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排序方式: 共有238条查询结果,搜索用时 187 毫秒
21.
砷的植物修复研究进展 总被引:3,自引:0,他引:3
由于砷的毒性和"三致"效应,砷已成为人们普遍关注的环境污染之一.文章总结了砷在土壤和砷超富集植物中的形态、砷污染条件下超富集植物的生长、砷污染的植物修复以及植物超富集砷的相关机理和分子生物学研究进展.文章就砷的植物修复研究做了展望:寻找、筛选更多砷超富集植物;深入研究砷超富集机理;砷富集相关基因识别和克隆;砷超富集植物应用研究;砷超富集植物用于环境修复工程时的环境影响评价;砷超富集植物后处置与资源化技术开发. 相似文献
22.
Experimental study on metallation of tetrapyrroles in biphasic systems showed that complexation with metal cations of the first transition series is a feasible under chemical environments similar to the naturally occurring ones. The metal transport from the aqueous media to the organic, which is a novel approach using naturally occurring fatty acids hydroxy aromatic compounds and thiols, is demonstrated. Selectivity between Ni2+ and VO2+ complexation is achieved under sulfurous rich conditions. The kinetic implications are discussed in view of their geoenvironmental applicability. 相似文献
23.
Donna C. Marron 《地球表面变化过程与地形》1989,14(5):419-432
A metal-contaminated overbank deposit in west-central South Dakota resulted from the discharge of a large volume of mine tailings into a river system between the late 1800s and 1977. The deposit along the Belle Fourche River is typically up to 2 m thick and extends about 90 m away from the channel along the insides of meander bends. The sediments contain above-background levels of copper, iron, manganese, zinc, and particularly arsenic, which is commonly two orders of magnitude above background level in the contaminated sediments. Carbonate minerals in the deposit limit the desorption of arsenic by preventing acid formation. Arsenic concentrations provide a measure of the dilution of mine tailings by uncontaminated sediment. The arsenic appears to have been transported and deposited as arsenopyrite, but is now at least partially associated with iron oxides and hydroxides. Within individual samples, arsenic concentration has an inverse relation with grain size that results from the more efficient accumulation of arsenic on the greater surface area of the smaller particles. Arsenic concentration is inversely related to the sample weight percent finer than 16 μm, however, as a consequence of the dilution of the contaminated sediments by uncontaminated sediment with a finer grain-size distribution. Dilution by uncontaminated sediment from tributaries cause arsenic concentrations to decrease by a factor of 3 along 100 km of floodplain. An influx at high streamflow of uncontaminated sediment from terraces and the premining floodplain as well as from tributaries causes arsenic concentrations in parts of the contaminated deposit that are farthest away from the channel to be two to three times less than arsenic concentrations in overbank sediment that is immediately adjacent to the channel. 相似文献
24.
María Gabriela García Ondra Sracek Diego Sebastián Fernández Margarita del Valle Hidalgo 《Environmental Geology》2007,52(7):1261-1275
The concentration of arsenic measured in groundwater from three aquifers in the study area located in the Eastern Tucuman
province, Argentina, mostly depends on the lithology, but the spatial and temporal variations of concentrations seem to be
also controlled by pH changes, climatic factors, and human perturbations. The highest concentrations of As (more than 1,000 μg
L−1) were found in the shallow aquifer, made of As-rich loess, while the lowest concentrations were measured in the deep confined
aquifer, consisting of alternating layers of alluvial sands/gravels and clays. Intermediate values were measured in the semiconfined
aquifer made of the fluvial sediments deposited in the Salí River valley, that alternate in the upper part of the sedimentary
sequence with layers of loess. Because most of As in the loess is considered to be adsorbed onto Fe-oxyhydroxide coatings,
the increase of pH in the flow direction (west-east) leads to increasing arsenic concentrations towards the eastern border
of the study area. The decomposition of organic wastes poured into the Salí River or associated with local and diffuse sources
of contamination in the eastern part of the study area depletes dissolved oxygen, which leads to the reductive dissolution
of Fe and Mn oxyhydroxides, and to the subsequent release of the adsorbed and co-precipitated As. This process mainly affects
shallow groundwater and the upper part of the semiconfined aquifer. Geochemical and hydrological data also suggest that rising
water table levels at the end of the wet season may also lead to reductive dissolution of As-rich Fe oxyhydroxides in the
shallow aquifer. 相似文献
25.
Jaya K. Gurung Hiroaki Ishiga Mohan S. Khadka Nav R. Shrestha 《Environmental Geology》2007,52(3):503-517
The geochemical analyses of fluvial-lacustrine aquifer sediments of the Kathmandu Valley have been made as a step in assessing
the environment for the mobilization of arsenic in groundwater. Elements measured by X-ray fluorescence (XRF) include 4 major
oxides (Fe2O3, TiO2, CaO, P2O5) and 14 trace elements (As, Pb, Zn, Cu, Ni, Cr, V, Sr, Y, Nb, Zr, Th, Sc and TS). Elution tests of 15 selected core samples
were also carried out to determine the potential leaching of arsenic from the sediments. The XRF results show that average
bulk concentrations of the major oxides and trace elements are similar to modern unconsolidated sediments and average upper
continental crust. However, the abundance of elements varies with grain size, with higher concentrations in finer-size grades.
