基于扫描电镜技术电弧直读原子发射光谱载体缓冲剂的改进     

邱宏喜  赵刚  刘玖芬  李克勇  龙志武  李志雄  向懋笔  刘伟洪 《岩矿测试》2018,37(3):283-291

原子发射光谱粉末固体进样法由于样品处理方法简单,检出限低,环境污染小,被大量应用于痕量Ag、B、Sn等多种元素的同时测定,但显著的基体效应制约了方法的适用性。本文基于扫描电镜微区检测技术,对比分析了特定配方与不同样品、在不同时段反应产物的组成差异,结合蒸发曲线反推反应过程,研制了适用于不同基体类型地球化学样品的载体缓冲剂。在实现前人致力改善弧烧过程的基础上,研制的载体缓冲剂是以K2S2O7、Na F作为助熔剂,"催化"基体分解,与聚四氟乙烯、沉降S等协同促进待测元素以多种形式快速蒸发;缓冲剂在与样品基体作用过程中形成的Al_2O_3-SiO_2-CaO-BaO互熔体降低了Tammann温度,能够原位吸收Ca O、Si O等基体氧化物,抑制了其干扰。相比已有方法,灵敏度提高1.2倍以上,精密度、准确度、检出限等优于各类地球化学调查规范要求。  相似文献   

稀有矿物天津蓟县锰方硼石振动光谱特征研究   总被引：2，自引：0，他引：2  

张然  许虹  李梅梅 《岩矿测试》2018,37(2):139-145

锰方硼石是一种罕见的锰氯硼酸盐矿物(Mn_3B_7O_(13)Cl),天津蓟县锰方硼石矿床是世界上唯一一个锰方硼石矿床,该地锰方硼石矿物粒度细小(50~300 nm),与美国锰方硼石存在明显差别。目前涉及我国锰方硼石的研究较少,为了探究稀有矿物蓟县锰方硼石矿物学和材料学特征,本文对其进行振动光谱和高温拉曼光谱研究。常温振动光谱结果表明,蓟县锰方硼石与美国锰方硼石各主要谱带归属一致,但峰位整体上表现为向高频方向偏移且谱峰宽、强度小。高温拉曼光谱显示,随着温度升高,谱带向低频方向偏移,位移距离随温度升高呈现先增大后减小的趋势,且在680~687K处位移距离出现转折。蓟县锰方硼石粒度细小是造成上述谱峰变化的主要原因。本文运用高温拉曼技术对粒度极为细小的锰方硼石进行测试分析,研究其谱峰变化与相变的关系,实验证明高温拉曼光谱可以作为研究矿物相变的一种有效手段。  相似文献   

电感耦合等离子体发射光谱法测定西藏矽卡岩型铜多金属富矿石中8种成矿元素     

王祝  邵蓓  柳诚  冯源强  刘高令  邬国栋  李明礼 《岩矿测试》2018,37(2):146-151

矽卡岩型铜多金属富矿石是西藏特有矿产,具有成矿元素多样且含量普遍较高的特点,矿物类型主要为硫化物型,成矿元素有Cu、Pb、Zn、Fe、Ag、Bi、Cd、Co等。采用湿法处理此类样品时常因银、铅等元素含量较高出现难溶解、易沉淀现象,导致测定结果偏低。本文采用盐酸预处理、硝酸-氢氟酸-高氯酸溶矿体系,能有效除去样品中的硫,样品分解效果好,选择稀释倍数为1000、溶液介质为10%盐酸,样品溶液不会产生沉淀,采用电感耦合等离子体发射光谱法测定各待测元素均可获得较好的准确度、精密度。方法测定范围为:Cu 0.0056%~20.0%,Pb 0.0087%~20.0%,Zn 0.0031%~20.0%,Fe 0.0090%~20.0%,Ag 5.40~3000μg/g,Bi 10.8~5000μg/g,Cd 0.69~5000μg/g,Co 2.09~5000μg/g。用国家标准物质进行验证,方法准确度小于5.40%,精密度(RSD,n=11)小于4.41%。该方法具有前处理流程简单、分析速度快、同时测定元素多、线性范围宽等优点,经实际样品测试与不同方法分析数据吻合。  相似文献   

