50%), but only after an adaptation period of 20 days. After a test prolongation to 40 days, the degree of biodegradation was 80%. In the ZWT, the biodegradability was > 95% after only a few days.  相似文献   

内蒙古地区地震活动度S值特征分析     

高立新 《东北地震研究》2004,20(2):15-20

采用定量描述地震活动强弱程度的地震活动度方法，研究了内蒙古地区1970年以来中强地震的分布特征和活动规律，发现内蒙古地区S值存在5年周期的起伏活动规律。在分区研究区的基础上，内蒙古地区从西到东，地震活动度S值呈现有规律的强一弱交替特征。  相似文献   

用远震接收函数研究滇西地区的深部结构   总被引：5，自引：1，他引：5       下载免费PDF全文

贺传松  王椿镛  吴建平 《地震学报》2004,26(3):238-246

滇西地区地处欧亚板块碰撞或俯冲的边界地带，曾受到多期构造运动的影响，其地质环境和构造背景十分复杂，是我国地震活动比较活跃的地区之一. 本文选用国家、地方和流动数字台网的16个台站的远震记录. 其中PASSCAL甚宽频带流动地震台站4个，提取有效接收函数近2 000条. 两条测线的直线距离分别为650 km和450 km， 横切了滇西地区的一些主要构造单元. 研究表明，怒江断裂可能是一条具有俯冲性质的缝合线. 川滇菱形块体东西两侧的分界线¾红河断裂和小江断裂可能是直立的缝合线或碰撞带. 攀西构造带仍具有大陆裂谷的特征，即地表凹陷、上地幔隆起. 滇西地区的构造格局具有一定的规律性，造山带与缝合线相间分布. 滇西地区由北向南地壳厚度渐次减薄，S波速度整体偏低.   相似文献