Variations in elemental abundances within the basin are strongly controlled by sediment facies. The elution tests show that
greater amounts of arsenic are generally eluted from the fine sediments, although the rates are variable. The results overall
suggest that As concentrations in the bulk sediments are not a controlling factor for elevated As in the Kathmandu Basin groundwater,
and the roles of other factors such as redox conditions and organic matter contents are likely to be more significant. 相似文献
26.
Arsenic in mine waters: an international study 总被引:4,自引:4,他引:4
M. Williams 《Environmental Geology》2001,40(3):267-278
Hydrochemical data are presented for arsenic (As) in the mine waters of 34 gold and base-metal mining localities in seven
countries of south-east Asia, Africa and Latin America, encompassing contrasting climatic settings and at least eight discrete
styles of primary mineralization. Peak dissolved As concentrations at these sites range from 0.005–72 mg/l, with the United
States Environmental Protection Agency (US-EPA) potable water threshold of 50 μg/l exceeded in 25 cases. Arsenate (As5+) constitutes the dominant species at over 80% of sites. Very high dissolved As concentrations (>1 mg/l) show no systematic
between-site relationship with mine water pH/Eh regime. Important determinants of mine water As fluxes include iron hydrochemistry,
the presence of cyanic ore processing effluents, site geology, the paragenetic sequence that follows sulphide oxidation, climate
and mine management. Human toxicological impacts of As contamination have been recognized at only one case-study site, with
a further four considered to warrant more detailed risk assessment.
Received: 2 November 1999 · Accepted: 21 March 2000 相似文献
27.
28.
本研究对西藏鄂雅错盐湖和主要支流中不同形态的砷(亚砷酸盐As(Ⅲ)、砷酸盐As(Ⅴ)、一甲基砷酸MMA、二甲基砷酸DMA)和总汞(THg)含量进行了测定,并与主要水质参数进行相关性分析研究,结果表明鄂雅错盐湖As主要以As(Ⅴ)形态存在,其次分别为As(Ⅲ)、DMA和MMA,其中无机砷的含量明显大于有机砷。相比较其他砷的形态,盐湖中As(Ⅲ)与主要水质参数的相关性显著,与总溶解性固体(TDS)、总溶解态氮(DTN)呈显著的强正相关性,与水温、溶解氧 (DO)、氧化还原电位(Eh)、pH呈显著负相关性。总汞浓度较低,且与主要水质参数相关性不显著。通过风险评价发现鄂雅错湖水中砷存在一定的致癌健康风险,汞不存在风险。本研究丰富了西藏盐湖和支流水体中砷、汞分布特征及其环境影响因素的认识,对于环境保护具有一定的意义。 相似文献
29.
《Chemie der Erde / Geochemistry》2015,75(2):261-270
The aim of this study was to investigate the accumulation of arsenic (As) in and on roots of Zea mays (maize) and Helianthus annuus (sunflower) by means of synchrotron-based micro-focused X-ray fluorescence imaging (μ-XRF). Plant and soil samples were collected from two field sites in the Hetao Plain (Inner Mongolia, China) which have been regularly irrigated with As-rich groundwater. Detailed μ-XRF element distribution maps were generated at the Fluo-beamline of the Anka synchrotron facility (Karlsruhe Institute of Technology) to assess the spatial distribution of As in thin sections of plant roots and soil particles. The results showed that average As concentrations in the roots (14.5–27.4 mg kg−1) covered a similar range as in the surrounding soil, but local maximum root As concentrations reached up to 424 mg kg−1 (H. annuus) and 1280 mg kg−1 (Z. mays), respectively. Importantly, the results revealed that As had mainly accumulated at the outer rhizodermis along with iron (Fe). We therefore conclude that thin crusts of Fe-(hydr)oxides cover the roots and act as an effective barrier to As, similar to the formation of Fe plaque in rice roots. In contrast to permanently flooded rice paddy fields, regular flood irrigation results in variable redox conditions within the silty and loamy soils at our study site and fosters the formation of Fe-(hydr)oxide plaque on the root surfaces. 相似文献
30.
Soil, mine tailing, and waste dump profiles above three mesothermal gold deposits in the Bohemian Massif with different anthropogenic histories have been studied. Their mineralogical, major element, and arsenic (As) contents and the contents of secondary arsenic minerals were analyzed. The As-bearing minerals were concentrated and determined using X-ray diffraction (XRD) analysis, the Debye-Scherrer powder method, scanning electron microscopy (SEM), and energy-dispersive microanalysis (EDAX). The amorphous hydrous ferric oxides (HFO), As-bearing goethite, K-Ba- or Ca-Fe- and Fe- arsenates pharmacosiderite, arseniosiderite, and scorodite, and sulfate-arsenate pitticite were determined as products of arsenopyrite or arsenian pyrite oxidation. The As behaviour in the profiles studied differs in dependence on the surface morphology, chemical and mineralogical composition of the soil, mine wastes or tailings, oxidation conditions, pH, presence of (or distance from) primary As mineralization in the bedrock, and duration of the weathering effect. Although the primary As mineralization and the bedrock chemical composition are roughly similar, there are distinct differences in the As behaviour amongst the Mokrsko, Roudný and Kaperské Hory deposits. 相似文献