Liassic age of an oceanic gabbro of the External Rif (Morocco): Implications for the Jurassic continent–ocean boundary of Northwest Africa     

《Comptes Rendus Geoscience》2018,350(6):299-309

This work concerns the northernmost limit of the West African Craton (WAC) and Variscan WAC-related terranes of NW Africa. Based on newly obtained radiometric age of an oceanic gabbro from the “Mesorif Suture Zone” of the External Rif Belt, we propose a revised interpretation of this puzzling lineament. We report on a 190 ± 2 Ma LA–ICP–MS U–Pb zircon age of a trondhjemite vein cross-cutting the Bou Adel gabbro, which is one of the largest oceanic units of the quoted suture zone. We previously interpreted the arcuate MSZ in terms of transported, hyper-extended margin of the Alpine Tethys, based on a K–Ar 166 ± 3 Ma age ascribed to the Bou Adel gabbro in the literature. The new, Early/Middle Liassic age coincides instead with the onset of oceanic floor formation in the Central Atlantic. We hypothesize that the Mesorif suture zone corresponds to the transported trace of the West African Atlantic margin surrounding the northwestern Moroccan Meseta promontory and connecting with the ENE-trending North African Transform North African transform. The latter zone sharply bounded the North Africa margin and connected the Central Atlantic with the Alpine Tethys. We propose that transported elements from the North African transform constitute the “Mesorif Basalt–Breccias” lineament parallel to and more external than the Mesorif suture zone. If correct, this new interpretation provides an opportunity to develop detailed field and laboratory studies of an exhumed segment of the up-to-now conceptual Jurassic North African transform.  相似文献   

Democracy,electoral systems and emissions: explaining when and why democratization promotes mitigation     

Zeynep Clulow 《Climate Policy》2019,19(2):244-257

Does democratization help countries mitigate climate change? On the one hand, by increasing the value placed on quality of life, creating more opportunity for environmental actors to influence policymaking and holding elected politicians accountable, an increase in democratic institution and process should promote emissions reduction. On the other hand, the desire to safeguard individual freedom presumably brings with it an aversion to intervene in lifestyle and market decisions, thereby raising the risk of climate inaction. This outcome is further encouraged by the political need to balance (conflicting) environmental and energy interests.

This article evaluates the thesis that democratization promotes mitigation in light of national emissions levels from 1990 to 2012. Using data from the Freedom House, Polity IV and V-Dem indices, World Bank World Development Indicators and the World Resources Institute Climate Data Explorer it conducts a large-N investigation of the emissions levels of 147 countries. Although several quantitative studies have found that domestic political regimes affect emissions levels, this article goes beyond existing research by building a more sophisticated – multilevel- research design to determine whether democracy: (a) continues to be an important driver of emissions when country-level clustering is accounted for and (b) has uniform effects across countries. The results indicate that, even after controlling for country-level clustering and holding constant the other confounding factors, democracy is indeed a significant driver. More strikingly, they reveal that while democracies tend to have lower emissions than non-democracies, democratization spells within the same country do not have the same kind of inhibitory effects as they do between countries. This article also finds tentative evidence that the type of electoral system plays a critical role in shaping the effect of democratization on individual countries.

Key policy insights

• Democracies tend to perform better in terms of emission levels than non-democracies.

• Democratization has non-uniform effects across different countries, with the type of electoral system playing a key role in determining the effect that democratization has on national emissions.

• Further research is needed to develop our understanding of how the political context influences emissions, especially with regard to the influence of pro and anti-decarbonisation actors.

