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1.
?zmir is the third largest city in Turkey and has being the centre of art, culture, tourism and trade activities throughout the 5,000 years of its history. Natural stones brought from different parts of the world have been widely used for construction of the prestigious buildings, monuments and roads etc., in the past in the city. Renovation of the street pavements and public gathering areas in the city centre has been undertaken by the Metropolitan Municipality in 2000 and continued through the year of 2001. These renovation activities have mainly been carried out in the streets running parallel to the sea shore. Volcanic rocks brought from the Central Anatolia Ankara-Gölba?? (andesites) and Kayseri-?ncesu (tuffs) have been used in the renovation works. These rocks have shown extensive deteriorations within 4 years of their usage between 2001 and 2005 under the influence of different environmental factors. In this study, the deteriorations developed in the recently placed volcanic rocks used as kerb and pavement stones in the city centre of ?zmir in the light of their mineralogical, chemical, physical and mechanical properties, used locations and the environmental factors are presented.  相似文献   
2.
Silicate and sulfide melt inclusions from the andesitic Farallón Negro Volcanic Complex in NW Argentina were analyzed by laser ablation ICPMS to track the behavior of Cu and Au during magma evolution, and to identify the processes in the source of fluids responsible for porphyry-Cu-Au mineralization at the 600 Mt Bajo de la Alumbrera deposit. The combination of silicate and sulfide melt inclusion data with previously published geological and geochemical information indicates that the source of ore metals and water was a mantle-derived mafic magma that contained approximately 6 wt.% H2O and 200 ppm Cu. This magma and a rhyodacitic magma mixed in an upper-crustal magma chamber, feeding the volcanic systems and associated subvolcanic intrusions over 2.6 million years. Generation of the ore fluid from this magma occurred towards the end of this protracted evolution and probably involved six important steps: (1) Generation of a sulfide melt upon magma mixing in some parts of the magma chamber. (2) Partitioning of Cu and Au into the sulfide melt (enrichment factor of 10,000 for Cu) leading to Cu and Au concentrations of several wt.% or ppm, respectively. (3) A change in the tectonic regime from local extension to compression at the end of protracted volcanism. (4) Intrusion of a dacitic magma stock from the upper part of the layered magma chamber. (5) Volatile exsolution and resorption of the sulfide melt from the lower and more mafic parts of the magma chamber, generating a fluid with a Cu/Au ratio equal to that of the precursor sulfide. (6) Focused fluid transport and precipitation of the two metals in the porphyry, yielding an ore body containing Au and Cu in the proportions dictated by the magmatic fluid source. The Cu/S ratio in the sulfide melt inclusions requires that approximately 4,000 ppm sulfur is extracted from the andesitic magma upon mixing. This exceeds the solubility of sulfide or sulfate in either of the silicate melts and implies an additional source for S. The extra sulfur could be added in the form of anhydrite phenocrysts present in the rhyodacitic magma. It appears, thus, that unusually sulfur-rich, not Cu-rich magmas are the key to the formation of porphyry-type ore deposits. Our observations imply that dacitic intrusions hosting the porphyry–Cu–Au mineralization are not representative of the magma from which the ore-fluid exsolved. The source of the ore fluid is the underlying more mafic magma, and unaltered andesitic dikes emplaced immediately after ore formation are more likely to represent the magma from which the fluids were generated. At Alumbrera, these andesitic dikes carry relicts of the sulfide melt as inclusions in amphibole. Sulfide inclusions in similar dykes of other, less explored magmatic complexes may be used to predict the Au/Cu ratio of potential ore-forming fluids and the expected metal ratio in any undiscovered porphyry deposit.Editorial handling: B. Lehmann  相似文献   
3.
本文对北京平原区Jr173井和Jr176井安山岩进行了SHRIMP和LA-LCP-MS锆石U-Pb定年,用以精确限定北京平原区火山岩时代、盆地形成与地貌转变之间的关系。2个安山岩中的锆石多晶型良好,具有典型的生长环带和较高的Th/U比值,显示其为岩浆锆石。Jr173井底部安山岩14颗锆石的206Pb/238U年龄可分为两组,其加权平均年龄分别为122.6Ma和138.4Ma;Jr176底部安山岩53颗锆石的206Pb/238U加权平均年龄为122.63Ma,表明该期火山岩的形成时代为早白垩世晚期,与前人认为的侏罗纪有较大区别。结合前人资料,北京地区沿着黄庄-高丽营断裂一线形成断陷盆地,西部隆升为山脉,东部下降为平原,就其安山岩喷发时代、空间展布和盆地发育特征而言,可视为中国东部晚中生代构造演化的一个缩影。  相似文献   
4.
大青山地区出露地层主要是侏罗系中统兰旗组安山岩、安山质角砾熔岩、凝灰岩等;侵入岩为晚侏罗世二长花岗岩;断裂发育,岩石蚀变强烈。金地球化学特征表明,金主要富集在侏罗系中统兰旗组火山岩中。金的原生晕、次生晕异常特征和分布表明,破碎蚀变岩带就是金矿化蚀变带。通过野外地质调查已在三道盘—马家窝铺的安山岩和二长花岗岩中发现了5条金矿化带和29条金银矿脉。实践证明,在大青山地区进行金矿普查运用地球化学方法是有效的。  相似文献   
5.
ABSTRACT

The early and middle Miocene andesitic lavas of the Sierra de Angangueo (MALSA) represent one of the most prominent landforms of intermediate magmatism in Central Mexico. In this paper, we present new petrological, geochemical, thermobarometric, and geochronological data in order to discuss the conditions of MALSA’s emplacement in the lithosphere.

