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71.
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73.
Rare earth elements (REE) have been mined in North America since 1885, when placer monazite was produced in the southeast USA. Since the 1960s, however, most North American REE have come from a carbonatite deposit at Mountain Pass, California, and most of the world’s REE came from this source between 1965 and 1995. After 1998, Mountain Pass REE sales declined substantially due to competition from China and to environmental constraints. REE are presently not mined at Mountain Pass, and shipments were made from stockpiles in recent years. Chevron Mining, however, restarted extraction of selected REE at Mountain Pass in 2007. In 1987, Mountain Pass reserves were calculated at 29 Mt of ore with 8.9% rare earth oxide based on a 5% cut‐off grade. Current reserves are in excess of 20 Mt at similar grade. The ore mineral is bastnasite, and the ore has high light REE/heavy REE (LREE/HREE). The carbonatite is a moderately dipping, tabular 1.4‐Ga intrusive body associated with ultrapotassic alkaline plutons of similar age. The chemistry and ultrapotassic alkaline association of the Mountain Pass deposit suggest a different source than that of most other carbonatites. Elsewhere in the western USA, carbonatites have been proposed as possible REE sources. Large but low‐grade LREE resources are in carbonatite in Colorado and Wyoming. Carbonatite complexes in Canada contain only minor REE resources. Other types of hard‐rock REE deposits in the USA include small iron‐REE deposits in Missouri and New York, and vein deposits in Idaho. Phosphorite and fluorite deposits in the USA also contain minor REE resources. The most recently discovered REE deposit in North America is the Hoidas Lake vein deposit, Saskatchewan, a small but incompletely evaluated resource. Neogene North American placer monazite resources, both marine and continental, are small or in environmentally sensitive areas, and thus unlikely to be mined. Paleoplacer deposits also contain minor resources. Possible future uranium mining of Precambrian conglomerates in the Elliott Lake–Blind River district, Canada, could yield by‐product HREE and Y. REE deposits occur in peralkaline syenitic and granitic rocks in several places in North America. These deposits are typically enriched in HREE, Y, and Zr. Some also have associated Be, Nb, and Ta. The largest such deposits are at Thor Lake and Strange Lake in Canada. A eudialyte syenite deposit at Pajarito Mountain in New Mexico is also probably large, but of lower grade. Similar deposits occur at Kipawa Lake and Lackner Lake in Canada. Future uses of some REE commodities are expected to increase, and growth is likely for REE in new technologies. World reserves, however, are probably sufficient to meet international demand for most REE commodities well into the 21st century. Recent experience shows that Chinese producers are capable of large amounts of REE production, keeping prices low. Most refined REE prices are now at approximately 50% of the 1980s price levels, but there has been recent upward price movement for some REE compounds following Chinese restriction of exports. Because of its grade, size, and relatively simple metallurgy, the Mountain Pass deposit remains North America’s best source of LREE. The future of REE production at Mountain Pass is mostly dependent on REE price levels and on domestic REE marketing potential. The development of new REE deposits in North America is unlikely in the near future. Undeveloped deposits with the most potential are probably large, low‐grade deposits in peralkaline igneous rocks. Competition with established Chinese HREE and Y sources and a developing Australian deposit will be a factor.  相似文献   
74.
We introduce and propose zircon M257 as a future reference material for the determination of zircon U‐Pb ages by means of secondary ion mass spectrometry. This light brownish, flawless, cut gemstone specimen from Sri Lanka weighed 5.14 g (25.7 carats). Zircon M257 has TIMS‐determined, mean isotopic ratios (2s uncertainties) of 0.09100 ± 0.00003 for 206pb/238U and 0.7392 ± 0.0003 for 207pb/235U. Its 206pb/238U age is 561.3 ± 0.3 Ma (unweighted mean, uncertainty quoted at the 95% confidence level); the U‐Pb system is concordant within uncertainty of decay constants. Zircon M257 contains ~ 840 μg g?1 U (Th/U ~ 0.27). The material exhibits remarkably low heterogeneity, with a virtual absence of any internal textures even in cathodoluminescence images. The uniform, moderate degree of radiation damage (estimated from the expansion of unit‐cell parameters, broadening of Raman spectral parameters and density) corresponds well, within the “Sri Lankan trends”, with actinide concentrations, U‐Pb age, and the calculated alpha fluence of 1.66 × 1018 g?1. This, and a (U+Th)/He age of 419 ± 9 Ma (2s), enables us to exclude any unusual thermal history or heat treatment, which could potentially have affected the retention of radiogenic Pb. The oxygen isotope ratio of this zircon is 13.9%o VSMOW suggesting a metamorphic genesis in a marble or calc‐silicate skarn.  相似文献   
75.