  相似文献   

40Ar/39Ar ages and zircon petrochronology for the rear arc of the Izu-Bonin-Marianas intra-oceanic subduction zone     

Axel K. Schmitt  Kevin Konrad  Graham D. M. Andrews  Kenji Horie  Sarah R. Brown  Anthony A. P. Koppers 《International Geology Review》2018,60(8):956-976

Long-lived intra-oceanic arcs of Izu-Bonin-Marianas (IBM)-type are built on thick, granodioritic crust formed in the absence of pre-existing continental crust. International Ocean Discovery Program Expedition 350, Site U1437, explored the IBM rear arc to better understand continental crust formation in arcs. Detailed petrochronological (U–Pb geochronology combined with trace elements, oxygen and hafnium isotopes) characterizations of zircon from Site U1437 were carried out, taking care to exclude potential contaminants by (1) comparison of zircon ages with ship-board palaeomagnetic and biostratigraphic ages and ⁴⁰Ar/³⁹Ar geochronology, (2) analysing zircon from drill muds for comparison, (3) selectively carrying out in situ analysis in petrographic thin sections, and (4) minimizing potential laboratory contamination through using pristine equipment during mineral separation. The youngest zircon ages in Site U1437 are consistent with ⁴⁰Ar/³⁹Ar and shipboard ages to a depth of ~1390 m below sea floor (mbsf) where Igneous Unit Ig 1 yielded an ⁴⁰Ar/³⁹Ar age of 12.9 ± 0.3 Ma (all errors 2σ). One single zircon (age 15.4 ± 1.0 Ma) was recovered from the deepest lithostratigraphic unit drilled, Unit VII (1459.80–1806.5 mbsf). Site U1437 zircon trace element compositions are distinct from those of oceanic and continental arc environments and differ from those generated in thick oceanic crust (Iceland-type) where low-δ¹⁸O evolved melts are produced via re-melting of hydrothermally altered mafic rocks. Ti-in-zircon model temperatures are lower than for mid-ocean ridge rocks, in agreement with low zircon saturation temperatures, suggestive of low-temperature, hydrous melt sources. Zircon oxygen (δ¹⁸O = 3.3–6.0‰) and hafnium (εHf = + 10–+16) isotopic compositions indicate asthenospheric mantle sources. Trace element and isotopic differences between zircon from Site U1437 rear-arc rocks and the Hadean detrital zircon population suggest that preserved Hadean zircon crystals were probably generated in an environment different from modern oceanic convergent margins underlain by depleted mantle.  相似文献   

华北克拉通古元古代地层划分与对比   总被引：2，自引：2，他引：0  

杨崇辉  杜利林  宋会侠  任留东  苗培森  路增龙 《岩石学报》2018,34(4):1019-1057

华北克拉通古元古代地层分布广泛,主要集中于胶辽吉带、中部带和西部孔兹岩带三个带状区域。近年来华北克拉通古元古代地层研究取得了很大的进展,根据作者的研究和前人的大量工作,本文对华北克拉通主要的古元古代地层的组成、时代、形成的构造背景等进行了总结。发现华北克拉通古元古代底部2.47～2.35Ga间的地层普遍缺失,反映了华北克拉通地质演化历史上的一个静寂时期。～2.3Ga在华北克拉通中条山及鲁山等地发育了少量的冷口变质火山岩以及上太华岩群变质地层。大量的年代学资料表明华北克拉通以往认为时代大致始于2.5Ga的滹沱群、甘陶河群、辽河岩群、绛县群、中条群等众多地层实际年龄多集中在2.2～1.9Ga之间,而且大多数地区所划分的不同的古元古代地层在时间上是并置或叠合的,没有新老或上下关系,仅在中条山地区和五台地区的古元古代地层具有从老到新连续演化的特征。目前,古元古代早期2.4～2.3Ga的地层研究程度还不高,形成的构造背景存在岛弧和裂谷两种不同的认识,我们倾向于活动大陆边缘环境,推测在鲁山-华山-中条山-吕梁山一带存在古元古代早期的岛弧与活动大陆边缘的相互作用。2.2～1.9Ga这一阶段的地层除孔兹岩系外,通常为变质火山-沉积岩系,且火山岩基本都具有双峰式火山岩特征,表明它们应该形成于伸展环境,但对伸展的机制还存在裂谷与弧后盆地的争议,根据作者等的工作本文倾向于它们形成于陆内裂谷环境,反映了华北克拉通可能从2.2Ga开始经历了强烈的伸展活动,最终导致了原有基底的裂解。  相似文献   

