稀土矿床：基本特点与全球分布规律     

毛景文  宋世伟  刘敏  孟健寅 《地质学报》2022,96(11):3675-3697

本文介绍了全球稀土资源供需历史、现状和对未来的展望。从矿床成因视角切入，将稀土矿床分为内生和外生两大类型，其中内生稀土矿床包括碳酸岩型、碱性岩型、碱性岩型- 碳酸岩型、氧化铁铜金型、热液脉型，外生稀土矿床包括风化壳离子吸附型、沉积岩型、沉积矿产(煤矿、铝土矿和沉积磷矿)伴生型、砂矿和现代海洋底部含稀土的锰结核、结壳和软泥型。归纳总结了主要类型矿床的基本特点和时空分布；认为内生稀土矿床产出于四类构造环境，包括裂谷环境、碰撞后伸展环境、大陆碰撞环境和后俯冲伸展环境；从构造演化入手，探讨了在外生与内生地质过程中稀土元素的迁移和富集规律，建立了涵盖主要矿床类型的构造- 成矿模型。  相似文献   

中国南方离子吸附型稀土矿床成矿类型及其母岩控矿因素探讨     

付伟  赵芹  罗鹏  李佩强  陆济璞  周辉  易泽邦  许成 《地质学报》2022,96(11):3901-3923

传统认为中国南方的离子吸附型稀土矿床可划分为以“足洞式”为代表的重稀土型和以“河岭式”(或“花山式”)为代表的轻稀土型两种矿化类型。然而，近年来发现的许多矿床(如清溪、寨背和馒头山等)的赋矿风化壳中出现了轻稀土矿与重稀土矿并存现象，表现出特殊的“上轻下重”双层矿体结构。这指示了除重稀土型和轻稀土型之外，还存在着轻重稀土共生型的过渡类型。本研究通过对三种不同成矿类型的若干典型矿床系统对比，指出成矿类型的多样性与母岩性质密切相关，尤其是母岩的稀土元素地球化学和稀土载体矿物属性是制约成矿类型变化的关键因素。统计数据表明，从重稀土型→轻重稀土共生型→轻稀土型，成矿母岩的全岩稀土总量变化不大(ΣREY: 200×10-6~450×10-6→200×10-6~500×10-6→200×10-6~800×10-6)，但轻重稀土配分值出现较显著的区间性差异(ΣLREE/ΣHREY: 02~1→1~5→2~10)。与之同时，母岩中能为离子相稀土提供物源且具有重稀土配分属性的稀土副矿物类型和数量明显减少，这与全岩稀土元素地球化学特征中重稀土分量占比的降低趋势也互相匹配。该结果指示，以往认为重稀土配分母岩形成重稀土矿床、轻稀土配分母岩形成轻稀土矿床的传统观点需要外延，即一部分具有低度轻稀土配分属性(1＜ΣLREE/ΣHREY＜5)且含有丰富易风化稀土副矿物的母岩还可能形成轻重稀土共生型矿床，该认识可为今后离子吸附型稀土矿床勘查工作提供新的找矿依据。  相似文献   

矿物标型六性及其在胶东金矿中的应用   总被引：2，自引：0，他引：2  

陈光远  孙岱生 《吉林地质》1990,9(3):1-8

目前矿物标型研究和应用已进入一个新的阶段。作者从哲学的高度,把国内外矿物标型特征的分散研究加以集中概括和总结,提出了“矿物标型六性”的普遍规律,即普遍性、特殊性、变化性、相应性、继承性和分带性,对矿物标型特征研究具重要的指导意义。这些规律在胶东金矿中得到广泛应用,并已取得良好效果。  相似文献   

Fluid sources for the La Guitarra epithermal deposit (Temascaltepec district, Mexico): Volatile and helium isotope analyses in fluid inclusions   总被引：1，自引：0，他引：1  

Antoni Camprubí  Beverly A. Chomiak  Ruth E. Villanueva-Estrada  David I. Norman  Martin Stute 《Chemical Geology》2006,231(3):252-284