The three largest discount chains, Kmart, Target, and Wal‐Mart, have adopted the supercenter format for expansion. This article examines the locations of and the competition among these supercenters. Wal‐Mart has the greatest number of supercenters and is driving the expansion of the supercenter format. Both Kmart and Target have clustered their supercenters in a small number of metropolitan markets. In contrast to Wal‐Mart and Kmart, Target has focused on a middle‐class rather than a blue‐collar clientele. Now Kmart is struggling following a declaration of bankruptcy. Wal‐Mart has largely defeated its supercenter competitors and now is confronting the major grocery chains for grocery sales.  相似文献   
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Two cases of on-ice and off-ice air flow characterizing the opposite weather situations over the ice-edge zone in the northern Baltic Sea are analysed on the basis of aircraft observations, and modelled using atwo-dimensional mesoscale model. The stable boundary layer (SBL) during theon-ice flow exhibited little thermal modification, but a low-level jet (LLJ) was generated at the 250-m high top of the SBL. In the model, the LLJ was associated with inertial oscillations in space, while the baroclinicity explained the shape of the wind profile well above the SBL. Although the observed LLJ was most pronounced over the ice, the modelling suggests that it was not generated by the ice edge but by the coastline some 400 km upwind of the ice edge, where a much more drastic change in the thermal stratification and surface roughness took place. The generation, maintenance, and strength of the LLJ were very sensitive to the parameterization of turbulent mixing in the SBL. In the case of the off-ice flow, the modification of the air mass and the development of a convective boundary layer (CBL) both over the ice and open sea were reasonably well modelled. Sensitivity runs suggested that it was essential to take into account the effects of subgrid-scale leads, a forest in the archipelago (which was crossed by the air flow), and water vapour condensationinto ice crystals. The heat flux from leads was particularly important for the heatbudget of the CBL, and the observed growth of the CBL was partly due to theeffective mixing over the rough and relatively warm forest.  相似文献   
78.
The response of low‐ductility reinforced concrete (RC) frames, designed typically for a non‐seismic region, subjected to two frequencies of base excitations is studied. Five half‐scaled, two‐bay, two‐storey, RC frames, each approximately 5 m wide by 3.3 m high, were subjected to both horizontal and/or vertical base excitations with a frequency of 40 Hz as well as a lower frequency of about 4 Hz (close to the fundamental frequency) using a shake table. The imposed acceleration amplitude ranged from 0.2 to 1.2g. The test results showed that the response characteristics of the structures differed under high‐ and low‐frequency excitations. The frames were able to sustain high‐frequency excitations without damage but were inadequate for low‐frequency excitations, even though the frames exhibited some ductility. Linear‐elastic time‐history analysis can predict reasonably well the structural response under high‐frequency excitations. As the frames were not designed for seismic loads, the reinforcement detailing may not have been adequate, based on the crack pattern observed. The effect of vertical excitation can cause significant additional forces in the columns and moment reversals in the beams. The ‘strong‐column, weak‐beam’ approach for lateral load RC frame design is supported by experimental observations. Copyright © 2001 John Wiley & Sons, Ltd.  相似文献   
79.
The seismic response of single‐degree‐of‐freedom (SDOF) systems incorporating flag‐shaped hysteretic structural behaviour, with self‐centring capability, is investigated numerically. For a SDOF system with a given initial period and strength level, the flag‐shaped hysteretic behaviour is fully defined by a post‐yielding stiffness parameter and an energy‐dissipation parameter. A comprehensive parametric study was conducted to determine the influence of these parameters on SDOF structural response, in terms of displacement ductility, absolute acceleration and absorbed energy. This parametric study was conducted using an ensemble of 20 historical earthquake records corresponding to ordinary ground motions having a probability of exceedence of 10% in 50 years, in California. The responses of the flag‐shaped hysteretic SDOF systems are compared against the responses of similar bilinear elasto‐plastic hysteretic SDOF systems. In this study the elasto‐plastic hysteretic SDOF systems are assigned parameters representative of steel moment resisting frames (MRFs) with post‐Northridge welded beam‐to‐column connections. In turn, the flag‐shaped hysteretic SDOF systems are representative of steel MRFs with newly proposed post‐tensioned energy‐dissipating connections. Building structures with initial periods ranging from 0.1 to 2.0s and having various strength levels are considered. It is shown that a flag‐shaped hysteretic SDOF system of equal or lesser strength can always be found to match or better the response of an elasto‐plastic hysteretic SDOF system in terms of displacement ductility and without incurring any residual drift from the seismic event. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
80.
The damping‐solvent extraction method for the analysis of unbounded visco‐elastic media is evaluated numerically in the frequency domain in order to investigate the influence of the computational parameters—domain size, amount of artificial damping, and mesh density—on the accuracy of results. An analytical estimate of this influence is presented, and specific questions regarding the influence of the parameters on the results are answered using the analytical estimate and numerical results for two classical problems: the rigid strip and rigid disc footings on a visco‐elastic half‐space with constant hysteretic material damping. As the domain size is increased, the results become more accurate only at lower frequencies, but are essentially unaffected at higher frequencies. Choosing the domain size to ensure that the static stiffness is computed accurately leads to an unnecessarily large domain for analysis at higher frequencies. The results improve by increasing artificial damping but at a slower rate as the total (material plus artificial) damping ratio ζt gets closer to 0.866. However, the results do not deteriorate significantly for the larger amounts of artificial damping, suggesting that ζt≈0.6 is appropriate; a larger value is not likely to influence the accuracy of results. Presented results do not support the earlier suggestion that similar accuracy can be achieved by a large bounded domain with small damping or by a small domain with larger damping. Copyright © 2002 John Wiley & Sons, Ltd.  相似文献   
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