MALSA comprises a voluminous eroded early Miocene andesitic structure, emplaced on a Mesozoic basement. MALSA shows a wide variety of textures, from glassy and aphanitic to porphyritic, mainly composed of plagioclase (An10-55), clinopyroxene (Wo60-65; En35-40), amphibole (Mg-hornblende/edenite), and rarely olivine (Fo75–86) or orthopyroxene (En72-80). Major and trace elements plots follow a typical calc-alkaline trend with relatively increasing fractionation.

The 87Sr/86Sr isotopic signatures range between 0.703343 and 0.704459 and εNd values from +1.37 to +4.84; apparently without a significant contribution of an old, thick, or highly radiogenic continental crust. Lead isotope values 206Pb/204Pb vary between 18.68 and 18.83, 207Pb/204Pb from 15.57 to 15.65, and 208Pb/204Pb from 38.39 to 38.67, suggesting contamination of magmas by juvenile crust. Thermodynamic calculations indicate equilibrium conditions at ≤900°C and ~2 kbar and an average log ?O2 ≈ ?10.

Ar–Ar and K–Ar dating carried out on whole rock, matrix, amphibole, and plagioclase phenocrysts yielded ages between 13.0 ± 0.5 and 23.9 ± 0.3 Ma. These dates indicate a series of pulses with maximum magmatic activity between 24 and 18 Ma.