河南西峡晚白垩世恐龙蛋化石壳微量元素组成及其对恐龙灭绝的指示意义   总被引：2，自引：1，他引：1  

汪晓伟  姚肖永  徐学义 《岩矿测试》2015,34(5):520-527

恐龙蛋化石是探索恐龙生存和灭绝的重要研究材料,目前对恐龙蛋化石的研究集中在生物学和埋藏特征方面。本文利用电感耦合等离子体发射光谱法(ICP-OES)对采自河南西峡晚白垩世的12枚恐龙蛋化石壳及部分围岩进行分析测试,研究其生命微量元素组成及其与恐龙灭绝的关系。结果表明,恐龙蛋壳中缺乏碳氮磷硫等有机质元素,而主要由钙铝镁铁钾等生命必需元素和锶锰钡镧锌硼钒钴铱等微量元素组成,其中锶和铱均具有明显的超高异常,这可能与地外撞击事件引起生态环境的急剧变化有关。元素的组合规律表明西峡盆地晚白垩世应为干旱、半干旱的气候环境,来自于环境中异常含量的锶和铱共同作用使这一时期该地区大量的恐龙蛋在恐龙体内遭受污染,发育孵化机能受到影响,成为导致盆地内恐龙灭亡的主要原因之一。这一发现为探讨恐龙生活环境变化、灭绝原因以及揭示晚白垩纪古气候提供了重要依据。  相似文献   

双毛细管在线干扰校正-电感耦合等离子体发射光谱法测定含铀地质样品中微量铅     

杨珍  贺攀红  张延玲  孙银生  荣耀  张伟 《岩矿测试》2015,34(5):528-532

应用电感耦合等离子体发射光谱法测定地质样品中的铅时,基体元素的干扰会使测量结果偏低。本文用氢氟酸、硝酸、高氯酸、盐酸溶解样品,采用等径双毛细管在线干扰校正的方法测定了含铀地质样品中的微量铅。首先通过双毛细管确定了样品溶液中的Fe、Al对铅有负干扰,而一定浓度的U、Ba、Ti、Ca、Mn、K、Mg、Na等基体元素没有干扰或可以忽略,由此在线双毛细管根据样品中Fe、Al的含量使用不同的校正试液建立标准曲线,测定未知样品时同步进行稀释,降低了Fe、Al的基体效应。方法检出限为1.5μg/g,精密度(RSD)小于5%。与普通干扰校正法相比,双毛细管在线干扰校正法可根据不同基体的样品使用不同的干扰校正试液,快速建立标准曲线进行复杂样品的测定,且避免了二次稀释,节省试剂,适合测定基体成分接近的批量样品。  相似文献   

电感耦合等离子体发射光谱-逐级化学提取法研究低硫煤矸石中微量元素的赋存状态及其环境效应     

丁帅帅  郑刘根  程桦 《岩矿测试》2015,34(6):629-635

煤矸石是我国堆存量最大的工业固体废物,本文应用电感耦合等离子体发射光谱法、逐级化学提取法和相关性分析研究了淮北临涣矿区低硫煤矸石中10种微量元素的含量及赋存状态,并运用风险评价指数法评价其环境效应。结果表明,低硫煤矸石中Ba、Co、Cr、Mn、Ni、Pb、V含量均高于淮北煤和中国煤均值,Mn、V的富集系数大于1,有一定迁移风险。微量元素主要以残渣态和铁锰氧化物结合态存在,两者质量分数之和为68.87%~92.93%,其中Cd、Co、Cr、Cu、Ni、Pb、Zn赋存于硫化物矿物中,V赋存于黏土矿物中,Mn赋存于碳酸盐矿物和硫化物矿物中。10种微量元素对环境的危害性大小为:MnZnNiPbCdCuBaVCrCo,表明低硫煤矸石堆存过程中活性态Mn对生态环境造成危害的可能性最大,由Mn可能引起的煤矸石山周边地区土壤及水体污染应当重视。  相似文献