The La Guitarra deposit (Temascaltepec district, South-Central Mexico), belongs to the low/intermediate sulfidation epithermal type, has a polymetallic character although it is currently being mined for Ag and Au. The mineralization shows a polyphasic character and formed through several stages and sub-stages (named I, IIA, IIB, IIC, IID, and III). The previous structural, mineralogical, fluid inclusion and stable isotope studies were used to constrain the selection of samples for volatile and helium isotope analyses portrayed in this study. The N₂/Ar overall range obtained from analytical runs on fluid inclusion volatiles, by means of Quadrupole Mass Spectrometry (QMS), is 0 to 2526, and it ranges 0 to 2526 for stage I, 0 to 1264 for stage IIA, 0 to 1369 for stage IIB, 11 to 2401 for stage IIC, 19 to 324 for stage IID, and 0 to 2526 for stage III. These values, combined with the CO₂/CH₄ ratios, and N₂-He-Ar and N₂-CH₄-Ar relationships, suggest the occurrence of fluids from magmatic, crustal, and shallow meteoric sources in the forming epithermal vein deposit. The helium isotope analyses, obtained by means of Noble Gas Mass Spectrometry, display R/Ra average values between 0.5 and 2, pointing to the occurrence of mantle-derived helium that was relatively diluted or “contaminated” by crustal helium. These volatile analyses, when correlated with the stable isotope data from previous works and He isotope data, show the same distribution of data concerning sources for mineralizing fluids, especially those corresponding to magmatic and crustal sources. Thus, the overall geochemical data from mineralizing fluids are revealed as intrinsically consistent when compared to each other.The three main sources for mineralizing fluids (magmatic, and both deep and shallow meteoric fluids) are accountable at any scale, from stages of mineralization down to specific mineral associations. The volatile and helium isotope data obtained in this paper suggest that the precious metal-bearing mineral associations formed after hydrothermal pulses of predominantly oxidized magmatic fluids, and thus it is likely that precious metals were carried by fluids with such origin. Minerals from base-metal sulfide associations record both crustal and magmatic sources for mineralizing fluids, thus suggesting that base metals could be derived from deep leaching of crustal rocks. At the La Guitarra epithermal deposit there is no evidence for an evolution of mineralizing fluids towards any dominant source. Rather than that, volatile analyses in fluid inclusions suggest that this deposit formed as a pulsing hydrothermal system where each pulse or set of pulses accounts for different compositions of mineralizing fluids.The positive correlation between the relative content of magmatic fluids (high N₂/Ar ratios) and H₂S suggests that the necessary sulfur to carry mostly gold as bisulfide complexes came essentially from magmatic sources. Chlorine necessary to carry silver and base metals was found to be abundant in inclusion fluids and although there is no evidence about its source, it is plausible that it may come from magmatic sources as well.  相似文献   

Environmental impacts from mining at Taojiang Mn ore deposit, central Hunan, China     

Bo PENG Shurong XIE Meilian XIAO Fucheng WU Zhi SONG 《中国地球化学学报》2006,25(B08):23-24

The Taojiang Mn ore deposit was exploited in the early 1960s, and waste rocks were developed since then. Because the Mn ores were hosted within the metal-enriched black shales （Peng et al., 2004）, the continuous mining has led to the exposure of an immense quality of black shales, which might cause serious impacts on environments. The present study deals with this environmental issue with samples from the waste rocks, and from the surrounding soils and surface water. The mineralogy of the waste rock was studied using EMPA, then a large number of elements in all waste rock, soil, and water samples were analyzed at a wide range of concentrations with high accuracy using an Elan6000 ICP-MS machine at Guangzhou Institute of Geochemistry, Chinese Academy of Sciences. The waste rock is composed mostly of black shales, with minor Mn carbonates. Both black shales and Mn carbonates of the waste rock contain many sulfide minerals, mainly pyrite, with minor galena, sphalerite, chalcopyrite, and others. The waste rocks are enriched in many metals including Sc, V, Cr, Co, Ni, Fe, Mn, Cu, Zn, Pb, Th, U, Mo, Sb, Sn, Tl, and others, and the metals are mostly hosted within the sulfides. Weathering of waste rocks might cause emission of the following metals： V, Cd, Ni, Th, U, Mo, Sb, Tl, Sc, Cr, Cu, Zn, Sn, and minor Co, and Pb. The surrounding soils are highly enriched in Cr, Co, Cu, Zn, Mn, Mo, Cd, Tl, and Pb, with the enrichment factors of 2.67.3.8, 7.26, 7.27, 8.2, 5.7, 13, and 5.4, respectively. The element ratios （Rb/Cs, Fe/Mn, Nb/Zr, Hf/Zr, and Ba/Sr） and REE distribution patterns of the soils are similar to those of the waste rocks and bedrocks.  相似文献   