The geochemical and petrologic data suggest partial melting processes in the lower or middle crust associated with possible magma mixing during its ascent; such a mechanism could explain a hybrid mantle-lower crust origin of this large volume of andesites. The MALSA, as well as the early to middle Miocene magmatism from Western Mexico, could represent two coeval and independent magmatic arcs prior to the present Trans-Mexican Volcanic Belt (TMVB) in Central Mexico.  相似文献   
6.
The evaluation of potential rock slope problems using stereographic projection techniques known as kinematic analysis is one of the most important parts of a slope stability investigation to be carried out in jointed rock media. In conventional stereoprojection techniques for the assessment of possible rock slope failures, the peak orientations of joints together with the slope geometry and the friction angle of the weakness planes are used. Other possible joint orientations which may be encountered in the rock media are ignored, although they belong to the group of joint peak orientations. In this study, nearly vertical jointed andesites cropped out at the Altindag settlement region in Ankara were studied in order to evaluate the relevance of this ignored discontinuity orientation data on slope stability. As a result, probabilistic risk maps for planar, toppling and wedge failures were produced using the kinematic rules and digital elevation model of the study area. The comparison of the distribution of the actual failures in the area and the probabilistic risk maps prepared for the study area revealed that all of the identified failures are found to be located in the higher risk zones on the probabilistic risk maps.  相似文献   
7.
Crystallization experiments at 400 MPa, oxidized condition (logfO2= NNO + 1, where NNO is nickel–nickel oxide buffer) andover a range of temperatures (850–950°C) and fluidcomposition (XH2Oin = 0·3–1) have been carriedout to constrain the storage conditions of the sulphur-richmagma of the Huerto Andesite (an anhydrite, pyrrhotite, andS-rich apatite-bearing, post-Fish Canyon Tuff mafic lava). Theresults are used to evaluate the role of fluids released fromthe crystallization of magmas such as the Huerto Andesite onthe remobilization of the largely crystallized dacitic FishCanyon magma body. Experiments were performed using the naturalandesitic bulk composition with and without added sulphur. Thepresence of sulphur slightly affects the phase equilibria bychanging the phase proportions, stability fields of plagioclase,pyroxenes and ilmenite, and also affects the plagioclase composition.Phase equilibria and mineral composition data indicate thatthe magma may have contained 4·5 wt % water in the meltand that the pre-eruptive temperature was 875 ± 25°C.Assuming that the magma was in equilibrium with a fluid phase,the CO2 concentration of the melt is estimated to be in therange 2000–4000 ppm (at 400 MPa). Before eruption, theandesite had an oxidation state very close to, or slightly within,the co-stability field of anhydrite–pyrrhotite at NNO+ 1·1. At these conditions, the sulphur content in themelt is 500 ppm. Assuming open-system degassing resulting fromcontinuing crystallization at depth, most of the CO2 dissolvedin the andesitic melt should be released after the crystallizationof <10 vol. % of the magma, corresponding to a cooling from875 to 825–850°C. Thus, the fluids released owingto crystallization processes should be mainly composed of waterat temperatures below 825°C. KEY WORDS: experimental study; andesite; volatile; Fish Canyon Tuff; Huerto Andesite  相似文献   
8.
东昆仑西段夏日哈木地区出露一套鄂拉山组火山岩,其成因对古特提斯洋演化过程具有重要的指示意义。通过对其进行锆石U-Pb年代学、Hf同位素和全岩主、微量元素、Sm-Nd同位素等研究确定其形成时代、岩石成因及其构造意义。安山岩中锆石的^(206)Pb/^(238)U加权平均年龄为223±2Ma,属于晚三叠世。岩石具有较低的SiO_(2)(59.45%~63.10%)和Mg^(#)值(28~51)、较高的Al_(2)O_(3)(16.19%~17.66%)和K_(2)O含量(1.42%~3.50%),表现为弱过铝高钾钙碱性系列。岩石具有富集轻稀土和大离子亲石元素,亏损高场强元素的特征,结合全岩ε_(Nd)(t)值(-4.3~-3.1)和锆石ε_(Hf)(t)值(-3.4~+1.1),表明其可能来源于受富集地幔熔体底侵的古老下地壳部分熔融。结合区域地质资料,认为这些安山岩形成于碰撞后伸展环境,而古特提斯洋在晚三叠世已关闭。本文研究结果也说明在造山带研究中需谨慎利用火成岩的岛弧性质来判断其俯冲环境这一构造属性。  相似文献   
9.
The small- to moderate-volume, Quaternary, Siwi pyroclastic sequence was erupted during formation of a 4 km-wide caldera on the eastern margin of Tanna, an island arc volcano in southern Vanuatu. This high-potassium, andesitic eruption followed a period of effusive basaltic andesite volcanism and represents the most felsic magma erupted from the volcano. The sequence is up to 13 m thick and can be traced in near-continuous outcrop over 11 km. Facies grade laterally from lithic-rich, partly welded spatter agglomerate along the caldera rim to two medial, pumiceous, non-welded ignimbrites that are separated by a layer of lithic-rich, spatter agglomerate. Juvenile clasts comprise a wide range of densities and grain sizes. They vary between black, incipiently vesicular, highly elongate spatter clasts that have breadcrusted pumiceous rinds and reach several metres across to silky, grey pumice lapilli. The pumice lapilli range from highly vesicular clasts with tube or coalesced spherical vesicles to denser finely vesicular clasts that include lithic fragments.Textural and lithofacies characteristics of the Siwi pyroclastic sequence suggest that the first phase of the eruption produced a base surge deposit and spatter-poor pumiceous ignimbrite. A voluminous eruption of spatter and lithic pyroclasts coincided with a relatively deep withdrawal of magma presumably driven by a catastrophic collapse of the magma chamber roof. During this phase, spatter clasts rapidly accumulated in the proximal zone largely as fallout, creating a variably welded and lithic-rich agglomerate. This phase was followed by the eruption of moderately to highly vesiculated magma that generated the most widespread, upper pumiceous ignimbrite. The combination of spatter and pumice in pyroclastic deposits from a single eruption appears to be related to highly explosive, magmatic eruptions involving low-viscosity magmas. The combination also indicates the coexistence of a spatter fountain and explosive eruption plume for much of the eruption.Editorial responsibility: R. Cioni  相似文献   
10.
Compositional heterogeneity (56–64 wt% SiO2 whole-rock) in samples of tephra and lava from the 1986 eruption of Augustine Volcano, Alaska, raises questions about the physical nature of magma storage and interaction beneath this young and frequently active volcano. To determine conditions of magma storage and evolutionary histories of compositionally distinct magmas, we investigate physical and chemical characteristics of andesitic and dacitic magmas feeding the 1986 eruption. We calculate equilibrium temperatures and oxygen fugacities from Fe-Ti oxide compositions and find a continuous range in temperature from 877 to 947°C and high oxygen fugacities (ΔNNO=1–2) for all magmas. Melt inclusions in pyroxene phenocrysts analyzed by Fourier-transform infrared spectroscopy and electron probe microanalysis are dacitic to rhyolitic and have water contents ranging from <1 to ∼7 wt%. Matrix glass compositions are rhyolitic and remarkably similar (∼75.9–76.6 wt% SiO2) in all samples. All samples have ∼25% phenocrysts, but lower-silica samples have much higher microlite contents than higher-silica samples. Continuous ranges in temperature and whole-rock composition, as well as linear trends in Harker diagrams and disequilibrium mineral textures, indicate that the 1986 magmas are the product of mixing between dacitic magma and a hotter, more mafic magma. The dacitic endmember is probably residual magma from the previous (1976) eruption of Augustine, and we interpret the mafic endmember to have been intruded from depth. Mixing appears to have continued as magmas ascended towards the vent. We suggest that the physical structure of the magma storage system beneath Augustine contributed to the sustained compositional heterogeneity of this eruption, which is best explained by magma storage and interaction in a vertically extensive system of interconnected dikes rather than a single coherent magma chamber and/or conduit. The typically short repose period (∼10 years) between Augustine's recent eruptive pulses may also inhibit homogenization, as short repose periods and chemically heterogeneous magmas are observed at several volcanoes in the Cook Inlet region of Alaska.  相似文献   
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