黔北喀斯特型铝土矿勘探工程间距的选择——以苟江铝土矿区水井坎矿段Ⅱ矿体生产勘探为例     

刘金海  王进 《贵州地质》2006,23(3):206-210

本文以苟江铝土矿水井坎矿段Ⅱ矿体用50×50m工程间距进行勘探与25×25m工程间距进行生产勘探后,对其矿体形态、厚度控制及储量变化进行对比分析,以探寻此类矿床勘探应如何选用工程间距,才能更合理地对矿体进行控制,满足生产设计的要求。  相似文献   

鄂尔多斯盆地北部底河道砂岩型铀矿地质特征   总被引：3，自引：0，他引：3  

吴仁贵  祝民强  余达淦  周万蓬 《华东地质学院学报》2006,29(1):1-6

鄂尔多斯盆地北部直罗组中的铀矿,是典型的产于河道中的砂岩铀矿,该矿床发育较好的卷状矿体。通过对该铀矿地质特征的研究,认识到发育卷状矿体的底河道砂岩型铀矿必须具备两大条件:其一是成矿砂体条件,即砂体要有较好的成层性、连通性和渗透性;其二是地层结构条件,即砂体必须存在较好的上、下隔水岩层。就砂体而言,河流相辫状沉积砂体是形成卷状矿体的主要砂体,并且以具有从辫状河向曲流河完整演化的辫状沉积砂体较好。砂体的上、下隔水岩层则有多种表现形式:下隔水层可由不透水的基岩或湖相沉积泥岩等构成;上隔水层由不透水的湖相泥岩、曲流沉积地层或岩浆岩等构成。在层间氧化作用过程上,存在纵横两个方向的氧化,即存在与河道方向一致的纵向氧化和与河道垂直的横向氧化,两种氧化作用成矿常叠加形成复杂的矿体类型;在矿化赋存的部位上,铀砂体通常发育在基底之上或不同建造之间;在古气候演变上,成矿作用发生在干旱气候条件下,或由潮湿向干旱的气候转变阶段。  相似文献   

深部找铀及湘南-桂北地区深部找铀潜景分析     

郑作环 《华东地质学院学报》2006,29(1):7-11

概述了国内外深部找矿的研究成果,指出深部找矿是当今发展的趋势。国内外重大矿产的成功发掘,其深度均在千米以上,铀矿化垂向分布深度可达4 km以上。综合介绍了国内外勘查深大矿床的特点和条件,认为岩石-构造条件是深部矿化定位的重要因素,复式岩体、成矿系统的垂向变化、构造地球物理-地球化学异常模型是深部找矿的关键依据。综述了中国南方湘南—桂北地区深部找铀的有利地质构造条件和潜力,成矿流体是该区铀矿化的根源,白垩—第三纪重大地质事件是该区深部铀成矿的重要前提,重大地质事件引发的NE-NNE,NW向深大断裂及断陷盆地是铀矿化赋存的重要场所和勘查靶区。在已知铀矿田、成矿带勘查范围基础上,在该区进行深部探索将会获得重大突破。探讨了湘南—桂北地区深部找铀的勘查思路和方法。  相似文献   

赣南银坑山铀矿点地球化学特征及其找矿意义     

张万良 《物探与化探》2005,29(3):220-223

银坑山铀矿点位于赣南九龙嶂火山盆地南东边缘,矿体呈脉状,水云母化、赤铁矿化明显。与围岩相比,矿石的Al₂O₃、SiO₂含量降低,Fe₂O₃(FeO)、MnO、CaO、S、Cl呈富集趋势,Mo、Ag、Th为主要伴生组分。从矿化蚀变组合特征看,银坑山矿点属岩浆热液型,且位于岩浆热液成矿系统的上部,深部具成矿前景。  相似文献   

地面地震层析技术在金属矿勘查中的试验研究   总被引：6，自引：0，他引：6  

徐明才  高景华  荣立新  柴铭涛  刘建勋  吕庆田  史大年 《物探与化探》2005,29(4):299-303

由于金属矿区地质构造的复杂性和复杂的地表条件, 适合于探测层状介质的地震反射方法技术在金属矿勘查中的应用受到了限制。为提高地震记录的横向分辨率, 探测复杂的地质构造及隐伏岩体等, 需研究相应的地震方法技术, 地面地震层析技术在金属矿勘查中的试验研究就是为解决上述问题而开展的。本文就非线性地面地震层析技术的基本原理进行了阐述, 并就该方法在金属矿勘查中的试验效果进行了讨论。  相似文献